● A spindle-shaped influent chamber was designed and equipped in FCDI system.

Flow-electrode capacitive deionization (FCDI) is an innovative technology in which an intermediate chamber plays an important role in the desalination process. However, relatively few studies have been conducted on the structures of these intermediate chambers. In this study, we propose a novel flow-electrode capacitive deionization device with a spindle-shaped inlet chamber (S-FCDI). The desalination rate of the S-FCDI under optimal operating conditions was 36% higher than that of the FCDI device with a conventional rectangular chamber (R-FCDI). The spindle-shaped chamber transferred 1.2 μmol more ions than the rectangular chamber, based on energy per joule. Additionally, we performed a detailed analysis of different inlet chamber shapes using computational fluid dynamics software. We concluded that S-FCDI has a relatively low flow resistance and almost no stagnation zone. This provides unique insights into the development of intermediate chambers. This study may contribute to the improvement of the desalination performance in industrial applications of FCDI.

● Temperature variability is an independent risk factor of cardiovascular diseases.

Relationships between nonoptimal temperatures and cardiovascular disease (CVD) mortality have been well documented. However, evidence of the association between temperature variability (TV) and CVD morbidity is limited. This study aimed to quantify the risk and burden of CVD-related hospitalization associated with the magnitude and direction of TV. Data on meteorology and population-based hospitalizations for myocardial infarction (MI) and stroke were collected in Guangzhou, China, from 2013 to 2017. Hourly temperature variability (HTV) was measured as the standard deviation of hourly temperature records over specific exposure days. The direction (upward or downward) of HTV was defined as the average daily mean temperature change relative to that of the previous day during the exposure period. Quasi-Poisson regression was applied to assess the impact of HTV after adjusting for the daily mean temperature, and the hospitalization fractions attributable to HTV were calculated. A 1 °C-increase in HTV was significantly associated with a 2.24% and 1.72% increase in hospitalizations for MI and hemorrhagic stroke (HS) at lag 0–1 d, respectively, and a 1.55% increase in hospitalizations for ischemic stroke (IS) at lag 0–3 d. During the study period, 5.99%, 4.64%, and 4.53% of MI, HS, and IS hospitalizations, respectively, were attributable to HTV. The upward TV exerts acute effects on CVD hospital admissions, whereas the impact of downward TV generally lags. These findings highlight the importance of the magnitude and direction of temperature fluctuations, in addition to the mean level, in assessing the adverse health impacts of temperature variations.

● Cr self-catalysis behaviors during Cr-initiated AOPs were described.

Chromium (Cr), as a transition metal material with multiple redox states, has exhibited the catalysis toward Fenton-like reactions over a wide pH range. Although it is not sensible to add Cr reagents as catalysts due to its toxicity, it is highly promising to remediate Cr-containing wastewater through Cr-initiated advanced oxidation processes (Cr-initiated AOPs), which are clean and low-cost. Moreover, the widely concerned Cr-complexes, considered as obstacles in the remediation process, can be effectively destroyed by AOPs. Cr self-catalysis is defined as Cr species is both substrate and catalyst. However, the full understanding of Cr self-catalysis, including the generation of intermediates Cr(IV)/Cr(V), the synergetic effects with co-existing ions, and the accumulation of toxic Cr(VI), remains a challenge for the practical application of Cr-initiated AOPs. In this review, relevant researches on Cr self-catalysis during Cr-initiated AOPs are summarized. Specifically, the Cr-Fenton-like reaction, Cr substituted materials, and Cr-sulfite reactions are explored as key mechanisms contributing to Cr self-catalysis. Moreover, Cr transformation processes, including synchronously Cr removal, Cr redox reactions, and Cr(VI) accumulation, in AOPs-based synergistic systems are systematically analyzed. Detailed approaches for the detection of active species in AOPs-based systems are also presented. The primary objective of this review is to explore the application of AOPs for Cr-containing wastewater remediation based on Cr self-catalysis, and provide fundamental insights and valuable information for future research on Cr-initiated AOPs.

● Energy harvesters harness multiple energies for self-powered water purification.

