Research on the theory and application of adsorbed natural gas used in new energy vehicles: A review

Abstract

Natural gas, whose primary constituent is methane, has been considered a convincing alternative for the growth of the energy supply worldwide. Adsorbed natural gas (ANG), the most promising methane storage method, has been an active field of study in the past two decades. ANG constitutes a safe and low-cost way to store methane for natural gas vehicles at an acceptable energy density while working at substantially low pressures (3.5–4.0 MPa), allowing for conformable store tank. This work serves to review the state-of-the-art development reported in the scientific literature on adsorbents, adsorption theories, ANG conformable tanks, and related technologies on ANG vehicles. Patent literature has also been searched and discussed. The review aims at illustrating both achievements and problems of the ANG technologies-based vehicles, as well as forecasting the development trends and critical issues to be resolved of these technologies.

Key words： adsorbed natural gas (ANG); adsorbent; adsorption theory; conformable tank; natural gas vehicles (NGVs)

Acknowledgments

The authors wish to thank Southern California Gas Company for funding the project that is related to this study. The authors also thank Professor Peter Pfeifer, Chairman of the Department of Physics and Astronomy of University of Missouri, for permitting to use some data generated from the ANG research project.

References

1 Wang L, Gardeler H, Gmehling J. Model and experimental data research of natural gas storage for vehicular usage. Separation and Purification Technology, 1997, 12(1): 35–41

2 EIA. U.S. Annual Energy Outlook 2014. 2014

3 NaturalGas.org. Natural Gas and the Environment. 2011

4 Menon V C, Komarneni S. Porous adsorbents for vehicular natural gas storage: A review. Journal of Porous Materials, 1998, 5(1): 43–58

5 Mason J A, Veenstra M, Long J R. Evaluating metal-organic frameworks for natural gas storage. Chemical Science (Cambridge), 2014, 5(1): 32–51

6 Wegrzyn J, Wiesmann H, Lee T. Low pressure storage of natural gas on activated carbon. In: Proceedings of 1992 Annual Automotive Technology Development Contractors’ Coordination meeting (ATD/CCM). Dearborn, 1992

7 Quinn D F, MacDonald J A, Sosin K. Microporous carbons as adsorbents for methane storage. U.S. Department of Energy Technical Report. 1994

8 Biloe S, Goetz V, Mauran S. Characterization of adsorbent composite blocks for methane storage. Carbon, 2001, 39(11): 1653–1662

9 Pupier O, Goetz V, Fiscal R. Effect of cycling operations on an adsorbed natural gas storage. Chemical Engineering and Processing: Process Intensification, 2005, 44(1): 71–79

10 Yang X D, Zheng Q R, Gu A Z, et al . Experimental studies of the performance of adsorbed natural gas storage system during discharge. Applied Thermal Engineering, 2005, 25(4): 591–601

11 Celzard A, Perrin A, Albiniak A, The effect of wetting on pore texture and methane storage ability of NaOH activated anthracite. Fuel, 2007, 86(1–2): 287–293

12 Molina-Sabio M, Almansa C, Rodríguez-Reinoso F. Phosphoric acid activated carbon discs for methane adsorption. Carbon, 2003, 41(11): 2113–2119

13 Bagheri N, Abedi J. Adsorption of methane on corn cobs based activated carbon. Chemical Engineering Research & Design, 2011, 89(10): 2038–2043

14 ARPA- E. U.S. ARPA-E’s MOVE Projects. 2015, http://arpa-e.energy.gov/?q=arpa-e-programs/move

15 Casco M E, Martínez-Escandell M, Gadea-Ramos E, High-pressure methane storage in porous materials: Are carbon materials in the pole position? Chemistry of Materials, 2015, 27(3): 959–964

16 Matranga K R, Myers A L, Glandt E D. Storage of natural gas by adsorption on activated carbon. Chemical Engineering Science, 1992, 47(7): 1569–1579

17 Nitta T, Nozawa M, Kida S. Gas-phase adsorption characteristics of high-surface area carbons activated from meso-carbon micro-beads. Journal of Chemical Engineering of Japan, 1992, 25(2): 176–182

