Tuning spin reorientation in Er_1–xY_xFeO₃ single crystal family

Abstract

A temperature-induced spin reorientation transition between Г₄ (G_x, A_y, F_z) and Г₂ (F_x, C_y, G_z) has been studied in the family of Er_1–xY_xFeO₃ (x = 0, 0.25, 0.5, 0.75, 1) single crystals. By doping nonmagnetic Y³⁺, we tuned the spin reorientation temperature to low temperature with increasing x. Moreover, the typical compensation point and spin flip transition of ErFeO₃ also decreases with doping, and disappears above x = 0.75. We also report the Rietveld refinements and Raman spectroscopy of Er_1–xY_xFeO₃, where some Raman peaks are shifted to low frequency with increasing doping. Our results shed light on the understanding of the interaction between two magnetic sub-lattices of rare earth (R³⁺) and iron (Fe³⁺) ions, and will also contribute to the materials design and potential applications.

Keywords

Er _{1– x}Y _xFeO ₃ / single crystal growth / magnetic measurements

References

[1] L. White, Review of recent work on the magnetic and spectroscopic properties of the rare-earth orthoferrites, J. Appl. Phys. 40(3), 1061 (1969)

[2] R. Huang, S. Cao, W. Ren, S. Zhan, B. Kang, and J. Zhang, Large rotating field entropy change in ErFeO₃ single crystal with angular distribution contribution, Appl. Phys. Lett. 103(16), 162412 (2013)

[3] J. Scola, W. Noun, E. Popova, A. Fouchet, Y. Dumont, N. Keller, P. Lejay, I. Sheikin, A. Demuer, and A. Pautrat, Spin reorientation induced by a very high magnetic field in domain-structured YFeO₃ films: Emergence of perpendicular anisotropy, Phys. Rev. B 81(17), 174409 (2010)

[4] X. Lin, J. Jiang, Z. Jin, D. Wang, Z. Tian, J. Han, Z. Cheng, and G. Ma, Terahertz probes of magnetic field induced spin reorientation in YFeO₃ single crystal, Appl. Phys. Lett. 106(9), 092403 (2015)

[5] V. D. Buchel’nikov, N. K. Dan’shin, L. T. Tsymbal, and V. G. Shavrov, Magnetoacoustics of rare-earth orthoferrites, Phys. Uspekhi 39(6), 547 (1996)

[6] S. J. Yuan, W. Ren, F. Hong, Y. B. Wang, J. C. Zhang, L. Bellaiche, S. X. Cao, and G. Cao, Spin switching and magnetization reversal in single-crystal NdFeO₃, Phys. Rev. B 87(18), 184405 (2013)

[7] L. T. Tsymbal, Y. B. Bazaliy, G. N. Kakazei, F. Palomares, and P. E. Wigen, Magnetic hysteresis in ErFeO₃ near the low temperature erbium ordering transition, Magn. IEEE Trans. On 44(11), 2933 (2008)

[8] S. Cao, H. Zhao, B. Kang, J. Zhang, and W. Ren, Temperature induced spin switching in SmFeO₃ single crystal, Sci. Rep. 4(1), 5960 (2015)

[9] G. Wang, W. Zhao, Y. Cao, B. Kang, J. Zhang, W. Ren, and S. Cao, Temperature-induced spin reorientation and magnetization jump of rare-earth orthoferrite Ho_0.5Pr_0.5FeO₃ single crystal, J. Alloys Compd. 674, 300 (2016)

[10] G. Deng, P. Guo, W. Ren, S. Cao, H. E. Maynard-Casely, M. Avdeev, and G. J. McIntyre, The magnetic structures and transitions of a potential multiferroic orthoferrite Er- FeO₃, J. Appl. Phys. 117(16), 164105 (2015)

[11] R. V. Mikhaylovskiy, T. J. Huisman, R. V. Pisarev, T. Rasing, and A. V. Kimel, Selective excitation of terahertz magnetic and electric dipoles in Er³⁺ ions by femtosecond laser pulses in ErFeO₃, Phys. Rev. Lett. 118(1), 017205 (2017)

[12] R. V. Mikhaylovskiy, E. Hendry, V. V. Kruglyak, R. V. Pisarev, T. Rasing, and A. V. Kimel, Terahertz emission spectroscopy of laser-induced spin dynamics in TmFeO₃ and ErFeO₃ Orthoferrites, Phys. Rev. B 90(18), 184405 (2014)

[13] R. Zhou, Z. Jin, G. Li, G. Ma, Z. Cheng, and X. Wang, Terahertz magnetic field induced coherent spin precession in YFeO₃, Appl. Phys. Lett. 100(6), 061102 (2012)

[14] M. K. Singh, H. M. Jang, H. C. Gupta, and R. S. Katiyar, Polarized Raman scattering and lattice eigenmodes of antiferromagnetic NdFeO₃, J. Raman Spectrosc. 39(7), 842 (2008)

[15] H. C. Gupta, M. Kumar Singh, and L. M. Tiwari, Lattice dynamic investigation of Raman and infrared wavenumbers at the zone center of orthorhombic RFeO₃ (R= Tb, Dy, Ho, Er, Tm) Perovskites, J. Raman Spectrosc. 33(1), 67 (2002)

[16] N. Koshizuka and S. Ushioda, Inelastic-light-scattering study of magnon softening in ErFeO₃, Phys. Rev. B 22(11), 5394 (1980)

[17] S. T. Zhang, Y. Zhang, M. H. Lu, C. L. Du, Y. F. Chen, Z. G. Liu, Y. Y. Zhu, N. B. Ming, and X. Q. Pan, Substitution-induced phase transition and enhanced multiferroic properties of Bi_1–xLa_xFeO₃ ceramics, Appl. Phys. Lett. 88(16), 162901 (2006)

[18] A. V. Kimel, A. Kirilyuk, A. Tsvetkov, R. V. Pisarev, and T. Rasing, Laser-induced ultrafast spin reorientation in the antiferromagnet TmFeO₃, Nature 429(6994), 850 (2004)

[19] M. Udagawa, K. Kohn, N. Koshizuka, T. Tsushima, and K. Tsushima, Influence of magnetic ordering on the phonon Raman spectra in YCrO₃ and GdCrO₃, Solid State Commun. 16(6), 779 (1975)

RIGHTS & PERMISSIONS

Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature