REVIEW ARTICLE

Polymer-nanoinorganic particles composite membranes: a brief overview

  • Zhen-liang XU , 1,2 ,
  • Li-yun YU 2 ,
  • Ling-feng HAN 2
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  • 1. State Key Laboratory of Chemical Engineering, East China University of Science and Technology , Shanghai 200237, China
  • 2. Membrane Science and Engineering R&D Lab, Chemical Engineering Research Center, East China University of Science and Technology, Shanghai 200237, China

Received date: 03 Nov 2008

Accepted date: 12 Feb 2008

Published date: 05 Sep 2009

Copyright

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg

Abstract

Polymer-nanoinorganic particles composite membranes present an interesting approach for improving the physical and chemical, as well as separation properties of polymer membranes, because they possess characteristics of both organic and inorganic membranes such as good permeability, selectivity, mechanical strength, thermal stability and so on. The preparations and structures of polymer-nanoinorganic particles composite membranes and their unique properties are reviewed.

Cite this article

Zhen-liang XU , Li-yun YU , Ling-feng HAN . Polymer-nanoinorganic particles composite membranes: a brief overview[J]. Frontiers of Chemical Science and Engineering, 2009 , 3(3) : 318 -329 . DOI: 10.1007/s11705-009-0199-0

Acknowledgements

The authors acknowledge the National Key Fundamental Research Development Plan (No. 2003CB615705) for giving financial supports in this project.
1
Clarizia G, Algieri C, Drioli E. Filler-polymer combination: a route to modify gas transport properties of a polymeric membrane. Polymer, 2004, 45: 5671-5681

DOI

2
Yang Y N, Wang P. Preparation and characterizations of a new PS/TiO2 hybrid membranes by sol-gel process. Polymer, 2006, 47: 2683-2688

DOI

3
Guizard C, Bac A, Barboiu M, Hovnanian N. Hybrid organic-inorganic membranes with specific transport properties: applications in separation and sensors technologies. Sep Purif Technol, 2001, 25: 167-180

DOI

4
Lu Z H, Liu G J, Duncan S. Poly(2-hydroxyethyl acrylate-co-methyl acrylate)/SiO2/TiO2 hybrid membranes. J Membr Sci, 2003, 221: 113-122

DOI

5
Chiang P C, Whang W T, Tsai M H, Wu S C. Physical and mechanical properties of polyimide/titania hybrid films. Thin Solid Films, 2004, 447-448: 359-364

DOI

6
Taniguchi A, Cakmak M. The suppression of strain induced crystallization in PET through submicron TiO2 particle incorporation. Polymer, 2004, 45: 6647-6654

DOI

7
Peng F, Lu L, Sun H, Wang Y, Wu H, Jiang Z. Correlations between free volume characteristics and pervaporation permeability of novel PVA-GPTMS hybrid membranes. J Membr Sci, 2006, 275: 97-104

DOI

8
Peng F, Lu L, Sun H, Wang Y, Liu J, Jiang Z. Hybrid organic-inorganic membrane: solving the tradeoff between permeability and selectivity. Chem Mater, 2005, 17: 6790-6796

DOI

9
Patel N P, Zielinski J M, Samseth J, Spontak R J. Effects of pressure and nanoparticle functionality on CO2-selective nanocomposites derived from cross-linked poly(ethylene glycol). Macromol Chem Phys, 2004, 205: 2409-2419

DOI

10
Shekhawat D, Luebke D R, Pennline H W. A review of carbon dioxide selective membranes. US Department of Energy, 2003

11
Okui T, Saito Y, Okubo T, Sadakata M. Gas permeation of porous organic/inorganic hybrid membranes. J Sol-Gel Sci Technol, 1995, 5: 127-134

DOI

12
Ai X, Hu X. Study on organic-inorganic hybrid membranes. Huaxue Jinzhan, 2003, 16: 654-659(in Chinese)

13
Genne I, Kuypers S, Leysen R. Effect of the addition of ZrO2 to polysulfone based UF membranes. J Membr Sci, 1996, 113: 343-350

DOI

14
Wara N M, Francis L F, Velamakanni B V. Addition of alumina to cellulose acetate membranes. J Membr Sci, 1995, 104: 43-49

DOI

15
Stephen R, Ranganathaiah C, Varghese S, Joseph K, Thomas S. Gas transport through nano and micro composites of natural rubber (NR) and their blends with carboxylated styrene butadiene rubber (XSBR) latex membranes. Polymer, 2006, 47: 858-870

DOI

16
Mascia L, Zhang Z, Shaw S J. Carbon fibre composites based on polyimide/silica ceramers: aspects of structure-properties relationship. Composites A,1996, 27: 1211-1221

