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Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites
Received date: 03 Apr 2021
Accepted date: 21 May 2021
Published date: 15 Apr 2022
Copyright
The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process. The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method, and the morphology and lamellar structure were examined carefully. Several properties of mechanical, thermal and tribological responses of epoxy nanocomposites were performed. It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix, and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected. In addition, friction coefficient and wear rate were increased first and then decreased along with the particle content, and showed the lowest values at a mass fraction of 5%. Nevertheless, the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin (EP) nanocomposites. This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites.
Jinian Yang , Xuesong Feng , Shibin Nie , Yuxuan Xu , Zhenyu Li . Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites[J]. Frontiers of Chemical Science and Engineering, 2022 , 16(4) : 484 -497 . DOI: 10.1007/s11705-021-2074-6
1 |
Sasidharan S, Anand A. Epoxy-based hybrid structural composites with nanofillers: a review. Industrial & Engineering Chemistry Research, 2020, 59(28): 12617–12631
|
2 |
Wei H Y, Xia J, Zhou W L, Zhou L S, Hussain G, Li Q, Ostrikov K. Adhesion and cohesion of epoxy-based industrial composite coatings. Composites. Part B, Engineering, 2020, 193: 108035
|
3 |
Chang L, Zhang Z, Ye L, Friedrich K. Tribological properties of epoxy nanocomposites: III. Characteristics of transfer films. Wear, 2007, 262(5): 699–706
|
4 |
Yu J, Zhao W, Wu Y, Wang D, Feng R. Tribological properties of epoxy composite coatings reinforced with functionalized C-BN and H-BN nanofillers. Applied Surface Science, 2018, 434: 1311–1320
|
5 |
Azeez A A, Rhee K Y, Park S J, Hui D. Epoxy clay nanocomposites-processing, properties and applications: a review. Composites. Part B, Engineering, 2013, 45(1): 308–320
|
6 |
Yang J N, Li Z Y, Xu Y X, Nie S B, Liu Y. Effect of nickel phyllosilicate on the morphological structure, thermal properties and wear resistance of epoxy nanocomposites. Journal of Polymer Research, 2020, 27(9): 274
|
7 |
Bazrgari D, Moztarzadeh F, Sabbagh-Alvani A A, Rasoulianboroujeni M, Tahriri M, Tayebi L. Mechanical properties and tribological performance of epoxy/Al2O3 nanocomposite. Ceramics International, 2018, 44(1): 1220–1224
|
8 |
Sakka M M, Antar Z, Elleuch K, Feller J F. Tribological response of an epoxy matrix filled with graphite and/or carbon nanotubes. Friction, 2017, 5(2): 171–182
|
9 |
Kumar A, Bag D S, Tiwari R K, Tripathi D N, Prasad N E. Copper nanoparticles filled epoxy nanocomposites and their mechanical properties. Journal of Polymer Materials, 2016, 33(3): 419–429
|
10 |
Nie S, Jin D, Xu Y, Han C, Dong X, Yang J. Effect of a flower-like nickel phyllosilicate-containing iron on the thermal stability and flame retardancy of epoxy resin. Journal of Materials Research and Technology, 2020, 9(5): 10189–10197
|
11 |
Liu J, Yuen R K K, Hong N, Hu Y. The influence of mesoporous SiO2-graphene hybrid improved the flame retardancy of epoxy resins. Polymers for Advanced Technologies, 2018, 29(5): 1478–1486
|
12 |
Qiu S, Hu Y, Shi Y, Hou Y, Kan Y, Chu F, Sheng H, Yuen R K K, Xing W. In situ growth of polyphosphazene particles on molybdenum disulfide nanosheets for flame retardant and friction application. Composites. Part A, Applied Science and Manufacturing, 2018, 114: 407–417
|
13 |
Yang Q, Liu L, Hui D, Chipara M. Microstructure, electrical conductivity and microwave absorption properties of γ-FeNi decorated carbon nanotube composites. Composites. Part B, Engineering, 2016, 87: 256–262
