Surface plasmon resonance and field confinement in graphene nanoribbons in a nanocavity

Sa Yang , Ren-Long Zhou , Yang-Jun Huang

Front. Phys. ›› 2021, Vol. 16 ›› Issue (4) : 43504

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Front. Phys. ›› 2021, Vol. 16 ›› Issue (4) :43504 DOI: 10.1007/s11467-021-1060-2
RESEARCH ARTICLE
Surface plasmon resonance and field confinement in graphene nanoribbons in a nanocavity
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Abstract

In this work, we demonstrate surface plasmon resonance properties and field confinement under a strong interaction between a waveguide and graphene nanoribbons (GNRs), obtained by coupling with a nanocavity. The optical transmission of a waveguide–cavity–graphene structure is investigated by finite-difference time-domain simulations and coupled-mode theory. The resonant frequency and intensity of the GNR resonant modes can be precisely controlled by tuning the Fermi energy and carrier mobility of the graphene, respectively. Moreover, the refractive index of the cavity core, the susceptibility χ(3) and the intensity of incident light have little effect on the GNR resonant modes, but have good tunability to the cavity resonant mode. The cavity length also has good tunability to the resonant mode of cavity. A strong interaction between the GNR resonant modes and the cavity resonant mode appears at a cavity length of L1 = 350 nm. We also demonstrate the slow-light effect of this waveguide–cavity–graphene structure and an optical bistability effect in the plasmonic cavity mode by changing the intensity of the incident light. This waveguide–cavity–graphene structure can potentially be utilised to enhance optical confinement in graphene nano-integrated circuits for optical processing applications.

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Keywords

graphene nanoribbon / surface plasmon resonance / confinement

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Sa Yang, Ren-Long Zhou, Yang-Jun Huang. Surface plasmon resonance and field confinement in graphene nanoribbons in a nanocavity. Front. Phys., 2021, 16 (4) : 43504 DOI:10.1007/s11467-021-1060-2

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1 Introduction

Graphene has received substantial attention in the fields of carbon-based nanomaterials and optoelectonic devices due to its remarkable electronic, mechanical and optical properties, including dynamic tunability, extreme confinement and low losses [1]. Surface plasmon resonance (SPR) plays a critical role in the properties of graphene and has numerous applications in optical devices such as bandpass filters, optical waveguides, infrared detector focal plane arrays, directional couplers and metal–dielectric–metal waveguides [2–4]. Compared with traditional plasmonic materials, plasmons in graphene, as a new plasmonic material, exhibit many unusual behaviours, including a higher wave velocity, longer lifetime and longer propagation distance [5]. The frequency tunability based on electrostatic gating or Fermi energy is an important characteristic of graphene plasmons (GPs) [6].

Graphene nanoribbons (GNRs) can directly couple propagating electromagnetic waves into bound collective charge oscillations [7]. However, the absorption of highly confined plasmonic waves in monolayer graphene is ~2.3% [8, 9]. Therefore, methods for enhancing the absorption in graphene plasmonic devices have been investigated [10–12]. GPs have been studied in a variety of patterns, such as disc, ring, nanoribbon and antidote array patterns [13–16]. Multiple coupling systems have been demonstrated, including band-pass filters, optical splitters, all-optical switches, graphene gratings and directional couplers [17, 18]. Numerous graphene structures have been designed to obtain surface plasmons and to improve the confinement in graphene. Previous works in graphene have demonstrated that GPs have a better tunability and lower loss than plasmons in metals. High absorption has been reported in grating-coupled graphene embedded in a Fabry–Perot cavity [19]. Additionally, GNR arrays have stronger coupling than single GNRs [20, 21]. Such designs also have advantages such as ease in fabrication, strong localization and zero bending loss [22]. Plasmonic–photonic absorption properties and their ultrafast dynamics in two-dimensional (2D) materials have broad applications for photodetectors [23–25], quantum dots [26–28], saturable absorbers [29, 30], biomedical devices [31–33], photothermal devices [34–36] and other 2D material nanoplatforms [37–43]. The limitations in controllable tuning between a single GNR and a propagating wave hinder the development of graphene plasmonic devices. Moreover, there are few reports of enhanced absorption in a single finite GNR. However, layered graphene systems and GNRs have exhibited the ability to directly tune plasmons in nanostructures, such as sinusoidally curved and planar graphene layer systems [44], double-layered GNR systems [45] and GNRs coupled with dielectric grating loaded graphene layer resonators [46].

