Reply to “Comment to ‘Dynamics of supercooled confined water measured by deep inelastic neutron scattering’ by Y. Finkelstein and R. Moreh”

V. De Michele, G. Romanelli, A. Cupane

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Front. Phys. ›› 2019, Vol. 14 ›› Issue (5) : 53606. DOI: 10.1007/s11467-019-0927-y
COMMENTARY
COMMENTARY

Reply to “Comment to ‘Dynamics of supercooled confined water measured by deep inelastic neutron scattering’ by Y. Finkelstein and R. Moreh”

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Abstract

We reply to the comment [Front. Phys. 14(5), 53605 (2019)] by Y. Finkelstein and R. Moreh on our article Front. Phys. 13(1), 138205 (2018). We agree with some of their criticisms about our calculation of the temperature effect on the kinetic energy of hydrogen atoms of supercooled confined water; we also agree with their statement that, in view of the current sensitivity of the technique, possible effects of the liquid–liquid water transition are hardly detected with deep inelastic neutron scattering (DINS). However, we disagree with their use of the translational mass ratio of a single water molecule and, in general, with their underestimation of collective effects.

Keywords

supercooled water / liquid–liquid transition / deep inelastic neutron scattering / libration / vibrational density of states / proton kinetic energy

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V. De Michele, G. Romanelli, A. Cupane. Reply to “Comment to ‘Dynamics of supercooled confined water measured by deep inelastic neutron scattering’ by Y. Finkelstein and R. Moreh”. Front. Phys., 2019, 14(5): 53606 https://doi.org/10.1007/s11467-019-0927-y

References

[1]
Y. Finkelstein and R. Moreh, Comment to “Dynamics of supercooled confined water measured by deep inelastic neutron scattering”, Front. Phys. 14(5), 53605 (2019)
[2]
V. De Michele, G. Romanelli, and A. Cupane, Dynamics of supercooled confined water measured by deep inelastic neutron scattering, Front. Phys. 13(1), 138205 (2018)
CrossRef ADS Google scholar
[3]
T. S. Grigera, V. Martín-Mayor, G. Parisi, and P. Verrocchio, Vibrational spectrum of topologically disordered systems, Phys. Rev. Lett. 87(8), 085502 (2001)
CrossRef ADS Google scholar
[4]
Yu. M. Galperin, V. G. Karpov, and V. I. Kozub, Localized states in glasses, Adv. Phys. 38(6), 669 (1989)
CrossRef ADS Google scholar
[5]
V. Lubchenko and P. G. Wolynes, The origin of the boson peak and thermal conductivity plateau in lowtemperature glasses, Proc. Natl. Acad. Sci. USA 100(4), 1515 (2003)
CrossRef ADS Google scholar
[6]
A. Cupane, M. Fomina, and G. Schirò, The boson peak of deeply cooled confined water reveals the existence of a low-temperature liquid–liquid crossover, J. Chem. Phys. 141, 18C510 (2014)
CrossRef ADS Google scholar
[7]
Y. Finkelstein and R. Moreh, Applying semi-empirical quantum harmonic calculations for studying the atomic kinetic energies in hydrogen bonded systems, Curr. Phys. Chem. 7(1), 3 (2017)
CrossRef ADS Google scholar
[8]
F. Perakis, G. Camisasca, T. J. Lane, A. Späh, K. T. Wikfeldt, , Coherent X-rays reveal the influence of cage effects on ultrafast water dynamics, Nat. Commun. 9(1), 1917 (2018)
CrossRef ADS Google scholar
[9]
V. De Michele, G. Romanelli, and A. Cupane, Kinetic energy and radial momentum distribution of hydrogen and oxygen atoms of water confined in silica hydrogel in the temperature interval 170–325 K, Sci. China Phys. Mech. & Astron. 62, 107012 (2019)
CrossRef ADS Google scholar

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