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  • RESEARCH ARTICLE
    Mingle Guan, Zheng Zhang, Weihua Zhu, Yuhang Gao, Sumei Wang, Xin Li
    Frontiers of Materials Science, 2024, 18(3): 240696. https://doi.org/10.1007/s11706-024-0696-6

    Flexible sensors with high sensitivity and stability are essential components of electronic skin, applicable to detecting human movement, monitoring physiological health, preventing diseases, and other domains. In this study, we utilized a straightforward and efficient femtosecond laser direct writing technique using phenolic resin (PR) as a carbon precursor to produce high-quality laser-induced graphene (LIG) characterized by high crystallinity and low defect density. The fabricated LIG underwent comprehensive characterization using SEM, Raman spectroscopy, XPS, and XRD. Subsequently, we developed strain sensors with a hexagonal honeycomb pattern and temperature sensors with a line pattern based on PR-derived LIG. The strain sensor exhibited an outstanding measurement factor of 4.16 × 104 with a rapid response time of 32 ms, which is applied to detect various movements like finger movements and human pulse. Meanwhile, the temperature sensor demonstrated a sensitivity of 1.49%/°C with a linear response range of 20–50 °C. The PR-derived LIG shows promising potential for applications in human physiological health monitoring and other advanced wearable technologies.

  • RESEARCH ARTICLE
    Zeqin Cui, Qifeng Hu, Jianzhong Wang, Lei Zhou, Xiaohu Hao, Wenxian Wang, Weiguo Li, Weili Cheng, Cheng Chang
    Frontiers of Materials Science, 2024, 18(3): 240699. https://doi.org/10.1007/s11706-024-0699-3

    Zinc-based composites represent promising materials for orthopedic implants owing to their adjustable degradation rates and excellent biocompatibility. In this study, a series of Zn–10Mg–xHA (x = 0–5 wt.%) composites with the core–shell structure were prepared through spark plasma sintering, and their microstructural, mechanical, and in vitro properties were systematically evaluated. Results showed that the doped hydroxyapatite (HA) is concentrated at the outer edge of the MgZn2 shell layer. The compression strength of the Zn‒10Mg‒HA composite gradually decreased with the increase of the HA content, while its corrosion rate decreased initially and then increased. The corrosion resistance of the composite with the addition of 1 wt.% HA was improved compared to that of Zn–10Mg–0HA. However, the further increase of the HA content beyond 1 wt.% resulted in a faster degradation of the composite. Moreover, the Zn–10Mg–1HA composite significantly enhanced the activity of MC3T3-E1 osteoblasts. Based on such findings, it is revealed that the composite containing 1 wt.% HA exhibits superior overall properties and is anticipated to serve as a promising candidate for bone implant materials.

  • RESEARCH ARTICLE
    Mahwash Mahar Gul, Khuram Shahzad Ahmad, Andrew Guy Thomas, Mohamed A. Habila
    Frontiers of Materials Science, 2024, 18(3): 240695. https://doi.org/10.1007/s11706-024-0695-7

    This study focuses on the synthesis and characterization of a thin film comprising of trimetallic sulphide, Cu2S:ZnS:NiS2. The fabrication process involved the utilization of diethyldithiocarbamate as a sulfur source, employing physical vapor deposition. A range of analytical techniques were employed to elucidate the material’s structure, morphology, and optical characteristics. The thin film exhibited a well-defined crystalline structure with an average crystallite size of 33 nm. X-ray photoelectron spectroscopy provided distinct core level peaks associated with Cu 2p, Zn 2p, Ni 2p, and S 2p. The electrochemical properties were assessed through voltammetry measurements, which demonstrated an impressive specific capacitive of 797 F·g−1. The thin film demonstrated remarkable stability over multiple cycles, establishing it as a highly promising candidate for diverse energy storage applications. In addition, comprehensive investigations were carried out to assess the photocatalytic performance of the fabricated material, particularly its efficacy in the degradation of diverse environmental pollutants. These notable findings emphasize the versatility of trimetal sulphide thin films, expanding their potential beyond energy storage and opening avenues for further research and technological advancements in fields including photocatalysis and beyond.