This paper presents optical confinement in two GNR layers combined with a plasmonic cavity and a waveguide based on the finite-difference time-domain (FDTD) method. In addition to the FDTD approach, the rapid and reliable temporal coupled-mode theory (CMT) method [47, 48] is also used to analyse this plasmonic waveguide–cavity–graphene (WCG) structure. The plasmonic WCG structure can couple the electromagnetic field of the plasmonic waveguide into a cavity resonator and the GNRs. The two GNR layers play an important role in tuning the plasmons in the GNRs and the cavity. Furthermore, the three resonant modes in this system are investigated separately by altering the Fermi energy of the GNRs, the carrier mobility of the GNRs, the cavity length, the refractive index of the cavity core, the susceptibility χ(3) and the intensity of the incident light. We also present the slow-light effect of this WCG structure and an optical bistability effect in the plasmonic cavity mode by changing the intensity of the incident light. The designed WCG structure can be potentially applied to optical confinement in integrated circuits for optoelectronic processing.

2 Design of the structure model

Figure 1 shows a schematic of the WCG structure, which consists of a plasmonic waveguide, a cavity resonator and two GNRs. A plane wave with a polarised Ex component is emitted from the left port of the plasmonic waveguide and propagates along the x-axis direction. To model the transmission and absorption properties of the structure, the perfectly matched layer (PML) absorbing boundary condition is employed.

The cavity resonator has a length of L1 = 400 nm and a width of L2 = 300 nm. One GNR, G1, with length L1 is placed in the cavity at a distance of h1 = 170 nm from the bottom of the cavity along the y direction. Another GNR, G0, with the same length L1 is also placed in the cavity at a distance of h2 = 150 nm from the bottom of the cavity. The distance between G0 and G1 is 20 nm. The metal in our structure is silver, which can be defined by the Drude model: εm(ω) = ε∞−ωp2/ω (ω+iγ) [22]. Here the dielectric constant at infinite frequency ε∞, the plasma frequency ωp and the damping rate γ are set as 3.7, 1.38 ×1016 rad/s and 2.73 ×1013 rad/s, respectively. We assume that the dielectric in the waveguide is air and set the waveguide width as 100 nm. The coupling thickness h3 between the waveguide and cavity resonator is 20 nm.

At room temperature, the intraband conductivity σintra of graphene is given by σintra = −ie2Ef/[πℏ2(ω − iτ−1)] [21], where ℏ, e, τ and Ef denote the reduced Planck constant, electric charge, carrier relaxation time and Fermi energy, respectively. The relaxation time τ can be determined by the carrier mobility µ and Fermi energy Ef in graphene as τ = (μEf)/(evf2). The carrier mobility µ is 1 m2/(V·s), and the Fermi velocity vf is ~106 m/s. The Fermi energy in G0 is fixed at Ef = 0.64 eV in this paper, and the Fermi energy in G1 is noted as Ef,G1 . Both G0 and G1 have a thickness of h = 1 nm. The graphene exhibits a metal-like response to an in-plane electric field and a dielectric-like response to a surface-normal electric field. The in-plane dielectric tensor component is ε11 = ε33 = 1 + iσintra/(ε0ωh), and the surface-normal dielectric tensor component is ε22 = 1.

A third-order nonlinear dielectric material is used to fill the cavity, with a dielectric constant of εd. Under nonlinear conditions, the dielectric constant εd of the Kerr material depends on the intensity of the electric field |E|2 as εd = ε0 + χ(3) |E|2, where the linear refractive index ε0 is set to 1.0 and the third-order nonlinear susceptibility is set to χ(3) = 1 ×10−14 m2/V2.

