RESEARCH ARTICLE

Development of oxide based diffusion barrier coatings for CFC components applied in modern furnaces

  • Kirsten BOBZIN ,
  • Lidong ZHAO ,
  • Thomas SCHLAEFER ,
  • Thomas WARDA
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  • Surface Engineering Institute, RWTH Aachen University, 52072 Aachen, Germany

Received date: 20 Jun 2011

Accepted date: 03 Aug 2011

Published date: 05 Dec 2011

Copyright

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg

Abstract

Carbon fibre reinforced carbon (CFC) materials show a high potential for usage in furnaces as sample carriers for example, which is due to their excellent thermal stability compared to steel carriers. Only their tendency to react with different metals at high temperatures by C-diffusion is a disadvantage, which can be solved by application of diffusion barriers. In order to enable the utilization of CFC-carriers for e.g. brazing furnaces, within the frame of this study thermally sprayed diffusion barrier coatings were developed. Coatings of mullite and ZrO2-7%βY2O3 (YSZ) were prepared by air plasma spraying (APS). The coatings were investigated in terms of their microstructure and thermal shock behaviour. In order to prove the suitability of the coatings for the application in brazing furnaces, the wettability of the coating surfaces by a Ni-based brazing alloy was investigated. The results showed that both mullite and YSZ could be deposited on CFC substrates with a bond coat of W or SiC. Both coatings exhibited good thermal shock behaviour and an excellent non-wetting behaviour against the used Ni-based braze alloy.

Cite this article

Kirsten BOBZIN , Lidong ZHAO , Thomas SCHLAEFER , Thomas WARDA . Development of oxide based diffusion barrier coatings for CFC components applied in modern furnaces[J]. Frontiers of Mechanical Engineering, 2011 , 6(4) : 392 -396 . DOI: 10.1007/s11465-011-0241-z

Acknowlegdements

This work was funded with budget funds of the Federal Ministries of Economics and Technology (BMWi) via the German Federation of Industrial Research Associations “Otto von Guericke” e.V. (AiF) (IGF-Nr.: 14.880 N/DVS-Nr.: 2.050) and supported by the Research Association of the German Welding Society (DVS). The authors would like to thank all parties involved for the funding and the support.
1
Klein J. Carbon-carbon composites. Advanced Materials & Processes, 1986, 130(5): 64–68

2
Buckley J D. Carbon-carbon an overview. American Ceramic Bulletin, 1988, 67(2): 364–368

3
Sheehan J E. Oxidation protection for carbon fiber composites. Carbon, 1989, 27(5): 709–715

DOI

4
Dhami T L, Bahl O P, Awasthy B R. Oxidation-resistant carbon-carbon composites up to 1700°C. Carbon, 1995, 33(4): 479–490

DOI

5
Kobayashi K, Maeda K, Sano H, Uchiyama Y. Formation and oxidation resistance of the coating formed on carbon materials composed of B4C-SiC powders. Carbon, 1995, 33(4): 397–403

DOI

6
Chakraborty N, Ficher W, Gupta A, Basu D. Performance of conventional CSZP-based ceramic coating on oxidation of carbon-carbon composites. Surface and Coatings Technology, 2006, 201(3-4): 1152–1159

DOI

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