  • RESEARCH ARTICLE
    Yanzhuang Jiang, Qian Yang, Lin Zhang, Liyan Yu, Na Song, Lina Sui, Qingli Wei, Lifeng Dong
    Frontiers of Materials Science, 2024, 18(3): 240692. https://doi.org/10.1007/s11706-024-0692-x

    MIL-101(Cr) has a special pore cage structure that provides broad channels for the transport of water molecules in the reverse osmosis (RO) water separation and purification. Combining MIL-101(Cr) with Fe3O4 nanoparticles forms a water transport intermediate layer between the polyamide separation membrane and the polysulfone support base under an external magnetic field. MIL-101(Cr) is stable in both water and air while resistant to high temperature. With the introduction of 0.003 wt.% MIL-101(Cr)/Fe3O4, the water flux increased by 93.31% to 6.65 L·m−2·h−1·bar−1 without sacrificing the NaCl rejection of 95.88%. The MIL-101(Cr)/Fe3O4 multilayer membrane also demonstrated certain anti-pollution properties and excellent stability in a 72-h test. Therefore, the construction of a MIL-101(Cr)/Fe3O4 interlayer can effectively improve the permeability of RO composite membranes.

  • RESEARCH ARTICLE
    Wenshuang Wang, Xingya Pan, Xinxin Zhang, Minglin Wang, Zijia Wang, Lingzhi Feng, Xiaolei Wang, Kongyin Zhao
    Frontiers of Materials Science, 2024, 18(3): 240693. https://doi.org/10.1007/s11706-024-0693-9

    Combining molecular imprinting technique with titanium dioxide (TiO2) photocatalysis technique can improve the degradation ability and selectivity of TiO2 nanoparticles towards pollutants. In this work, methyl orange-imprinted polysiloxane particles (MIPs) were synthesized using TiO2 as matrix and silane as functional monomers. The adsorption capacity (Qe) of MIPs was 20.48 mg·g−1, while the imprinting efficiency (IE) was 3.4. Such MIPs exhibited stable imprinting efficiencies and adsorption efficiencies towards methyl orange (MO) in the multi-cycle stability test. Photocatalytic degradation performances of both MIPs and non-imprinted polysiloxane particles (NIPs) were investigated. Compared with NIPs, MIPs exhibited better photocatalytic degradation performance towards MO, with the degradation efficiency of 98.8% in 12 min and the apparent rate constant (Kobs) of 0.077 min−1. The interaction between silane and MO was also studied through molecular dynamics simulation. This work provides new insights into the use of silane for the synthesis of MIPs as well as the molecular imprinting technique for applications in the field of TiO2 photocatalysis.

  • RESEARCH ARTICLE
    Mengdan Jia, Mei-Chen Lin, Hai-Tao Ren, Bing-Chiuan Shiu, Ching-Wen Lou, Zhi-Ke Wang, Li-Yan Liu, Ting-Ting Li
    Frontiers of Materials Science, 2024, 18(3): 240690. https://doi.org/10.1007/s11706-024-0690-z

    The absorption of high-viscosity oil by traditional oil absorbing materials has always been a challenge. So there is an urgent need to solve the problem of slow absorption of high-viscosity oil. In this work, an emulsion composed of polydimethylsiloxane (PDMS), carbon black (CB) and waterborne polyurethane (solid content 40%) was sprayed on the melamine foam (MF). After volatilization of organic solvents, the photothermal material CB was fixed on the MF framework, making it photothermal. By raising the temperature of the modified foam to accelerate the internal thermal movement of high-viscosity oil molecules around the foam, intermolecular forces are reduced, thereby accelerating the separation process. The absorption capacity of this modified MF towards organic solvents and oil is up to 79 times its own weight. In addition, the mechanical properties of the modified foam are improved to a certain extent, more conducive to the continuous oil–water separation. This photothermal absorption material provides ideas for the rapid removal of high-viscosity oil, heavy oil, etc.