For the WCG structure, the dynamic transmission features can be analysed by the CMT. S±,in and S±,out denote the incoming and outgoing waves in the waveguide ports, and the subscript ± represents the two propagating directions of the waveguide modes. The transfer function t(ω) = S±,out/S±,in of this plasmonic WCG system can be calculated by the following formula:

(1)t(ω)=1−(1τw1+1τi1)P0P1−(1τw2+1τi2)P0P2−(1τw3+1τi3)P0P3,

(2)P0=(χ1χ4χ5+χ1χ3γ3+χ2χ5γ2+χ2χ3χ6+γ1χ4χ6−γ1γ2γ3)−1,

(3)P1=(γ2γ3−χ4χ6)1τw1+(χ1γ3+χ2χ6)1τw2+(χ2γ2+χ1χ4)1τw3,

(4)P2=(χ4χ5+χ3γ3)1τw1+(γ1γ3−χ2χ5)1τw2+(γ1χ4+χ2χ3)1τw3,

(5)P3=(γ2χ5+χ3χ6)1τw1+(γ1χ6+χ1χ5)1τw2+(γ1γ2−χ1χ3)1τw3,

where 1/τim (m = 1, 2, 3) is the decay rate due to the intrinsic loss of the m-th mode in the graphene grating and τim is the lifetime in this process. 1/τwm is the decay rate due to the energy coupling from each mode into the light field, and τwm is the lifetime during the process of energy coupling. µij (i, j = 1, 2, 3) represents the coefficients of coupling among the three resonant modes. ωm(λm) (m = 1, 2, 3) is the resonant frequency (wavelength) of the three modes. δm = ω−ωm, γm = iδm−1/τim−1/τwm, χ1 = iµ12, χ2 = iµ13, χ3 = iµ21, χ4 = iµ23, χ5 = iµ31, χ6 = iµ32. The transmission of the system can be expressed as T (ω) = |t(ω)|2.

3 Surface plasmon resonance and strong field confinement

The FDTD and CMT methods were applied to investigate the optical spectra for this plasmonic WCG structure. The PML boundary conditions enclose the computational domain. The interior of the computational window contains the silver, waveguide, cavity and two GNRs, as shown in Fig. 1. The Fermi energy in G1 is set as Ef,G1 = 0.74 eV.

Figure 2 presents transmission spectra for the WCG structure. The red line in Fig. 2(a) shows the transmission spectrum for the cavity only in the WCG structure, in which one transmission dip arises at 977.7 nm. The blue line in Fig. 2(a) shows the transmission spectrum for G0 and the cavity existing in the WCG structure, in which two transmission dips arise at 900.1 and 997.2 nm. The green line in Fig. 2(a) presents the transmission spectrum for G1 and the cavity existing in the WCG structure, in which two transmission dips arise at 838.6 and 988.7 nm. Figure 2(b) shows the transmission spectrum for the cavity and two GNRs existing in the WCG structure based on the CMT (red solid line) and numerical FDTD simulations (black circles). Three transmission dips arise, corresponding to resonant wavelengths of λ1 = 838 nm, λ2 = 903 nm and λ3 = 1006 nm, which represent resonant mode 1 of G1, resonant mode 2 of G0 and resonant mode 3 of the cavity, respectively. For the results shown in Fig. 2(b), all other CMT parameters were set as follows: τw1 = 5.2×1012 rad/s, τw2 = 5.2 ×1012 rad/s, τw3 = 8.5 ×1012 rad/s, τi1 = 2.2 ×1012 rad/s, τi2 = 2.2 ×1012 rad/s, τi3 =1.8 ×1012 rad/s, µ12 = µ21 = 2 ×1012 rad/s, µ13 = µ31 = 2 ×1013 rad/s, µ23 = µ32 = 2 ×1013 rad/s. Clearly, the FDTD simulation results agree well with the CMT results.

To more clearly illustrate the three resonance modes,the corresponding electric field amplitude distributions(|E|) at the transmission dips (λ1, λ2 and λ3) are displayed in Figs. 3(a)–(c). Figures 3(d)–(f) present top view of Figs. 3(a)–(c). It is found that the energy of the electric field at wavelengths λ1, λ2 and λ3 is strongly confined in G0, G1 and the cavity, respectively, due to the plasmon resonance effect. Additionally, the intensity of the electric field (|E|) in G0 and G1 is larger than that in the cavity.