The development of self-powered water purification technologies for decentralized applications is crucial for ensuring the provision of drinking water in resource-limited regions. The elimination of the dependence on external energy inputs and the attainment of self-powered status significantly expands the applicability of the treatment system in real-world scenarios. Hybrid energy harvesters, which convert multiple ambient energies simultaneously, show the potential to drive self-powered water purification facilities under fluctuating actual conditions. Here, we propose recent advancements in hybrid energy systems that simultaneously harvest various ambient energies (e.g., photo irradiation, flow kinetic, thermal, and vibration) to drive water purification processes. The mechanisms of various energy harvesters and point-of-use water purification treatments are first outlined. Then we summarize the hybrid energy harvesters that can drive water purification treatment. These hybrid energy harvesters are based on the mechanisms of mechanical and photovoltaic, mechanical and thermal, and thermal and photovoltaic effects. This review provides a comprehensive understanding of the potential for advancing beyond the current state-of-the-art of hybrid energy harvester-driven water treatment processes. Future endeavors should focus on improving catalyst efficiency and developing sustainable hybrid energy harvesters to drive self-powered treatments under unstable conditions (e.g., fluctuating temperatures and humidity).

● A study assessing the temperature-injury relationship was conducted among students.

Although studies have suggested that non-optimal temperatures may increase the risk of injury, epidemiological studies focusing on the association between temperature and non-fatal injury among children and adolescents are limited. Therefore, we investigated the short-term effect of ambient temperature on non-fatal falls and road traffic injuries (RTIs) among students across Jiangsu Province, China. Meteorological data and records of non-fatal outdoor injuries due to falls and RTIs among students aged 6–17 were collected during 2018–2020. We performed a time-stratified case-crossover analysis with a distributed lag nonlinear model to examine the effect of ambient temperature on the risk of injury. Individual meteorological exposure was estimated based on the address of the selected school. We also performed stratified analyses by sex, age, and area. A total of 57322 and 5455 cases of falls and RTIs were collected, respectively. We observed inverted U-shaped curves for temperature-injury associations, with maximum risk temperatures at 18 °C (48th of daily mean temperature distribution) for falls and 22 °C (67th of daily mean temperature distribution) for RTIs. The corresponding odds ratios (95% confidence intervals) were 2.193 (2.011, 2.391) and 3.038 (1.988, 4.644) for falls and RTIs, respectively. Notably, there was a significant age-dependent trend in which the temperature effect on falls was greater in older students (P-trend < 0.05). This study suggests a significant association between ambient temperature and students’ outdoor falls and RTIs. Our findings may help advance tailored strategies to reduce the incidence of outdoor falls and RTIs in children and adolescents.

● Increased DAAO offsets 3/4 of the decrease of DAAP in 2013–2020.

PM_2.5 concentration declined significantly nationwide, while O₃ concentration increased in most regions in China in 2013–2020. Recent evidences proved that peak season O₃ is related to increased death risk from non-accidental and respiratory diseases. Based on these new evidences, we estimate excess deaths associated with long-term exposure to ambient PM_2.5 and O₃ in China following the counterfactual analytic framework from Global Burden Disease. Excess deaths from non-accidental diseases associated with long-term exposure to ambient O₃ in China reaches to 579 (95% confidential interval (CI): 93, 990) thousand in 2020, which has been significantly underestimated in previous studies. In addition, the increased excess deaths associated with long-term O₃ exposure (234 (95% CI: 177, 282) thousand) in 2013–2020 offset three quarters of the avoided excess deaths (302 (95% CI: 244, 366) thousand) mainly due to PM_2.5 exposure reduction. In key regions (the North China Plain, the Yangtze River Delta and the Fen-Wei Plain), the former is even larger than the latter, particularly in 2017–2020. Health benefit of PM_2.5 concentration reduction offsets the adverse effects of population growth and aging on excess deaths attributed to PM_2.5 exposure. Increase of excess deaths associated with O₃ exposure is mainly due to the strong increase of O₃ concentration, followed by population aging. Considering the faster population aging process in the future, collaborative control, and faster reduction of PM_2.5 and O₃ are needed to reduce the associated excess deaths.

● A global snapshot of plastic waste generation and disposal is analysed.

Plastic is considered one of the most indispensable commodities in our daily life. At the end of life, the huge ever-growing pile of plastic waste (PW) causes serious concerns for our environment, including agricultural farmlands, groundwater quality, marine and land ecosystems, food toxicity and human health hazards. Lack of proper infrastructure, financial backup, and technological advancement turn this hazardous waste plastic management into a serious threat to developing countries, especially for Bangladesh. A comprehensive review of PW generation and its consequences on environment in both global and Bangladesh contexts is presented. The dispersion routes of PW from different sources in different forms (microplastic, macroplastic, nanoplastic) and its adverse effect on agriculture, marine life and terrestrial ecosystems are illustrated in this work. The key challenges to mitigate PW pollution and tackle down the climate change issue is discussed in this work. Moreover, way forward toward the design and implementation of proper PW management strategies are highlighted in this study.

● China has pledged ambitious carbon peak and neutrality goals for mitigating global climate change.

China is the largest developing economy and carbon dioxide emitter in the world, the carbon neutrality goal of which will have a profound influence on the mitigation pathway of global climate change. The transition towards a carbon-neutral society is integrated into the construction of ecological civilization in China, and brings profound implications for China’s socioeconomic development. Here, we not only summarize the major challenges in achieving carbon neutrality in China, but also identify the four potential new opportunities: namely, the acceleration of technology innovations, narrowing regional disparity by reshaping the value of resources, transforming the industrial structure, and co-benefits of pollution and carbon mitigation. Finally, we provide five policy suggestions and highlight the importance of balancing economic growth and carbon mitigation, and the joint efforts among the government, the enterprises, and the residents.

● Electroconductive RGO-MXene membranes were fabricated.

Reduced graphene oxide (RGO) membranes are theoretically more conducive to the rapid transport of water molecules in their channels compared with graphene oxide (GO) membranes, as they have fewer oxygen-containing functional groups and more non-oxidized regions. However, the weak hydrophilicity of RGO membranes inhibits water entry into their channels, resulting in their low water permeability. In this work, we constructed wettable RGO-MXene channels by intercalating hydrophilic MXene nanosheets into the RGO membrane for improving the water permeance. The RGO-MXene composite membrane exhibits high pure water permeance of 62.1 L/(m²·h·bar), approximately 16.8 times that of the RGO membrane (3.7 L/(m²·h·bar)). Wettability test results and molecular dynamics simulations suggest that the improved water permeance results from the enhanced wettability of RGO-MXene membrane and increased rate of water molecules entering the RGO-MXene channels. Benefiting from good conductivity, the RGO-MXene membrane with electro-assistance exhibits significantly increased rejection rates for negatively charged dyes (from 56.0% at 0 V to 91.4% at 2.0 V for Orange G) without decreasing the permeate flux, which could be attributed to enhanced electrostatic repulsion under electro-assistance.

● Systematic information of recent progress in photocatalytic NO _x removal is provided.

The significant increase of NO_x concentration causes severe damages to environment and human health. Light-driven photocatalytic technique affords an ideal solution for the removal of NO_x at ambient conditions. To enhance the performance of NO_x removal, 1D, 2D and 3D photocatalysts have been constructed as the light absorption and the separation of charge carriers can be manipulated through controlling the morphology of the photocatalyst. Related works mainly focused on the construction and modification of special morphologic photocatalyst, including element doping, heterostructure constructing, crystal facet exposing, defect sites introducing and so on. Moreover, the excellent performance of the photocatalytic NO_x removal creates great awareness of the application, which has promising practical applications in NO_x removal by paint (removing NO_x indoor and outdoor) and pavement (degrading vehicle exhausts). For these considerations, recent advances in special morphologic photocatalysts for NO_x removal was summarized and commented in this review. The purpose is to provide insights into understanding the relationship between morphology and photocatalytic performance, meanwhile, to promote the application of photocatalytic technology in NO_x degradation.