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Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties
Received date: 02 Feb 2021
Accepted date: 23 Apr 2021
Published date: 15 Mar 2022
Copyright
Copper(I) selenide-nanocrystalline semiconductor was synthesized via one-step mechanochemical synthesis after 5 min milling in a planetary ball mill. The kinetics of synthesis was followed by X-ray powder diffraction analysis and specific surface area measurements of milled 2Cu/Se mixtures. The X-ray diffraction confirmed the orthorhombic crystal structure of Cu2Se with the crystallite size ~25 nm. The surface chemical structure was studied by X-ray photoelectron spectroscopy, whereby the binding energy of the Cu 2p and Se 3d signals corresponded to Cu+ and Se2– oxidation states. Transmission electron microscopy revealed agglomerated nanocrystals and confirmed their orthorhombic structure, as well. The optical properties were studied utilizing ultraviolet-visible spectroscopy and photoluminescence spectroscopy. The direct bandgap energy 3.7 eV indicated a blue-shift phenomenon due to the quantum size effect. This type of Cu2Se synthesis can be easily adapted to production dimensions using an industrial vibratory mill. The advantages of mechanochemical synthesis represent the potential for inexpensive, environmentally-friendly, and waste-free manufacturing of Cu2Se.
Katarína Gáborová , Marcela Achimovičová , Michal Hegedüs , Vladimír Girman , Mária Kaňuchová , Erika Dutková . Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties[J]. Frontiers of Chemical Science and Engineering, 2022 , 16(3) : 433 -442 . DOI: 10.1007/s11705-021-2066-6
1 |
Heydin R D, Murray R M. The crystal structures of Cu1.8Se, Cu3Se2, α- and γ-CuSe, CuSe2, and CuSe2II. Canadian Journal of Chemistry, 1976, 54(6): 841–848
|
2 |
Butt S, Farooq M, Mahmood W, Salam S, Sultan M, Basit M, Ma J, Lin Y, Nan C. One-step rapid synthesis of Cu2Se with enhanced thermoelectric properties. Journal of Alloys and Compounds, 2019, 786: 557–564
|
3 |
Gulay L, Daszkiewicz M, Strok O, Pietraszko A. Crystal structure of Cu2Se. Chemistry of Metals and Alloys, 2011, 4(3/4): 200–205
|
4 |
Byeon D, Sobota R, Delime-Codrin K, Choi S, Hirata K, Adachi M, Kiyama M, Matsuura T, Yamamoto Y, Matsunami M, Takeuchi T. Discovery of colossal Seebeck effect in metallic Cu2Se. Nature Communications, 2019, 10(1): 72
|
5 |
Liu K, Liu H, Wang J, Shi L J. Synthesis and characterization of Cu2Se prepared by hydrothermal co-reduction. Journal of Alloys and Compounds, 2009, 484(1-2): 674–676
|
6 |
Han X, Liao F, Zhang Y, Yuan Z, Chen H, Xu C. CTAB-assisted hydrothermal synthesis of Cu2Se films composed of nanowire networks. Materials Letters, 2018, 210: 62–65
|
7 |
Hsiang H, Hsu W, Lu L, Chang Y, Yen F. Cuprous selenide nano-crystal synthesis and characterization. Materials Research Bulletin, 2013, 48(2): 715–720
|
8 |
Jia F, Zhang S, Zhang X, Peng X, Zhang H, Xiang Y. Sb-triggered β-to-α transition: solvothermal synthesis of metastable alpha-Cu2Se. Chemistry (Weinheim an der Bergstrasse, Germany), 2014, 20(48): 15941–15946
|
9 |
Zhao Y, Zhu L, Jiang Y, Xie H, Zhang G, Ba N. Microphone shaped Cu2Se micro/nanoarchitecture: preparation, formation mechanism and optical property. Materials Letters, 2015, 147: 82–84
|
10 |
Eikeland E, Blichfeld A, Borup K, Zhao K, Overgaard J, Shi X, Chen L, Iversen B. Crystal structure across the beta to alpha phase transition in thermoelectric Cu2−xSe. Journal of Applied Crystallography, 2017, 4: 476–485
|
11 |
Xu S, Wang H, Zhu J, Chen H. Sonochemical synthesis of copper selenides nanocrystals with different phases. Journal of Crystal Growth, 2002, 234(1): 263–266
|
12 |
Kaur H, Kaur J, Singh L, Singh S. Electrochemical synthesis and characterization of Cu2Se nanowires. Superlattices and Microstructures, 2013, 64: 294–302
|
13 |
Yang C, Hsiang H, Tu J. Copper selenide crystallites synthesized using the hot-injection process. Advanced Powder Technology, 2016, 27(3): 959–963
|
14 |
Yang C, Hsiang H. Rapid synthesis and characterization of nearly dispersed marcasite CuSe2 and berzelianite Cu2Se crystallites using the chemical reduction process. Materials Research Bulletin, 2018, 97: 30–36
|
15 |
Su Y, Li G, Guo Z, Li Y Y, Li Y X, Huang X J, Liu J H. Cation-exchange synthesis of Cu2Se nanobelts and thermal conversion to porous CuO nanobelts with highly selective sensing toward H2S. ACS Applied Nano Materials, 2018, 1(1): 245–253
|
16 |
Bulat L, Osvenskii V, Ivanov A, Sorokin A, Pshenay-Severin D, Bublik V, Tabachkova N, Panchenko V, Lavrentev M. Experimental and theoretical study of the thermoelectric properties of copper selenide. Semiconductors, 2017, 51(7): 854–857
|
17 |
Ivanov A, Sorokin A, Panchenko V, Tarasova I, Tabachkova N, Bublik V, Akchurin R. Structure of the Cu2Se compound produced by different methods. Semiconductors, 2017, 51(7): 866–869