From a practical viewpoint, the ability to tune the spectral response of the GP structure is an essential feature for optical applications. Tunability based on electrostatic gating or Fermi energy is a dominant feature of GPs. The evolution of the transmission spectrum for different Fermi energies Ef,G1 with three coupling quality factors (Q12 = 30, 50 and 200) between G0 and G1 were investigated using the CMT, as shown in Fig. 4(a). Figure 4(b) presents a more detailed view of Fig. 4(a). Additional detailed views are also shown in Figs. 4(c)–(f). The transmission spectra (black circles) simulated for four Fermi energies [(c) Ef,G1 = 0.74 eV, (d) Ef,G1 = 0.64 eV, (e) Ef,G1 = 0.54 eV and (f) Ef,G1 = 0.44 eV] are in good agreement with the CMT results (red line).

Figure 4 shows that graphene plasmon resonant mode 2 remains almost unchanged at λ2 = 903 nm when Ef,G0 is fixed at 0.64 eV. Meanwhile, graphene plasmon resonant mode 1 can be tuned by altering Ef,G1 . This structure exhibits strong localisation in the two GNRs due to the enhanced interaction between the GNRs and the plasmonic waves. Graphene plasmon resonant modes 1 and 2 are denoted as bound states in the continuum (BIC). All of the energy in these modes is confined in the two GNRs. Because of their special properties, BICs are desirable for applications in the design of resonators, lasers, filters and biosensors. In Figs. 4(a) and (b), when Ef,G1 is equal to 0.64 eV, the graphene plasmon resonant mode 1 of G1 cannot be excited due to destructive interference from the BIC. Thus, leaky resonance occurs at Ef,G1 = 0.64 eV. When the Fermi energy Ef,G1 in G1 approaches near 0.64 eV, the resonant frequency of the coupling between G0 and G1 can be deduced as ω≈ω±≈(ω1+ω2)/2±|µ12|. The resonant frequency will split when ω1≈ω2. When ω1≈ω2, the split frequency difference∆ω≈2 |µ12 | is 5.4314 ×1013 rad/s for Q12 = 200. Moreover, the split frequency difference∆ω≈2 |µ12| is ~1.038 ×1014 rad/s and 7.7768 ×1013 rad/s for Q12 = 30 and 50, respectively.

Figure 5 presents transmission spectra for GNRs with different carrier mobilities when Ef,G1 is fixed at 0.74 eV. This figure shows that the simulated transmission spectra (black circles) for carrier mobilities of (a) µ = 1 m2/(V·s), (b) µ = 0.1 m2/(V·s) and (c) µ = 0.03 m2/(V·s) are in good agreement with the CMT results (red line). The transmission spectra become broader and shallower as the carrier mobility µ decreases from µ = 1 m2/(V·s) to µ = 0.03 m2/(V·s). Lower carrier mobility in the GNRs corresponds to a higher loss and a lower quality factor. As a result, the interaction between the graphene surface plasmons and waves is reduced, and the binding effect of the graphene plasmon resonance is also reduced. Thus, the intensity of the graphene plasmon resonance can be largely determined by the carrier mobility of the GNRs.

The WCG coupling system also supports low group velocities. The slow-light effect is described by the group index ng :

(6)ng=cvg=cL1τg=cL1dψ(ω)dω.

Here, vg denotes the group velocity in the WCG system, τg and ψ(ω) are the optical delay time and transmission phase shift, respectively, and L1 = 400 nm is the length of the cavity in the plasmonic coupled system.

Figure 6(a) shows that the slope of the transmission phase shift is negative and is the steepest at the location of the peaks. The maximum optical delay times τg in the transmission are 0.29, 0.23 and 0.27 fs, as shown in Fig. 6(b). A negative optical delay time corresponding to fast light is observed. The group index ng is depicted in Fig. 6(c). The high group index ng near the peaks results from strong dispersion. The maximum group index ng exceeds 0.21 at the peak wavelength, λ1 = 838 nm. The slow-light effect of this WCG coupling system can be used in the design of optical storage devices and high-sensitivity sensing devices.

The FDTD method was utilised to investigate the dependence of the transmission characteristics on the length L1 of the cavity with two GNRs. The parameter Ef,G1 was set as Ef,G1 = 0.74 eV. The evolution of the transmission spectrum with length L1 in the WCG system without the two GNRs is shown in Fig. 7(a). The results show that the resonance wavelength of the cavity mode varies with length L1 in an approximately linear manner. Figure 7(b) shows the evolution of the transmission spectrum with length L1 for the cavity with two GNRs in the WCG structure. When L1 is less than 380 nm, the GNR resonant modes interact with the cavity resonant mode. A strong interaction occurs when L1 reaches ~350 nm. As the cavity length changes from 380 to 500 nm, it has little influence on the two GNR resonant modes.