|
14 |
Wu F, Zhao W, Chen H, Zeng Z, Wu X, Xue Q. Interfacial structure and tribological behaviours of epoxy resin coating reinforced with graphene and graphene oxide. Surface and Interface Analysis, 2017, 49(2): 85–92
|
15 |
Chen J, Yang J, Chen B, Liu S, Dong J, Li C. Large-scale synthesis of NbSe2 nanosheets and their use as nanofillers for improving the tribological properties of epoxy coatings. Surface and Coatings Technology, 2016, 305(305): 23–28
|
16 |
Burattin P, Che M, Louis C. Characterization of the Ni(II) phase formed on silica upon deposition-precipitation. Journal of Physical Chemistry B, 1997, 101(36): 7060–7074
|
17 |
Mizutani T, Fukushima Y, Okada A, Kamigaito O. Synthesis of nickel and magnesium phyllosilicates with 1:1 and 2:1 layer structures. Bulletin of the Chemical Society of Japan, 1990, 63(7): 2094–2098
|
18 |
Nares R, Ramírez J, Gutiérrez-Alejandre A, Louis C, Klimova T. Ni/Hβ-zeolite catalysts prepared by deposition-precipitation. Journal of Physical Chemistry B, 2002, 106(51): 13287–13293
|
19 |
Nares R, Ramírez J, Gutiérrez-Alejandre A, Cuevas R. Characterization and hydrogenation activity of Ni/Si(Al)-MCM-41 catalysts prepared by deposition-precipitation. Industrial & Engineering Chemistry Research, 2009, 48(3): 1154–1162
|
20 |
Fang Q, Xuan S, Jiang W, Gong X. Yolk-like micro/nanoparticles with superparamagnetic iron oxide cores and hierarchical nickel silicate shells. Advanced Functional Materials, 2011, 21(10): 1902–1909
|
21 |
Zhang C, Yue H, Huang Z, Li S, Wu G, Ma X, Gong J. Hydrogen production via steam reforming of ethanol on phyllosilicate-derived Ni/SiO2: enhanced metal-support interaction and catalytic stability. ACS Sustainable Chemistry & Engineering, 2013, 1(1): 161–173
|
22 |
Gui C, Hao S, Liu Y, Qu J, Yang C, Yu Y, Wang Q, Yu Z. Carbon nanotube@layered nickel silicate coaxial nanocables as excellent anode materials for lithium and sodium storage. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(32): 16551–16559
|
23 |
Qiu C, Ai L H, Jiang J. Layered phosphate-incorporated nickel-cobalt hydrosilicates for highly efficient oxygen evolution electrocatalysis. ACS Sustainable Chemistry & Engineering, 2018, 6(4): 4492–4498
|
24 |
Jian G, Meng Q, Jiao Y, Meng F, Cao Y, Wu M. Enhanced performances of triboelectric nanogenerators by filling hierarchical flower-like TiO2 particles into polymethyl methacrylate film. Nanoscale, 2020, 12(26): 14160–14170
|
25 |
Ma X Y, Zhang W D. Effects of flower-like ZnO nanowhiskers on the mechanical, thermal and antibacterial properties of waterborne polyurethane. Polymer Degradation & Stability, 2009, 94(7): 1103–1109
|
26 |
Xu N, Hu L, Zhang Q, Xiao X, Yang H, Yu E. Significantly enhanced dielectric performance of poly(vinylidene fluoride-co-hexafluoropylene)-based composites filled with hierarchical flower-like TiO2 particles. ACS Applied Materials & Interfaces, 2015, 7(49): 27373–27381
|
27 |
Fukushima Y, Tani M. Synthesis of 2:1 type 3-(methacryloxy) propyl magnesium (nickel) phyllosilicate. Bulletin of the Chemical Society of Japan, 1996, 69(12): 3667–3671
|
28 |
Ohtsuka K, Koga J, Suda M, Ono M. Fabrication of metal-layer (nickel) silicate microcomposite particles by a surfacenucleated precipitation route. Journal of the American Ceramic Society, 1989, 72(10): 1924–1930
|
29 |
Gui C X, Wang Q Q, Hao S M, Qu J, Huang P P, Cao C Y, Song W G, Yu Z Z. Sandwichlike magnesium silicate/reduced graphene oxide nanocomposite for enhanced Pb2+ and methylene blue adsorption. ACS Applied Materials & Interfaces, 2014, 6(16): 14653–14659
|
30 |
Chabrol K, Gressier M, Pebere N, Menu M J, Martin F, Bonino J P, Marichal C, Brendle J. Functionalization of synthetic talc-like phyllosilicates by alkoxyorganosilane grafting. Journal of Materials Chemistry, 2010, 20(43): 9695–9706