18 Pfeifer P, Ehrburger-Dolle F, Rieker T P, Nearly space-filling fractal networks of carbon nanopores. Physical Review Letters, 2002, 88(11): 115502

19 Pfeifer P, Burressa J W, Wood M B, High-surface-area biocarbons for reversible on-board storage of natural gas and hydrogen. In: Fthenakis V, Dillon A, Savage N, eds. MRS Proceedings. Volume 1041. Cambridge: Cambridge University Press, 2007

20 Firlej L, Roszak S, Kuchta B, Enhanced hydrogen adsorption in boron substituted carbon nanospaces. Journal of Chemical Physics, 2009, 131(16): 164702

21 Zhao Y L, Stoddart J F. Noncovalent functionalization of single-walled carbon nanotubes. Accounts of Chemical Research, 2009, 42(8): 1161–1171

22 Bekyarova E, Murata K, Yudasaka M, Single-wall nanostructured carbon for methane storage. Journal of Physical Chemistry B, 2003, 107(20): 4681–4684

23 Tanaka H, El-Merraoui M, Steele W A, Methane adsorption on single-walled carbon nanotube: A density functional theory model. Chemical Physics Letters, 2002, 352(5–6): 334–341

24 Cao D, Zhang X, Chen J, Optimization of single-walled carbon nanotube arrays for methane storage at room temperature. Journal of Physical Chemistry B, 2003, 107(48): 13286–13292

25 Ganji M D, Mirnejad A, Najafi A. Theoretical investigation of methane adsorption onto boron nitride and carbon nanotubes. Science and Technology of Advanced Materials, 2010, 11(4): 045001

26 Lee J W, Kang H C, Shim W G, Methane adsorption on multi-walled carbon nanotube at (303.15, 313.15, and 323.15) K. Journal of Chemical & Engineering Data, 2006, 51(3): 963–967

27 Thierfelder C, Witte M, Blankenburg S, Methane adsorption on graphene from first principles including dispersion interaction. Surface Science, 2011, 605(7–8): 746–749

28 Carrillo I, Rangel E, Magaña L. Adsorption of carbon dioxide and methane on graphene with a high titanium coverage. Carbon, 2009, 47(11): 2758–2760

29 Wood B C, Bhide S Y, Dutta D, Methane and carbon dioxide adsorption on edge-functionalized graphene: A comparative DFT study. Journal of Chemical Physics, 2012, 137(5): 054702

30 Chae H K, Siberio-Pérez D Y, Kim J, A route to high surface area, porosity and inclusion of large molecules in crystals. Nature, 2004, 427(6974): 523–527

31 Romanos J, Beckner M, Rash T, Nanospace engineering of KOH activated carbon. Nanotechnology, 2012, 23(1): 015401

32 Eddaoudi M, Moler D B, Li H, Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks. Accounts of Chemical Research, 2001, 34(4): 319–330

33 Getman R B, Bae Y S, Wilmer C E, Review and analysis of molecular simulations of methane, hydrogen, and acetylene storage in metal-organic frameworks. Chemical Reviews, 2012, 112(2): 703–723

34 Furukawa H, Ko N, Go Y B, Ultrahigh porosity in metal-organic frameworks. Science, 2010, 329(5990): 424–428

35 Farha O K, Eryazici I, Jeong N C, Metal-organic framework materials with ultrahigh surface areas: Is the sky the limit? Journal of the American Chemical Society, 2012, 134(36): 15016–15021

36 Morse P M. Diatomic molecules according to the wave mechanics. II. Vibrational levels. Physical Review, 1929, 34(1): 57–64

37 Lennard-Jones J E. Cohesion. Proceedings of the Physical Society, 1931, 43(5): 461–482

38 Allinger N L. Conformational analysis. 130. MM2. A hydrocarbon force field utilizing V1 and V2 torsional terms. Journal of the American Chemical Society, 1977, 99(25): 8127–8134

39 Xu Q, Zhong C. A general approach for estimating framework charges in metal-organic frameworks. Journal of Physical Chemistry C, 2010, 114(11): 5035–5042

40 Wilmer C E, Snurr R Q. Towards rapid computational screening of metal-organic frameworks for carbon dioxide capture: Calculation of framework charges via charge equilibration. Chemical Engineering Journal, 2011, 171(3): 775–781