DOI

17
Shi D, Kong Y, Yang J, Du H. Study on transitional metal organic complex-polyimide hybrid material for gas separation membranes. Acta Polym Sin, 2000, 4: 457-461

18
Liu H. Synthesis of TiO2 nanopowder enwrapped by organic membrane with microwave induced plasma method. Huaxue Tongbao, 1997, 10: 44-46

19
Doucoure A, Guizard C, Durand J, Berjoan R, Cot L. Plasma polymerization of fluorinated monomers on mesoporous silica membranes and application to gas permeation. J Membr Sci, 1996, 117: 143-150

DOI

20
Patel N P, Miller A C, Spontak R J. Highly CO2-permeable and selective polymer nanocomposite membranes. Adv Mater, 2003, 15: 729-733

DOI

21
Patel N P, Aberg C M, Sanchez A M, Capracotta M D, Martin J D, Spontak R J. Morphological, mechanical and gas-transport characteristics of cross-linked poly(propylene glycol): homopolymers, nanocomposites and blends. Polymer, 2004, 45: 5941-5950

DOI

22
Nunes S P, Peinenmann K V, Ohlorogge K, Alpers A, Keller M, Pires A T N. Membranes of poly(ether imide) and nanodispersed silica. J Membr Sci, 1999, 157: 219-226

DOI

23
Brzesowsky R H, de With G, van den Cruijsem S, Snijkers-Hendrickx I J M, Wolter W A M, van Lierop J G. Glass strengthening by silica particle reinforced organic-inorganic coatings. J Non-Cryst Solids, 1998, 241: 27-37

DOI

24
Livage J, Sanchez C. Sol-gel chemistry. J Non-Cryst Solids, 1992, 145: 11-19

DOI

25
Kioul A, Mascia L. Compatibility of polyimide-silicate ceramers induced by alkoxysilane silane coupling agents. J Non-Cryst Solids, 1994, 175: 169-186

DOI

26
Smaihi M, Jermoumi T, Marignan J, Noble R D. Organic-inorganic gas separation membranes: preparation and characterization. J Membr Sci, 1996, 116: 211-220

DOI

27
Iwata M, Adachi T, Tomidokoro M, Ohta M, Kobayashi T. Hybrid sol-gel membranes of polyacrylonitrile–tetraethoxysilane composites for gas permselectivity. J Appl Polym Sci, 2003, 88: 1752-1759

DOI

28
Gomes D, Nunes S P, Peinemann K V. Membranes for gas separation based on poly(1-trimetylsilyl-1-propyne)-silica nanocomposites. J Membr Sci, 2005, 246: 13-25

DOI

29
Vollenberg P H T, Heikens D. Particle size dependence of the Young's modulus of filled polymers: 1. preliminary experiments. Polymer, 1989, 30: 1656-1662

DOI

30
Chan C M, Wu J, Li J X, Cheung Y K. Polypropylene/calcium carbonate nanocomposites. Polymer, 2002, 43: 2981-2992

DOI

31
Shelley J S, Mather P T, DeVries K L. Reinforcement and environmental degradation of nylon-6/clay nanocomposites. Polymer, 2001, 42: 5849-5858

DOI

32
Park C I L, Park O O, Lim J G, Kim H J. The fabrication of syndiotactic polystyrene/organophilic clay nanocomposites and their properties. Polymer, 2001, 42: 7465-7475

DOI

33
Jordan J, Jacob K I, Tannenbaum R, Sharaf M A, Jasiuk I. Experimental trends in polymer nanocomposites—a review. Mat Sci Eng A, 2005, 393: 1-11

DOI

34
Reynaud E, Jouen T, Gautheir C, Vigier G. Nanofillers in polymeric matrix: a study on silica reinforced PA6. Polymer, 2001, 42: 8759-8768

DOI

35
Rong M Z, Zhang M Q, Zheng Y X, Zeng H M, Walter R, Friedrich K. Structure-property relationships of irradiation grafted nano-inorganic particle filled polypropylene composites. Polymer, 2001, 42: 167-183

DOI

36
Sheng N, Boyce M C, Parks D M, Rutledge G C, Abes J I, Cohen R E. Multiscale micromechanical modeling of polymer/clay nanocomposites and the effective clay particle. Polymer, 2004, 45: 487-506

DOI

37
Priya L, Jog J P. Poly(vinylidene fluoride)/clay nanocomposites prepared by melt intercalation: crystallization and dynamic mechanical behavior studies. J Polym Sci B: Polym Phys, 2002, 40: 1682-1689

DOI

38
Tortora M, Gorrasi G, Vittoria V, Galli G, Ritrovati S, Chiellini E. Structural characterization and transport properties of organically modified montmorillonite/polyurethane nanocomposites. Polymer, 2002, 43: 6147-6157