|
31 |
Yamini S, Young R J. Crack propagation in and fractography of epoxy resins. Journal of Materials Science, 1979, 14(7): 1609–1618
|
32 |
Yamini S, Young R J. Stability of crack propagation in epoxy resins. Polymer, 1977, 18(10): 1075–1080
|
33 |
Chen X, Wang L, Shi J, Shi H, Liu Y. Effect of barium sulfate nanoparticles on mechanical properties and crystallization behaviour of HDPE. Polymers & Polymer Composites, 2010, 18(3): 145–152
|
34 |
Yasmin A, Abot J L, Daniel I M. Processing of clay/epoxy nanocomposites by shear mixing. Scripta Materialia, 2003, 49(1): 81–86
|
35 |
Wu C L, Zhang M Q, Rong M Z, Friedrich K. Tensile performance improvement of low nanoparticles filled-polypropylene composites. Composites Science and Technology, 2002, 62(10): 1327–1340
|
36 |
Liu X, Wu Q. PP/clay nanocomposites prepared by grafting-melt intercalation. Polymer, 2001, 42(25): 10013–10019
|
37 |
Zhao C X, Zhang W D. Preparation of waterborne polyurethane nanocomposites: polymerization from functionalized hydroxyapatite. European Polymer Journal, 2008, 44(7): 1988–1995
|
38 |
Zhou K, Liu J, Shi Y, Jiang S, Wang D, Hu Y, Gui Z. MoS2 nanolayers grown on carbon nanotubes: an advanced reinforcement for epoxy composites. ACS Applied Materials & Interfaces, 2015, 7(11): 6070–6081
|
39 |
Kim H, Abdala A A, Macosko C W. Graphene/polymer nanocomposites. Macromolecules, 2010, 43(16): 6515–6530
|
40 |
Myshkin N, Kovalev A. Adhesion and surface forces in polymer tribology: a review. Friction, 2018, 6(2): 143–155
|
41 |
Gupta S, Hammann T, Johnson R, Riyad M F. Tribological behavior of novel Ti3SiC2 (natural nanolaminates)-reinforced epoxy composites during dry sliding. Tribology Transactions, 2015, 58(3): 560–566
|
42 |
Baptista R, Mendão A, Rodrigues F, Figueiredo-Pina C, Guedes M, Marat-Mendes R. Effect of high graphite filler contents on the mechanical and tribological failure behavior of epoxy matrix composites. Theoretical and Applied Fracture Mechanics, 2016, 85: 113–124
|
43 |
Nosonovsky M, Mortazavi V. Friction-Induced Vibrations and Self-Organization: Mechanics and Non-Equilibrium Thermodynamics of Sliding Contact. 1st ed. Boca Raton, FL: CSC Press, 2018
|
44 |
Dasari A, Yu Z Z, Mai Y W. Fundamental aspects and recent progress on wear/scratch damage in polymer nanocomposites. Materials Science and Engineering: R: Reports, 2009, 63(2): 31–80
|
45 |
Chen W X, Tu J P, Wang L Y, Gan H Y, Xu Z D, Zhang X B. Tribological application of carbon nanotubes in a metal-based composite coating and composites. Carbon, 2003, 41(2): 215–222
|
46 |
Fei J, Luo D, Wang H, Li H, Huang J, Luo W, Duan X. Effect of nano-SiO2 particles on the carbon fabric/resin friction materials by microwave-hydrothermal treatment. Journal of Composite Materials, 2017, 52(2): 245–252
|
47 |
Tan B J, Klabunde K J, Sherwood P M A. X-ray photoelectron spectroscopy studies of solvated metal atom dispersed catalysts. Monometallic iron and bimetallic iron-cobalt particles on alumina. Chemistry of Materials, 1990, 2(2): 186–191
|
48 |
Mathieu H J, Landolt D. An investigation of thin oxide films thermally grown in situ on Fe24Cr and Fe24Cr11Mo by auger electron spectroscopy and X-ray photoelectron spectroscopy. Corrosion Science, 1986, 26(7): 547–559
|
49 |
Dedryvère R, Maccario M, Croguennec L, Le Cras F, Delmas C, Gonbeau D. X-ray photoelectron spectroscopy investigations of carbon-coated LixFePO4 materials. Chemistry of Materials, 2008, 20(22): 7164–7170
|
50 |
Hawn D D, DeKoven B M. Deconvolution as a correction for photoelectron inelastic energy losses in the core level XPS spectra of iron oxides. Surface and Interface Analysis, 1987, 10(2-3): 63–74
|
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