41 Frost H, Düren T, Snurr R Q. Effects of surface area, free volume, and heat of adsorption on hydrogen uptake in metal-organic frameworks. Journal of Physical Chemistry B, 2006, 110(19): 9565–9570

42 Düren T, Snurr R Q. Assessment of isoreticular metal-organic frameworks for adsorption separations: A molecular simulation study of methane/n-butane mixtures. Journal of Physical Chemistry B, 2004, 108(40): 15703–15708

43 Gallo M, Glossman-Mitnik D. Fuel gas storage and separations by metal-organic frameworks: Simulated adsorption isotherms for H2 and CH4 and their equimolar mixture. Journal of Physical Chemistry C, 2009, 113(16): 6634–6642

44 Kaye S S, Dailly A, Yaghi O M, Impact of preparation and handling on the hydrogen storage properties of Zn4O (1, 4-benzenedicarboxylate) 3 (MOF-5). Journal of the American Chemical Society, 2007, 129(46): 14176–14177

45 ARPA- E. MOVE Annual Meeting/NGVTF 2014 Fall Meeting Onboard Storage Projects. 2014

46 Zhang S Y, Talu O, Hayhurst D T. High-pressure adsorption of methane in zeolites NaX, MgX, CaX, SrX and BaX. Journal of Physical Chemistry, 1991, 95(4): 1722–1726

47 Reich R, Ziegler W T, Rogers K A. Adsorption of methane, ethane, and ethylene gases and their binary and ternary mixtures and carbon dioxide on activated carbon at 212–301 K and pressures to 35 atmospheres. Industrial & Engineering Chemistry Process Design and Development, 1980, 19(3): 336–344

48 Ding T F, Ozawa S, Yamazaki T, A generalized treatment of adsorption of methane onto various zeolites. Langmuir, 1988, 4(2): 392–396

49 Abdul-Rehman H, Hasanain M, Loughlin K. Quaternary, ternary, binary, and pure component sorption on zeolites. 1. Light alkanes on Linde S-115 silicalite at moderate to high pressures. Industrial & Engineering Chemistry Research, 1990, 29(7): 1525–1535

50 Talu O, Zhang S Y, Hayhurst D T. Effect of cations on methane adsorption by NaY, MgY, CaY, SrY, and BaY zeolites. Journal of Physical Chemistry, 1993, 97(49): 12894–12898

51 Quinn D F, Holland J A. Carbonaceous Material with High Micropore and Low Macropore Volume and Process for Producing Same. Google Patents. 1991

52 Pfeifer P. Advanced natural gas fuel tank project. In: Proceedings of Natural Gas Vehicle Technology Forum. San Francisco, 2011

53 Raff L, Lorenzen J, McCoy B. Theoretical investigations of gas—Solid interaction phenomena. I. Journal of Chemical Physics, 1967, 46(11): 4265–4274

54 Do D D. Adsorption Analysis. Singapore: World Scientific, 1998

55 Condon J B. Surface Area and Porosity Determinations by Physisorption: Measurements and Theory. Elsevier, 2006

56 Rouquerol J, Rouquerol F, Sing K S W. Adsorption by Powders and Porous Solids: Principles, Methodology and Applications. 2nd ed. London: Academic press, 2014

57 Choudhary V R, Mayadevi S. Adsorption of methane, ethane, ethylene, and carbon dioxide on silicalite-l. Zeolites, 1996, 17(5–6): 501–507

58 Jensen H. Chemical studies on toad poisons. VIII. The dehydrogenation of cinobufagin. Journal of the American Chemical Society, 1935, 57(12): 2733–2734

59 Brunauer S, Emmett P H, Teller E. Adsorption of gases in multimolecular layers. Journal of the American Chemical Society, 1938, 60(2): 309–319

60 Kim S K, Oh B K. Theory of localized and non-localized adsorption. Thin Solid Films, 1968, 2(5–6): 445–456

61 Xi Y, Bažant Z P, Jennings H M. Moisture diffusion in cementitious materials adsorption isotherms. Advanced Cement Based Materials, 1994, 1(6): 248–257

62 Kruk M, Jaroniec M, Bereznitski Y. Adsorption study of porous structure development in carbon blacks. Journal of Colloid and Interface Science, 1996, 182(1): 282–288