  • RESEARCH ARTICLE
    Xiaoqing Jin, Yae Qi, Yongyao Xia
    Frontiers of Materials Science, 2024, 18(3): 240694. https://doi.org/10.1007/s11706-024-0694-8

    Aqueous Zn//MnO2 rechargeable zinc-ion batteries (ZIBs) possess potential applications in electrochemical energy storage due to their safety, low cost, and environmental friendliness. However, manganese dioxide as the cathode material has poor cycle stability and low conductivity. In this work, the SnO2@K-MnO2 (SMO) composite was prepared using the hydrothermal method followed by the treatment with SnCl2 sensitization, and its electrochemical characteristics were examined using SMO as the cathode material for ZIBs. The reversible specific capacity reaches 298.2 mA·h·g−1 at 0.5 A·g−1, and an excellent capacity retention of 86% is realized after 200 cycles, together with a high discharge capacity of 105 mA·h·g−1 at 10 A·g−1 and a long-term cycling life of over 8000 cycles with no apparent capacity fade. This cathode exhibits a long cycle life up to 2000 cycles at 2 A·g−1 with the mass loading of 5 mg·cm−2, and the battery maintains the capacity of 80%. The reversible co-embedding mechanism of H+/Zn2+ in such a Zn//SMO battery was confirmed by XRD and SEM during the charge/discharge process. This work can enlighten and promote the development of advanced cathode materials for ZIBs.

  • REVIEW ARTICLE
    Yufei Wang, Dandan Hou, Hui Zhao, Xue Geng, Xin Wu, Gaobiao Li, Fei Sha, Zengguo Feng, Zongjian Liu, Lin Ye
    Frontiers of Materials Science, 2024, 18(3): 240691. https://doi.org/10.1007/s11706-024-0691-y

    Diabetic foot ulcer (DFU) often evolves into chronic wounds that resist healing over an extended period, sometimes necessitating amputation in severe cases. Traditional wound management approaches generally fail to control these chronic sores successfully. Thus, it arouses a huge demand in clinic for a novel wound dressing to treat DFU effectively. Hydrogel as an ideal delivery system exhibits excellent loading capacity and sustainable release behavior. It also boasts tunable physical and chemical properties adaptable to diverse biomedical scenarios, making it a suitable material for fabricating functional wound dressings to treat DFU. The hydrogel dressings are classified into hemostatic, antibacterial and anti-inflammatory, and healing-promoting hydrogel dressings by associating the pathogenesis of DFU in this paper. The design and fabrication strategies for the dressings, as well as their therapeutic effects in treating DFU, are extensively reviewed. Additionally, this paper highlights future perspectives of multifunctional hydrogel dressings in DFU treatment. This review aims to provide valuable references for material scientists to design and develop hydrogel wound dressings with enhanced capabilities for DFU treatment, and to further translate them into the clinic in the future.

  • RESEARCH ARTICLE
    Dandan Hu, Linxiu Sui, Jinjin Shi, Dongfeng Li, Yuxuan Zhang, Yimeng Li, Bingbing Hu, Xiaoya Yuan
    Frontiers of Materials Science, 2024, 18(2): 240687. https://doi.org/10.1007/s11706-024-0687-7

    In this work, C@Fe3O4 composites were prepared through a typical template method with emulsified asphalt as carbon source, ammonium ferric citrate as transition metal oxide precursor, and NaCl as template. As an anode for lithium-ion batteries, the optimized C@Fe3O4-1:2 composite exhibits an excellent reversible capacity of 856.6 mA·h·g−1 after 100 cycles at 0.1 A·g−1 and a high capacity of 531.1 mA·h·g−1 after 300 cycles at 1 A·g−1, much better than those of bulk carbon/Fe3O4 prepared without NaCl. Such remarkable cycling performance mainly benefits from its well-designed structure: Fe3O4 nanoparticles generated from ammonium ferric citrate during pyrolysis are homogenously encapsulated in graphitized and in-plane porous carbon nanocages derived from petroleum asphalt. The carbon nanocages not only improve the conductivity of Fe3O4, but also suppress the volume expansion of Fe3O4 effectively during the charge‒discharge cycle, thus delivering a robust electrochemical stability. This work realizes the high value-added utilization of low-cost petroleum asphalt, and can be extended to application of other transition-metal oxides-based anodes.

