Frontiers of Chemical Science and Engineering >
Size-controllable synthesis of monodispersed nitrogen-doped carbon nanospheres from polydopamine for high-rate supercapacitors
Received date: 14 Jan 2023
Accepted date: 21 Mar 2023
Published date: 15 Nov 2023
Copyright
Monodispersed nitrogen-doped carbon nanospheres with tunable particle size (100–230 nm) were synthesized via self-polymerization of biochemical dopamine in the presence of hexamethylenetetramine as a buffer and F127 as a size controlling agent. Hexamethylenetetramine can mildly release NH3, which in turn initiates the polymerization reaction of dopamine. The carbon nanospheres obtained exhibited a significant energy storage capability of 265 F·g–1 at 0.5 A·g–1 and high-rate performance of 82% in 6 mol·L–1 KOH (20 A·g–1), which could be attributed to the presence of abundant micro-mesoporous structure, doped nitrogen functional groups and the small particle size. Moreover, the fabricated symmetric supercapacitor device displayed a high stability of 94% after 5000 cycles, revealing the considerable potential of carbon nanospheres as electrode materials for energy storage.
Key words: carbon nanospheres; size-controlled; nitrogen-doped; high-rate; supercapacitors
Ning Zhang , Fu-Cheng Gao , Hong Liu , Feng-Yun Wang , Ru-Liang Zhang , Qing Yu , Lei Liu . Size-controllable synthesis of monodispersed nitrogen-doped carbon nanospheres from polydopamine for high-rate supercapacitors[J]. Frontiers of Chemical Science and Engineering, 2023 , 17(11) : 1788 -1800 . DOI: 10.1007/s11705-023-2326-8
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