Within Lie algebraic model, the vibrational chaotic dynamics in triatomic molecules are studied. The molecules of H2S, NO2, and O3 are sampled to explore the dynamical differences between the local and normal mode molecules. The comprehensive effects of the local and normal mode vibrations, resonances and chaos on the dynamical entanglement are studied. The results demonstrate that the resonances as well as chaos can promote the evolution of dynamical entanglement.
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