Electroconductive RGO-MXene membranes with wettability-regulated channels: improved water permeability and electro-enhanced rejection performance

Highlights

● Electroconductive RGO-MXene membranes were fabricated.

● Wettable membrane channels were established between RGO and MXene nanosheets.

● Hydrophilic MXene reduces the resistance of water entering the membrane channels.

● Water permeance of RGO-MXene membrane is 16.8 times higher than that of RGO membrane.

● Electro-assistance can enhance the dye rejection performance of RGO-MXene membrane.

Abstract

Reduced graphene oxide (RGO) membranes are theoretically more conducive to the rapid transport of water molecules in their channels compared with graphene oxide (GO) membranes, as they have fewer oxygen-containing functional groups and more non-oxidized regions. However, the weak hydrophilicity of RGO membranes inhibits water entry into their channels, resulting in their low water permeability. In this work, we constructed wettable RGO-MXene channels by intercalating hydrophilic MXene nanosheets into the RGO membrane for improving the water permeance. The RGO-MXene composite membrane exhibits high pure water permeance of 62.1 L/(m²·h·bar), approximately 16.8 times that of the RGO membrane (3.7 L/(m²·h·bar)). Wettability test results and molecular dynamics simulations suggest that the improved water permeance results from the enhanced wettability of RGO-MXene membrane and increased rate of water molecules entering the RGO-MXene channels. Benefiting from good conductivity, the RGO-MXene membrane with electro-assistance exhibits significantly increased rejection rates for negatively charged dyes (from 56.0% at 0 V to 91.4% at 2.0 V for Orange G) without decreasing the permeate flux, which could be attributed to enhanced electrostatic repulsion under electro-assistance.

Graphical abstract

Keywords

Reduced graphene oxide / MXene / Membrane / Water permeance / Dye rejection / Electro-assistance

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Acknowledgements

This research was supported by the National Key Research and Development Program of China (No. 2020YFA0211001), the National Natural Science Foundation of China (Nos. 21976024 and 22106017), and the Programme of Introducing Talents of Discipline to Universities (China) (B13012).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11783-023-1601-8 and is accessible for authorized users.

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