63 Sing K S W, Everett D H, Haul R A W, Physical and biophysical chemistry division commission on colloid and surface chemistry including catalysis. Pure and Applied Chemistry, 1985, 57(4): 603–619

64 Kapoor A, Yang R. Correlation of equilibrium adsorption data of condensible vapours on porous adsorbents. Gas Separation & Purification, 1989, 3(4): 187–192

65 Donohue M, Aranovich G. Classification of Gibbs adsorption isotherms. Advances in Colloid and Interface Science, 1998, 76–77: 137–152

66 Li H, Eddaoudi M, Groy T L, Establishing microporosity in open metal-organic frameworks: Gas sorption isotherms for Zn (BDC) (BDC=1, 4-benzenedicarboxylate). Journal of the American Chemical Society, 1998, 120(33): 8571–8572

67 Tan Z, Gubbins K E. Selective adsorption of simple mixtures in slit pores: A model of methane-ethane mixtures in carbon. Journal of Physical Chemistry, 1992, 96(2): 845–854

68 Cracknell R F, Gordon P, Gubbins K E. Influence of pore geometry on the design of microporous materials for methane storage. Journal of Physical Chemistry, 1993, 97(2): 494–499

69 Mota J B, Rodrigues A E, Saatdjian E, Dynamics of natural gas adsorption storage systems employing activated carbon. Carbon, 1997, 35(9): 1259–1270

70 Stella A, Myers A. Adsorption of methane on activated carbon: Comparison of molecular simulation with experiment. In: Proceedings of Annual AIChE Meeting. 1991

71 Sun J, Todd A B, Mark J R. Adsorbed natural gas storage with activated carbon. Preprints of Papers, American Chemical Society, Division of Fuel Chemistry, 1996, 41(1): 246–250

72 Basumatary R, Dutta P, Prasad M, Thermal modeling of activated carbon based adsorptive natural gas storage system. Carbon, 2005, 43(3): 541–549

73 Cracknell R, Gubbins K. A Monte Carlo study of methane adsorption in aluminophosphates and porous carbons. Journal of Molecular Liquids, 1992, 54(4): 239–251

74 Ma Z, Kyotani T, Liu Z, Very high surface area microporous carbon with a three-dimensional nano-array structure: Synthesis and its molecular structure. Chemistry of Materials, 2001, 13(12): 4413–4415

75 Bojan M J, van Slooten R, Steele W. Computer simulation studies of the storage of methane in microporous carbons. Separation Science and Technology, 1992, 27(14): 1837–1856

76 Humble P H, Williams R M, Hayes J C. Finite element modeling of adsorption processes for gas separation and purification. In: Proceedings of Monitoring Research Review (MRR 2009): Ground-Based Nuclear Explosion Monitoring Technologies. Los Alamos: Los Alamos National Laboratory, 2009, 659–666

77 Di J, Liu J. Numerical simulation based on COMSOL multiphysic to steady and non-equilibrium adsorption-mobilization of coalbed methane. Journal of Wuhan Polytechnic University, 2007, 26(3): 60–62 (in Chinese)

78 Sahoo P K, John M, Newalkar B L, Filling characteristics for an activated carbon based adsorbed natural gas storage system. Industrial & Engineering Chemistry Research, 2011, 50(23): 13000–13011

79 Sahoo P K, John M, Newalkar B L, Corrections to “filling characteristics for an activated carbon based adsorbed natural gas storage system”. Industrial & Engineering Chemistry Research, 2014, 53(11): 4522–4523

80 Kunz R, Golde R. High-pressure conformable hydrogen storage for fuel cell vehicles. In: Proceedings of the 2000 Hydrogen Program Review. Alexandria, 2000

81 Xu H, Lin Y. Optimal Design of Conformable Adsorbed Natural Gas Tank. University of Missouri Project Report. 2013

82 APRA- E. Low-Cost Efficient Manufacturing of Pressurized Conformal Compressed Natural Gas Storage Tanks. 2014

83 Lin Y, Xu H. US Patent Application, 2014 0166664 A1, 2014-06-19

84 FuelMaker B. Home-fueling CNG Compressor. 2015