New approaches to vibrational spectroscopy of zeolite catalysts: a perspective

  • Russell F Howe
Expand
  • Chemistry Department, University of Aberdeen, Aberdeen 999020, UK
r.howe@abdn.ac.uk

Received date: 29 Feb 2024

Accepted date: 23 Apr 2024

Copyright

2024 Higher Education Press

Abstract

This perspective discusses three alternative techniques which complement conventional infrared spectroscopy for obtaining vibrational information about zeolite catalysts and adsorbed molecules: inelastic neutron scattering, infrared micro-spectroscopy, and two-dimensional infrared spectroscopy. The techniques are illustrated briefly and future prospects for their use discussed.

Cite this article

Russell F Howe . New approaches to vibrational spectroscopy of zeolite catalysts: a perspective[J]. Frontiers of Chemical Science and Engineering, 2024 , 18(11) : 123 . DOI: 10.1007/s11705-024-2474-5

Competing interests

The authors declare that they have no competing interests.

Acknowledgements

The author has been privileged to collaborate with three different research groups using the techniques discussed here: Professors David Lennon (Glasgow) and Stewart Parker (ISIS), Professors Paul Wright (St Andrews) and Gianfelice Cinque and colleagues (Diamond Light Source), Professor Paul Donaldson and colleagues (Central Laser Facility, Rutherford Appleton Laboratory).
1
Bordiga S, Lamberti C, Bonino F, Travert A, Thibault-Starzyk F. Probing zeolites by vibrational spectroscopies. Chemical Society Reviews, 2015, 44(20): 7262–7341

DOI

2
Yu X, Cheng Y, Li Y, Polo-Garzon F, Liu J, Mamontov E, Li M, Lennon D, Parker S F, Ramirez-Cuesta A J. . Neutron scattering studies of heterogeneous catalysis. Chemical Reviews, 2023, 123(13): 8638–8700

DOI

3
Howard J, Waddington T C, Wright C J. Ethylene adsorbed by silver exchanged 13X zeolite, an inelastic neutron scattering study. Chemical Communications, 1975, (19): 775–776

4
Brun T O, Curtiss L A, Iton L E, Kleb R, Newsam J M, Beyerlein R A, Vaughan D E W. Inelastic neutron scattering from tetramethylammonium cations occluded within zeolites. Journal of the American Chemical Society, 1987, 109(13): 4118–4119

DOI

5
Jobic H. Observation of the fundamental bending vibrations of hydroxyl groups in HNa Y zeolite by neutron inelastic scattering. Journal of Catalysis, 1991, 131(1): 289–293

DOI

6
Jacobs W P J H, van Santen R A, Jobic H. Inelastic neutron scattering study of NH, Y zeolites. Journal of the Chemical Society, Faraday Transactions, 1994, 90(8): 1191–1196

DOI

7
Trouw F R, Price D L. Chemical applications of neutron scattering. Annual Review of Physical Chemistry, 1999, 50(1): 571–601

DOI

8
Jobic H. Inelastic scattering of organic molecules in zeolites. Physica B, Condensed Matter, 2000, 276–278: 222–225

DOI

9
Zachariou A, Hawkins A P, Howe R F, Skakle J M S, Barrow N, Collier P, Nye D W, Smith R I, Stenning G B G, Parker S F. . Counting the acid sites in a commercial ZSM-5 zeolite catalyst. ACS Physical Chemistry Au, 2023, 3(1): 74–83

DOI

10
Hawkins A P, Zachariou A, Collier P, Ewings R A, Howe R F, Parker S F, Lennon D. Low-temperature studies of propene oligomerization in ZSM-5 by inelastic neutron scattering spectroscopy. RSC Advances, 2019, 9(33): 18785–18790

DOI

11
Hawkins A P, Zachariou A, Parker S F, Collier P, Barrow N S, Silverwood I P, Howe R F, Lennon D. Effect of steam de-alumination on the interactions of propene with H-ZSM-5 zeolites. RSC Advances, 2020, 10(39): 23136–23147

DOI

12
Hawkins A P, Zachariou A, Parker S F, Collier P, Silverwood I P, Howe R F, Lennon D. Onset of propene oligomerization reactivity in ZSM-5 studied by inelastic neutron scattering spectroscopy. ACS Omega, 2020, 5(14): 7762–7770

DOI

13
Hawkins A P, O’Malley A J, Zachariou A, Collier P, Ewings R A, Silverwood I P, Howe R F, Parker S F, Lennon D. Investigation of the dynamics of 1-octene adsorption at 293 K in a ZSM-5 catalyst by inelastic and quasielastic neutron scattering. Journal of Physical Chemistry C, 2019, 123(1): 417–425

