RESEARCH ARTICLE

Microstructure and electrical properties of NaNbO3-BaTiO3 lead-free piezoelectric ceramics

  • Shihui XIE ,
  • Kongjun ZHU ,
  • Jinhao QIU ,
  • Hua GUO
Expand
  • Aeronautic Key Laboratory for Smart Materials & Structures, Nanjing University of Aeronautics & Astronautics, Nanjing, 210016, China

Received date: 10 Nov 2008

Accepted date: 01 Dec 2008

Published date: 05 Sep 2009

Copyright

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg

Abstract

Lead-free piezoelectric ceramics (1-x)NaNbO3-xBaTiO3 have been fabricated by a traditional ceramic sintering technique. The effects of BaTiO3 (BT) synthesized by hydrothermal method on crystal structure, density, dielectric, piezoelectric, and electromechanical properties were investigated. Results show that the phase structure transforms from the orthorhombic phase to the tetragonal phase with the increase of the content of BT, and the two phases co-exist when 0.08<x≤0.10. However, the optimum composition for (1-x)NaNbO3-xBaTiO3 ceramics is 0.90NaNbO3-0.10BaTiO3. The 0.90NaNbO3-0.10BaTiO3 ceramics sintered at 1250°C have higher properties: piezoelectric constant d33 of 120 pC/N, dielectric constant ϵr of 718, planar electromechanical coupling factor kp of 24%, planar frequency Nd of 3 MHz·mm, and the mechanical quality factor Qm of 138, respectively. The results show that the (1-x)NaNbO3-xBaTiO3 ceramics is one of the promising lead-free materials for high-frequency applications.

Cite this article

Shihui XIE , Kongjun ZHU , Jinhao QIU , Hua GUO . Microstructure and electrical properties of NaNbO3-BaTiO3 lead-free piezoelectric ceramics[J]. Frontiers of Mechanical Engineering, 2009 , 4(3) : 345 -349 . DOI: 10.1007/s11465-009-0050-9

Acknowledgements

The authors would like to thank the financial support from the Fostering Fund of the Ministry of Education (No. 707031) and the National 863 Foundation Program (No. 2007AA03Z104).
1
Matsubara M, Yamaguchi T. Processing and piezoelectric properties of lead-free (K,Na)(Nb,Ta)O3 ceramics. J Am Ceram Soc, 2005, 88 (5): 1190-1196

DOI

2
Zhang S J, Xia R. Characterization of lead free (Na0.5K0.5)NbO3-LiSbO3 piezoceramic. Solid State Communications, 2007, 141: 675-679

DOI

3
Zhang S J, Xia R. Lead-free piezoelectric ceramics vs. PZT. J. Electroceram, DOI:10.1007/s10832-007-9056-z, 2007

DOI

4
Ahn C W, Song H C. Effect of MnO2 on the piezoelectric properties of (1-x)(Na0.5K0.5)NbO3-xBaTiO3 ceramics. Japanese Journal of Applied Physics, 2005, 44: 1361-1364

DOI

5
Zhi Y, Chen A. Piezoelectric and strain properties of Ba(Ti1-xZrx)O3 ceramics. Journal of Applied Physics, 2002, 92(3): 1489-1493

DOI

6
Lin D, Kowk K W. Structure and electrical properties of (Na0.5K0.5)NbO3-LiSbO3 lead-free piezoelectric ceramics. Journal of Applied Physics, 2007, 101: 074111–(1–6)

7
Chang R C, Chu S Y. The effect of sintering temperature on the properties of (Na0.5K0.5)NbO3-CaTiO3 based lead-free piezoelectric ceramics. Sensors and Actuators A, 2007, 138: 355-360

DOI

8
Du H L, Tang F S. Influence of sintering temperature on piezoelectric Properties of (Na0.5K0.5)NbO3-LiNbO3 lead-free piezoelectric ceramics. Materials Research Bulletin, 2007, 42: 1594-1601

DOI

9
Hagh N M, Jadidian B. Property-processing Relationship in Lead-Free (K,Na,Li)NbO3-solid solution system. J Electroceram, 2007, 18: 339-346

DOI

10
Satio Y, Takao H. Lead-Free Piezoceramics. Nature, 2004, 432(4): 84-87

11
Matsubara M, Yamaguchi T. Synthesis and characterization of (Na0.5K0.5)(Nb0.7Ta0.3)O3 piezoelectric ceramics sintered with sintering aid K5.4Cu1.3Ta10O29. Japanese Journal of Applied Physics, 2005, 44(9) : 6618-6623

DOI

12
Guo Y P, Kakimoto K I. (Na0.5K0.5)NbO3-LiTaO3 lead-free piezoelectric ceramics. Materials Letters, 2005, 59: 241-244

DOI

13
Hollenstein E, Davis M. Piezoelectric properties of Li- and Ta-modified (Na0.5K0.5)NbO3 ceramics. Applied Physics Letters, 2005, 87: 182905–(1–3)

14
Guo Y P, Kakimoto K. Dielectric and piezoelectric properties of lead-free (Na0.5K0.5)NbO3-SrTiO3 ceramics. Solid State Communications, 2004, 129: 279-284

DOI

15
Chang Y F, Yang Z P. Dielectric and piezoelectric properties of Alkaline-earth Titanate doped (Na0.5K0.5)NbO3 ceramics. Materials Letters, 2007, 61: 785-789

DOI

16
Jiao G C, Fan H Q. Structure and piezoelectric properties of Cu-doped Potassium Sodium Tantalite Niobate ceramics. Materials Letters, 2007, 61: 4185-4187

DOI

17
Wang R, Xie R J. Enhanced piezoelectricity around the tetragonal/orthorhombic morphotropic phase boundary in (K,Na)NbO3-ATiO3 solid solution. J Electroceram, DOI:10.1007/s10832-007-9136-0, 2007

DOI

18
Zeng J T, Kwok K W. Ferroelectric and Piezoelectric Properties of Na1-xBaxNb1-xTixO3 Ceramics. J Am Ceram Soc, 2006 , 89: 2828-2832

19
Aoyagi R, Matsuoka T. Piezoelectric properties of NaNbO3-BaTiO3 ceramics. In: Sixteenth IEEE International Symposium. Applications of Ferroelectrics, ISAF, 2007, 677-678

20
Park S H, Ahn C W. Microstructure and piezoelectric properties of ZnO-added (Na0.5K0.5)NbO3 ceramics. Japanese Journal of Applied Physics, 2004, 43(8B): 1072-1074

DOI

Outlines

/