RESEARCH ARTICLE

The effect of altering crosslinker chemistry during interfacial polymerization on the performance of nanofiltration membranes for desalination, organic, and micropollutants removal

  • Jamilu Usman 1 ,
  • Abdul Waheed , 1 ,
  • Umair Baig 1 ,
  • Isam H. Aljundi , 1,2
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  • 1. Interdisciplinary Research Centre for Membranes and Water Security, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
  • 2. Chemical Engineering Department, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia
abdul.waheed@kfupm.edu.sa
aljundi@kfupm.edu.sa

Received date: 03 May 2023

Accepted date: 12 Jul 2023

Published date: 15 Dec 2023

Copyright

2023 Higher Education Press

Abstract

Chemistry of the polyamide active layer of a desalination membrane is critical in determining both its physical and chemical properties. In this study, we designed and fabricated three novel membranes with different active layers using the crosslinkers: terephthaloyl chloride, isophthaloyl chloride, and trimesoyl chloride. The crosslinkers were reacted with an aqueous solution of an aliphatic tetra-amine. Because these crosslinkers differ in their structures and crosslinking mechanisms during interfacial polymerization, the resultant membranes also possess different structural properties. The water contact angle of the fabricated membranes also varies; the water contact angles of 4A-3P-TPC@PSF/PET, 4A-3P-TMC@PSF/PET, and 4A-3P-IPC@PSF/PET, are 68.9°, 65.6°, and 53.9°, respectively. Similarly, the desalination performance of resultant membranes also showed variations, with 4A-3P-TPC@PSF/PET, 4A-3P-IPC@PSF/PET, and 4A-3P-TMC@PSF/PET having a permeate flux of 17.14, 25.70, and 30.90 L·m−2·h−1, respectively, at 2.5 MPa. The 4A-3P-TPC@PSF/PET membrane exhibited extensive crosslinking with aliphatic linear amine, and cationic dye rhodamine B, MgCl2, and amitriptyline rejection rates of 98.6%, 92.7% and 80.9%, respectively. The 4A-3P-TMC@PSF/PET membrane showed mediocre performance, while 4A-3P-IPC@PSF/PET membrane showed even lower performance, with a 35% rejection of methyl orange dye.

Cite this article

Jamilu Usman , Abdul Waheed , Umair Baig , Isam H. Aljundi . The effect of altering crosslinker chemistry during interfacial polymerization on the performance of nanofiltration membranes for desalination, organic, and micropollutants removal[J]. Frontiers of Chemical Science and Engineering, 2023 , 17(12) : 2025 -2036 . DOI: 10.1007/s11705-023-2356-2

Competing interests

The authors declare that they have no competing interests.

Acknowledgements

The authors gratefully appreciate the support offered by the KFUPM Fund received from Mr. Al-Bin Saleh donated through project MWS-90130027 to the Interdisciplinary Research Center for Membranes and Water Security, King Fahd University of Petroleum and Minerals, Saudi Arabia.

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11705-023-2356-2 and is accessible for authorized users.
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