DOI

14
Hawkins A P, Zachariou A, Parker S F, Collier P, Barrow N S, Howe R F, Lennon D. On the transition to gasoline-to-olefins chemistry in the cracking reactions of 1-octene over H-ZSM-5 catalysts. Applied Catalysis A, General, 2023, 667: 119442

DOI

15
Hawkins A P, Zachariou A, Parker S F, Collier P, Howe R F, Lennon D. Studies of propene conversion over H-ZSM-5 demonstrate the importance of propene as an intermediate in methanol-to-hydrocarbons chemistry. Catalysis Science & Technology, 2021, 11(8): 2924–2938

DOI

16
Suwardiyanto S, Howe R F, Gibson E K, Catlow C R A, Hameed A, McGregor J, Collier P, Parker S F, Lennon D. An assessment of hydrocarbon species in the methanol-to-hydrocarbon reaction over a ZSM-5 catalyst. Faraday Discussions, 2017, 197: 447–471

DOI

17
Zachariou A, Hawkins A P, Lennon D, Parker S F, Suwardiyanto S, Matam S K, Catlow C R A, Collier P, Hameed A, McGregor J. . Investigation of ZSM-5 catalysts for dimethylether conversion using inelastic neutron scattering. Applied Catalysis A, General, 2019, 569: 1–7

DOI

18
Zachariou A, Hawkins A P, Collier P, Howe R F, Parker S F, Lennon D. The effect of co-feeding methyl acetate on the H-ZSM5 catalysed methanol-to-hydrocarbons reaction. Topics in Catalysis, 2020, 63(3–4): 370–377

DOI

19
Zachariou A, Hawkins A P, Parker S F, Lennon D, Howe R F. Neutron spectroscopy studies of methanol to hydrocarbons catalysis over ZSM-5. Catalysis Today, 2021, 368: 20–27

DOI

20
Zachariou A, Hawkins A P, Suwardiyanto S, Collier P, Barrow N, Howe R F, Parker S F, Lennon D. New spectroscopic insight into the deactivation of a ZSM-5 methanol-to-hydrocarbons catalyst. ChemCatChem, 2021, 13(11): 2625–2633

DOI

21
Zachariou A, Hawkins A P, Howe R F, Barrow N, Bradley J, Collier P, Lennon D, Parker S F. A spectroscopic paradox: the interaction of methanol with ZSM-5 at room temperature. Topics in Catalysis, 2021, 64(9–12): 672–684

DOI

22
Zachariou A, Hawkins A P, Collier P, Howe R F, Parker S F, Lennon D. Neutron scattering studies of the methanol-to-hydrocarbons reaction. Catalysis Science & Technology, 2023, 13(7): 1976–1990

DOI

23
Howe R F, Suwardiyanto S, Price D J, Castro M, Wright P A, Greenaway A, Frogley M D, Cinque G. Reactions of dimethylether in single crystals of the silicoaluminophosphate STA-7 studied via operando synchrotron infrared microspectroscopy. Topics in Catalysis, 2018, 61(3–4): 199–212

DOI

24
Minova I B, Matam S K, Greenaway A, Catlow C R A, Frogley M D, Cinque G, Wright P A, Howe R F. Elementary steps in the formation of hydrocarbons from surface methoxy groups in HZSM-5 seen by synchrotron infrared micro-spectroscopy. ACS Catalysis, 2019, 9(7): 6564–6570

DOI

25
Minova I B, Matam S K, Greenaway A, Catlow C R A, Frogley M D, Cinque G, Wright P A, Howe R F. Effects of crystal size on methanol to hydrocarbon conversion over single crystals of ZSM-5 studied by synchrotron infrared microspectroscopy. Physical Chemistry Chemical Physics, 2020, 22(34): 18849–18859

DOI

26
Minova I B, Bühl M, Matam S K, Catlow C R A, Frogley M D, Cinque G, Wright P A, Howe R F. Carbene-like reactivity of methoxy groups in a single crystal SAPO-34 MTO catalyst. Catalysis Science & Technology, 2022, 12(7): 2289–2305

DOI

27
Donaldson P M, Howe R F, Hawkins A P, Towrie M, Greetham G M. Ultrafast 2D-IR spectroscopy of intensely optically scattering pelleted solid catalysts. Journal of Chemical Physics, 2023, 158(11): 114201

DOI

28
Donaldson P M. Spectrophotometric concentration analysis without molar absorption coefficients by two-dimensional-infrared and Fourier transform infrared spectroscopy. Analytical Chemistry, 2022, 94(51): 17988–17999

DOI

29
Hawkins A P, Edmeades A E, Hutchison C D M, Towrie M, Howe R F, Greetham G M, Donaldson P M. Laser induced temperature-jump time resolved IR spectroscopy of zeolites. Chemical Science, 2024, 15(10): 3453–3465

DOI

Outlines

/