|
18 |
Li J, Liu G, Wu X, He G, Yang Z, Li J. Reaction mechanism in mechanochemical synthesis of Cu2−xSe. Ceramics International, 2018, 44(18): 22172–22175
|
19 |
Stevels A, Jellinek F. Phase transitions in copper chalcogenides: 1. Copper-selenium system. Recueil Des Travaux Chimiques Des Pays-Bas, 1971, 90(3): 273–283
|
20 |
Lévy-Clément C, Neumann-Spallart M, Haram S, Santhanam K. Chemical bath deposition of cubic copper(I) selenide and its room temperature transformation to the orthorhombic phase. Thin Solid Films, 1997, 302(1-2): 12–16
|
21 |
Kopp O, Cavin O. Hydrothermal growth of single-crystal Cu2Se (Berzelianite). Journal of Crystal Growth, 1984, 67(2): 391–392
|
22 |
Haram S, Santhanam K, Neumann-Spallart M, Lévy-Clément C. Electroless deposition on copper substrates and characterization of thin-films of copper(I) selenide. Materials Research Bulletin, 1992, 27(10): 1185–1191
|
23 |
Baláž M, Zorkovská A, Urakaev F, Baláž P, Briančin J, Bujňáková Z, Achimovičová M, Gock E. Ultrafast mechanochemical synthesis of copper sulfides. RSC Advances, 2016, 6(91): 87836–87842
|
24 |
Achimovičová M, Daneu N, Rečnik A, Ďurišin J, Peter B, Fabián M, Kováč J, Šatka A. Characterization of mechanochemically synthesized lead selenide. Chemical Papers, 2009, 63(5): 562–567
|
25 |
Achimovičová M, Baláž P, Ohtani T, Kostova N, Tyuliev G, Feldhoff A, Šepelák V. Characterization of mechanochemically synthesized ZnSe in a laboratory and an industrial mill. Solid State Ionics, 2011, 192(1): 632–637
|
26 |
Achimovičová M, Gotor F, Real C, Daneu N. Mechanochemical synthesis and characterization of nanocrystalline BiSe, Bi2Se3 semiconductors. Journal of Materials Science Materials in Electronics, 2012, 23(10): 1844–1850
|
27 |
Achimovičová M, Daneu N, Tóthová E, Mazaj M, Dutková E. Combined mechanochemical/thermal annealing approach for the synthesis of Co9Se8 with potential optical properties. Applied Physics. A, Materials Science & Processing, 2019, 125(1): 8
|
28 |
Zhu L, Xie H, Liu Y, Chen D, Bian M, Zheng W. Novel ultralong hollow hyperbranched Cu2−xSe with nanosheets hierarchical structure: preparation, formation mechanism and properties. Journal of Alloys and Compounds, 2019, 802: 430–436
|
29 |
Riha S, Johnson D, Prieto A. Cu2Se nanoparticles with tunable electronic properties due to a controlled solid-state phase transition driven by copper oxidation and cationic conduction. Journal of the American Chemical Society, 2011, 133(5): 1383–1390
|
30 |
Baláž M, Dutková E, Bujňáková Z, Tóthová E, Kostova N, Karakirova Y, Briančin J, Kaňuchová M. Mechanochemistry of copper sulfides: characterization, surface oxidation and photocatalytic activity. Journal of Alloys and Compounds, 2018, 746: 576–582
|
31 |
Hegedüs M, Baláž M, Tešinský M, Sayagues M, Siffalovic P, Kruľaková M, Kaňuchová M, Briančin J, Fabián M, Baláž P. Scalable synthesis of potential solar cell absorber Cu2SnS3 (CTS) from nanoprecursors. Journal of Alloys and Compounds, 2018, 768: 1006–1015
|
32 |
Tufts B J, Abrahams I L, Caley C E, Lunt S R, Miskelly G M, Sailor M J, Santangelo P G, Lewis N S, Roe A L, Hodgson A O. XPS and EXAFS studies of the reactions of Co(III) ammine complexes with GAAS-surfaces. Journal of the American Chemical Society, 1990, 112(13): 5123–5136
|
33 |
Theye M L, Gheorghiu A, Senemaud C H, Kotkata M F, Kandil K. Studies of short-range order in amorphous GexSe100−x compounds by X-ray photoelectron spectroscopy. Philosophical Magazine B, Physics of Condensed Matter. Structural, Electronic, Optical and Magnetic Properties, 1994, 69: 209–222
|
34 |
Zyoud A, Murtada K, Kwon H, Choi H, Kim T, Helal M, Faroun M, Bsharat H, Park D, Hilal H. Copper selenide film electrodes prepared by combined electrochemical/chemical bath depositions with high photo-electrochemical conversion efficiency and stability. Solid State Sciences, 2018, 75: 53–62
|
35 |
Tauc J, Grigorovici R, Vancu A. Optical properties and electronic structure of amorphous germanium. Physica Status Solidi B, Basic Research, 1966, 15(2): 627–637
|
36 |
Gurin V, Alexeenko A, Zolotovskaya S, Yumashev K. Copper and copper selenide nanoparticles in the sol-gel matrices: structural and optical. Materials Science and Engineering C, 2006, 26(5-7): 952–955
|
37 |
Sakr G B, Yahia I S, Fadel M, Fouad S S, Romčevic N. Optical spectroscopy, optical conductivity, dielectric properties and new methods for determining the gap states of CuSe thin films. Journal of Alloys and Compounds, 2010, 507(2): 557–562
|
38 |
Petrovic M, Gilic M, Cirkovic J, Romčevic M, Romčevic N, Trajic J, Yahia I S. Optical properties of CuSe thin films—band gap determination. Science of Sintering, 2017, 49(2): 167–174
|
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