DOI

39
Varlot K M, Reynaud E, Vigier G, Varlet J. Mechanical properties of clay-reinforced polyamide. J Polym Sci B: Polym Phys, 2002, 40: 272-283

DOI

40
Arocha P U, Mehler C, Puskas J E, Altstat V. Effect of sample thickness on the mechanical properties of injection-molded polyamide-6 and polyamide-6 clay nanocomposites. Polymer, 2003, 44: 2441-2446

DOI

41
Zoppi R A, das Neves S, Nunes S P. Hybrid films of poly(ethylene oxide-b-amide-6) containing sol-gel silicon or titanium oxide as inorganic fillers: effect of morphology and mechanical properties on gas permeability. Polymer, 2000, 41: 5461-5470

DOI

42
Park C I, Choi W M, Kim M H, Park O O. Thermal and mechanical properties of syndiotactic polystyrene/organoclay nanocomposites with different microstructures. J Polym Sci B: Polym Phys, 2004, 42: 1685-1693

43
Gangopadhyay R, De A. Conducting polymer nanocomposites: a brief overview. Chem Mater, 2000, 12: 608-622

DOI

44
Xiao Y C, Wang K Y, Chung T S, Tan J. Evolution of nano-particle distribution during the fabrication of mixed matrix TiO2-polyimide hollow fiber membranes. Chem Eng Sci, 2006, 61: 6228-6233

DOI

45
Jiang L Y, Chung T S, Cao C, Huang Z, Kulprathipanja S. Fundamental understanding of nano-sized zeolite distribution in the formation of the mixed matrix single- and dual-layer asymmetric hollow fiber membranes. J Membr Sci, 2005, 252: 89-100

DOI

46
Lu Y, Yu S L, Chai B X, Shun X D. Effect of nano-sized Al2O3-particle addition on PVDF ultrafiltration membrane performance. J Membr Sci, 2006, 276: 162-167

DOI

47
Li J F, Xu Z L, Yang H, Yu L Y, Liu M. Effect of TiO2 nanoparticles on the surface morphology and performance of microporous PES membrane. Appl Surf Sci, 2009, 255(9), 4725-4732

DOI

48
Zulfikar M A, Mohammad A W, Hilal N. Preparation and characterization of novel porous PMMA-SiO2 hybrid membranes. Desalination, 2006, 192: 262-270

DOI

49
Merkel T C, Freeman B D, Spontak R J, He Z, Pinnau I, Meakin P, Hill A J. Ultrapermeable, reverse-selective nanocomposite membranes. Science, 2002, 296: 519-522

DOI

50
Moaddeb M, Koros W J. Gas transport properties of thin polymeric membranes in the presence of silicon dioxide particles. J Membr Sci, 1997, 125: 143-163

DOI

51
Hibshman C, Cornelius C J, Marand E. The gas separation effects of annealing polyimide-organosilicate hybrid membranes. J Membr Sci, 2003, 211: 25-40

DOI

52
Higuchi A, Agatsuma T, Uemiya S, Kojima T, Mizoguchi K, Pinnau I, Nagai K, Freeman B D. Preparation and gas permeation of immobilized fullerene membranes. J Appl Polym Sci, 2000, 7: 529-537

DOI

53
Merkel T C, He Z, Pinnau I, Freeman B D, Hill A J, Meakin P. Sorption and transport in poly(2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole-cotetrafluoroethylene) containing nanoscale fumed silica. Macromolecules, 2003, 36: 8406-8484

DOI

54
Winberg P, DeSitter K, Dotremont C, Mullens S, Vankelecom I F J, Maurer F H J. Free volume and interstitial mesopores in silica filled poly(1-trimethylsilyl-1-propyen) nanocomposites. Macromolecules, 2005, 38: 3776-3782

DOI

55
Kim J H, Lee Y M. Gas permeation properties of poly(amide-6-b-ethyleneoxide)-silica hybrid membranes. J Membr Sci, 2001, 193: 209-225

DOI

56
Hu Q, Marand E, Dhingra S, Fritsch D, Wen J, Wilkes G. Poly(amideimide)/TiO2 nano-composite gas separation membranes: fabrication and characterization. J Membr Sci, 1997, 135: 65-79

DOI

57
Cong H L, Radosz M, Towler B F, Shen Y Q. Polymer-inorganic nanocomposite membranes for gas separation. Sep Purif Technol, 2007, 55: 281-291

DOI

58
Lu Y, Yu S L, Chai B X. Preparation of poly(vinylidene fluoride) (pvdf) ultrafiltration membrane modified by nano-sized alumina (Al2O3) and its antifouling research. Polymer, 2005, 46: 7701-7706