  • RESEARCH ARTICLE
    Mingjun Pang, Zhaoyang Song, Miaomiao Mao, Shang Jiang, Ruxia Zhang, Runwei Wang, Jianguo Zhao
    Frontiers of Materials Science, 2024, 18(2): 240688. https://doi.org/10.1007/s11706-024-0688-6

    In situ carbon-coated Co3Se4/CoSe2 (CoxSey) nanoparticles (NPs) attached on three-dimensional (3D) reduced graphene oxide (rGO) sheets were skillfully developed in this work, which involved the environment-friendly hydrothermal method, freeze drying, and selenide calcination. Within the structure, the glucose-derived carbon layer exhibited significantly homogeneous dispersion under an argon environment. This structure not only has enhanced stability, but also can effectively mitigate the volume swell of CoxSey particles. The resulted Co3Se4/CoSe2@C/rGO (CSe@C/rGO) exhibited a specific surface area (SSA) of 240.9 m2·g−1, offering more electrochemically active sites for the storage of energy related to lithium ions. The rGO matrix held exceptional flexibility and functional structural rigidity, facilitating the swift ion intercalation and ensuring the high conductivity and recyclability of the structure. When applied to anodes designed for lithium-ion batteries (LIBs), this material demonstrated distinguished rate and ultra-high reversible capacity (872.98 mA·h·g−1 at 0.5 A·g−1). Meanwhile, its capacity retention reached 119.5% after 500 cycles at 2 A·g−1, with a coulombic efficiency of 100%. This work potentially paves the way for generating fast and powerful metal selenide anodes and initiating LIBs with good performance.

  • RESEARCH ARTICLE
    Jie Meng, Hongmei Liu, Sainan Zhang, Baogui Ye, Min Feng, Daoai Wang
    Frontiers of Materials Science, 2024, 18(2): 240686. https://doi.org/10.1007/s11706-024-0686-8

    The solar-to-hydrogen conversion using the photoelectrochemical (PEC) method is a practical approach to producing clean energy. However, it relies on the availability of photocatalyst materials. In this work, a novel photocatalyst comprising molybdenum telluride quantum dots (MoTe2 QDs)-modified titanium dioxide nanorods (TiO2 NRs) was prepared for the enhancement of the PEC water splitting performance after combination with a Al2O3 layer using the atomic layer deposition (ALD) technique. MoTe2 QDs were initially prepared, and then they were loaded onto TiO2 NRs using a warm water bath-based heating method. After a layer of Al2O3 was deposited onto resulted TiO2 NRs/MoTe2 QDs, the composite TiO2 NRs/MoTe2 QDs/Al2O3 was finally obtained. Under simulated sunlight (100 mW·cm−2), such a composite exhibited a maximum photocurrent density of 2.25 mA·cm−2 at 1.23 V (versus RHE) and an incident photon-to-electron conversion efficiency of 69.88% at 380 nm, which are 4.33 and 6.66 times those of pure TiO2 NRs, respectively. Therefore, the composite photocatalyst fabricated in this work may have promising application in the field of PEC water splitting, solar cells and other photocatalytic devices.

  • RESEARCH ARTICLE
    Junhai Wang, Huaqiu Huang, Chen Chen, Jiandong Zheng, Yaxian Cao, Sang Woo Joo, Jiarui Huang
    Frontiers of Materials Science, 2024, 18(2): 240683. https://doi.org/10.1007/s11706-024-0683-y

    There are still many challenges including low conductivity of cathodes, shuttle effect of polysulfides, and significant volume change of sulfur during cycling to be solved before practical applications of lithium–sulfur (Li–S) batteries. In this work, (FeO)2FeBO3 nanoparticles (NPs) anchored on interconnected nitrogen-doped carbon nanosheets (NCNs) were synthesized, serving as sulfur carriers for Li–S batteries to solve such issues. NCNs have the cross-linked network structure, which possess good electrical conductivity, large specific surface area, and abundant micropores and mesopores, enabling the cathode to be well infiltrated and permeated by the electrolyte, ensuring the rapid electron/ion transfer, and alleviating the volume expansion during the electrochemical reaction. In addition, polar (FeO)2FeBO3 can enhance the adsorption of polysulfides, effectively alleviating the polysulfide shuttle effect. Under a current density of 1.0 A·g−1, the initial discharging and charging specific capacities of the (FeO)2FeBO3@NCNs-2/S electrode were obtained to be 1113.2 and 1098.3 mA·h·g−1, respectively. After 1000 cycles, its capacity maintained at 436.8 mA·h·g−1, displaying a decay rate of 0.08% per cycle. Therefore, combining NCNs with (FeO)2FeBO3 NPs is conducive to the performance improvement of Li–S batteries.