One can also introduce materials that enable the refractive index of the cavity core (nd) to be changed slightly by external mechanisms such as electro-optic effects. The evolution of the transmission spectrum for different values of nd is shown in Fig. 8. For a small perturbation of nd, the results show that one can reliably predict the spectral response for a perturbed cavity resonator. The zero-order cavity mode in line C1 and the higher-order cavity modes in lines C2 and C3 exhibit an approximately linear relation with nd. Energy splits exist between the second-order modes of the cavity (in line C3) and modes P1 and P2 in the GNRs. The mode 1 of G1 in line P1 and the mode 2 of G0 in line P2 exhibit little change with nd.

We also investigated the susceptibility χ(3) in this system. Figure 9(a) shows the evolution of transmission through the structure for various values of the susceptibility χ(3). The three resonant wavelengths vary with χ(3), as shown in Fig. 9(b). Transmission results are shown for three susceptibility values of χ(3) = 1 (red), 0.5 (blue) and 0.01 (black) in Fig. 9(c). For a small value of χ(3) = 0.01, we see three resonant wavelengths of λ1 = 838 nm, λ2 = 903 nm and λ3 = 1006 nm. As χ(3) increases, the two resonant modes of the two GNRs show little change. However, the resonant wavelength of the cavity mode exhibits a red shift with increasing susceptibility χ(3).

Figure 10(a) shows the evolution of transmission for various values of the incident light intensity I from I = 1×1010 V2/m2 to I = 4 ×1014 V2/m2. As the intensity of the incident light increases, the two resonant modes of the two GNRs show little change. However, the resonant wavelength of the cavity mode exhibits a red shift as the incident light intensity increases.

From Figs. 8–10, we can see that the refractive index of the cavity core nd, the susceptibility χ(3) and the intensity of incident light have little effect on the GNR resonant modes, but can influence the cavity resonant mode. This behaviour is due to the formation of plasmon resonant modes in the GNRs. When light passes through the waveguide, the graphene surface plasmons on the GNRs are excited by a strong interaction among the waveguide, cavity and GNRs. The excited electrons migrate from the metal to the graphene sheet. Subsequently, the GNRs receive excited electrons from the metal, resulting in a collective resonance of a large number of excited electrons. SPR then occurs on the GNR. Thus, the factors that affect the cavity resonant mode, such as nd, the susceptibility χ(3) and the intensity of incident light, have little effect on the graphene resonance modes.

To elucidate the bistability behaviour, Fig. 10(b) shows the transmission of the WCG structure as a function of the incident light intensity at a wavelength at 1016 nm. Clearly, significant differences arise in the transmission response as the intensity of the source increases or decreases. A bistability effect is apparent, and the transmission can follow either the upper branch of the bistability loop (corresponding to an increasing source intensity) or the lower branch (corresponding to a decreasing source intensity). As the incident light intensity increases, the transmission decreases rapidly to a value of ~2.7×1014 V2/m2. Conversely, as the incident light intensity decreases, the transmission remains at a lower value and then jumps suddenly to a value of ~1.85 ×1014 V2/m2. Thus, this WCG structure can also be used in high-speed optical communication, optical storage, optical limiter and optical logic elements.

4 Conclusions

In conclusion, optical confinement in graphene has been numerically and theoretically studied in a coupling WCG structure by FDTD and CMT methods. The results show that the cavity plays an important role in strengthening the graphene plasmon resonance and boosting confined plasmonic waves in GNRs. Three resonance modes were observed in this WCG system. The resonant frequency and intensity of the GNR resonant modes can be precisely controlled by the Fermi energy and carrier mobility of the graphene, respectively. Although the refractive index of the cavity core, the susceptibility χ(3) and the intensity of incident light have little effect on the two GNR resonant modes, they can tune the cavity resonant mode. The length of the cavity can also tune the cavity resonant mode. A strong interaction between the GNR resonant modes and the cavity resonant mode appears at a cavity length of L1 = 350 nm. An optical bistability effect was obtained for the plasmonic cavity mode by changing the intensity of the incident light. The proposed configuration and results can provide guidance for further development of optical confinement in graphene devices.

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