DOI

59
Yang Y N, Zhang H X, Wang P, Zheng Q Z, Li J. The influence of nano-sized TiO2 fillers on the morphologies and properties of PSF UF membrane. J Membr Sci, 2007, 288: 231-238

DOI

60
Bae T H, Tak T M. Preparation of TiO2 self-assembled polymeric nanocomposite membranes and examination of their fouling mitigation effects in a membrane bioreactor system. J Membr Sci, 2005, 266: 1-5

DOI

61
Yuan H K, Xu Z L, Shi J H, Ma X H. Perfluorosulfonic acid-tetraethoxysilane/polyacrylonitrile (PFSA-TEOS/PAN) hollow fiber composite membranes prepared for pervaporation dehydration of ethyl acetate-water solutions. J Appl Polym Sci, 2008, 109: 4025-4035

DOI

62
Lang W Z, Xu Z L, Yang H, Tong W. Preparation and characterization of PVDF-PFSA blend hollow fiber UF membrane. J Membr Sci, 2007, 288: 123-131

DOI

63
Aerts P, Greenberg A R, Leysen R, Krantz W B, Reinsch V E, Jacobs P A. The influence of filler concentration on the compaction and filtration properties of zirfon-composite ultrafiltration membranes. Sep Purif Technol, 2001, 22–23: 663-669

DOI

64
Bottino A, Capannelli G, Asti V D. Preparation and properties of novel organic-inorganic porous membranes. Sep Purif Technol, 2001, 22-23: 269-275

DOI

65
Bottino A, Capannelli G, Comite A. Preparation and characterization of novel porous PVDF-ZrO2 composite membranes. Desalination, 2002, 146: 35-40

DOI

66
Lin D J, Chang C L, Huang F M, Cheng L P. Effect of salt additive on the formation of microporous poly(vinylidene fluoride) membranes by phase inversion from LiClO4/water/DMF/PVDF system. Polymer, 2003, 44: 413-422

DOI

67
Yang Y N, Wu J, Zheng Q Z, Chen X S, Zhang H X. The research of rheology and thermodynamics of organic-inorganic hybrid membrane during the membrane formation. J Membr Sci, 2008, 311: 200-207

DOI

68
Bottino A, Capannelli G, Comite A. Preparation and characterization of novel porous PVDF-ZrO2 composite membranes. Desalination, 2002, 146: 35-40

DOI

69
Yang Y N, Wang P, Zheng Q Z. Preparation and properties of polysulfone/TiO2 composite ultrafiltration membranes. J Polym Sci Part B: Polym Phys, 2006, 44: 879-887

DOI

70
Lee H S, Im S J, Kim J H, Kim H J, Kim J P, Min B R. Polyamide thin-film nanofiltration membranes containing TiO2 nanoparticles. Desalination, 2008, 219: 48-56

DOI

71
Chang C L, Chang M S. Preparation of multi-layer silicone/PVDF composite membranes for pervaporation of ethanol aqueous solutions. J Membr Sci, 2004, 238: 117-122

DOI

72
Sairam M, Patil M B, Veerapur R S, Patil S A, Aminabhavi T M. Novel dense poly(vinyl alcohol)-TiO2 mixed matrix membranes for pervaporation separation of water-isopropanol mixtures at 30°C. J Membr Sci, 2006, 281: 95-102

DOI

73
Chen J H, Liu Q L, Fang J, Zhu A M, Zhang Q G. Composite hybrid membrane of chitosan-silica in pervaporation separation of MeOH/DMC mixtures. J Colloid Interf Sci, 2007, 316: 580-588

DOI

74
Veerapur R S, Patil M B, Gudasi K B, Aminabhavi T M. Poly(vinyl alcohol)-zeolite T mixed matrix composite membranes for pervaporation separation of water+ 1,4-dioxane mixtures. Sep Purif Technol. 2008, 58: 377-385

DOI

75
Wang Y B, Yang D, Zheng X H, Jiang Z Y, Li J. Zeolite beta-filled chitosan membrane with low methanol permeability for direct methanol fuel cell. J Power Sources, 2008, 183: 454-463

DOI

76
Navarra M A, Abbati C, Scrosati B. Properties and fuel cell performance of a Nafion-based, sulfated zirconia-added, composite membrane. J Power Sources, 2008, 183: 109-113

DOI

77
Xu T W. Ion exchange membranes: State of their development and perspective. J Membr Sci, 2005, 263: 1-29

DOI

78
Mahendran. Filtration membrane with calcined alpha-alumina particles therein. <patent>United States Patent, US 5914039</patent>

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