  • RESEARCH ARTICLE
    Xinghua Liang, Pengcheng Shen, Lingxiao Lan, Yunmei Qin, Ge Yan, Meihong Huang, Xuanan Lu, Qiankun Hun, Yujiang Wang, Jixuan Wang
    Frontiers of Materials Science, 2024, 18(2): 240685. https://doi.org/10.1007/s11706-024-0685-9

    Electrolyte interface resistance and low ionic conductivity are essential issues for commercializing solid-state lithium metal batteries (SSLMBs). This work details the fabrication of a double-layer solid composite electrolyte (DLSCE) for SSLMBs. The composite comprises poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF‒HFP) and poly(methyl methacrylate) (PMMA) combined with 10 wt.% of Li6.4La3Zr1.4Ta0.6O12 (LLZTO), synthesized through an ultraviolet curing process. The ionic conductivity of the DLSCE (2.6 × 10−4 S·cm−1) at room temperature is the high lithium-ion transference number (0.57), and the tensile strength is 17.8 MPa. When this DLSCE was assembled, the resulted LFP/DLSCE/Li battery exhibited excellent rate performance, with the discharge specific capacities of 162.4, 146.9, 93.6, and 64.0 mA·h·g−1 at 0.1, 0.2, 0.5, and 1 C, respectively. Furthermore, the DLSCE demonstrates remarkable stability with lithium metal batteries, facilitating the stable operation of a Li/Li symmetric battery for over 200 h at both 0.1 and 0.2 mA·cm−2. Notably, the formation of lithium dendrites is also effectively inhibited during cycling. This work provides a novel design strategy and preparation method for solid composite electrolytes.

  • REVIEW ARTICLE
    Chaiqiong Guo, Xuhong He, Xuanyu Liu, Yuhui Wang, Yan Wei, Ziwei Liang, Di Huang
    Frontiers of Materials Science, 2024, 18(2): 240689. https://doi.org/10.1007/s11706-024-0689-5

    Black phosphorus (BP), a novel two-dimensional material, exhibits remarkable photoelectric characteristics, ultrahigh photothermal conversion efficiency, substantial specific surface area, high carrier mobility, and tunable band gap properties. These attributes have positioned it as a promising candidate in domains such as energy, medicine, and the environment. Nonetheless, its vulnerability to light, oxygen, and water can lead to rapid degradation and loss of crystallinity, thereby limiting its synthesis, preservation, and application. Moreover, BP has demonstrated cytotoxic tendencies, substantially constraining its viability in the realm of biomedicine. Consequently, the imperative for surface modification arises to bolster its stability and biocompatibility, while concurrently expanding its utility spectrum. Biological macromolecules, integral components of living organisms, proffer innate advantages over chemical agents and polymers for the purpose of the BP modifications. This review comprehensively surveys the advancements in utilizing biological macromolecules for the modifications of BP. In doing so, it aims to pave the way for enhanced stability, biocompatibility, and diversified applications of this material.

  • RESEARCH ARTICLE
    Huaying Hao, Lihong Sun, Jiaxuan Chen, Jun Liang
    Frontiers of Materials Science, 2024, 18(2): 240682. https://doi.org/10.1007/s11706-024-0682-z

    The in vitro expansion of stem cells is important for their application in different life science fields such as cellular tissue and organ repair. An objective of this paper was to achieve static cell culture in vitro through peptide hydrogel-supported microspheres (MSs). The peptides, with their gel-forming properties, microstructures, and mechanical strengths characterized, were found to have good support for the MSs and to be injectable. The internal structures of poly(L-lactic acid) microspheres (PLLA-MSs) and polystyrene microspheres (PS-MSs) made in the laboratory were observed and statistically analyzed in terms of particle size and pore size, following which the co-cultured MSs with cells were found to have good cell adhesion. In addition, three-dimensional (3D) culturing of cells was performed on the peptide and microcarrier composite scaffolds to measure cell viability and cell proliferation. The results showed that the peptides could be stimulated by the culture medium to self-assembly form a 3D fiber network structure. Under the peptide-MS composite scaffold-based cell culture system, further enhancement of the cell culture effect was measured. The peptide-MS composite scaffolds have great potential for the application in 3D cell culture and in vitro cell expansion.