Ion-imprinted silica gel and its dynamic membrane for nickel ion removal from wastewaters

Abstract

An ion-imprinted sorbent (IIP) was prepared by using Ni²⁺ as template, 3-[2-(2-aminoethylamino) ethylamino] propyl-trimethoxysilane as functional monomer, and silica gel as carrier. The adsorption performance of IIP towards Ni²⁺ was investigated. IIP showed a higher adsorption capacity than that of non-imprinted sorbent, and it also exhibited high selectivity for Ni²⁺ in the presence of Cu²⁺ and Zn²⁺ ions. Then, IIP was used to form a dynamic membrane onto the surface of ceramic membrane for treatment of electroplating wastewater containing Ni²⁺. Compared with ceramic membrane, IIP dynamic membrane had much higher steady membrane flux, and also rejected Ni²⁺ to obtain a lower concentration of Ni²⁺ in the permeate fluid. Perhaps it is suitable for future practice applications.

Key words： ion-imprinted; nickel ion; dynamic membrane; adsorption

Acknowledgments

This work was supported by the National Natural Science Foundation of China (Grant Nos. 51573041 and 21776067); and the Demonstration Base Project of University-Enterprise Cooperation of Hunan Province (No. 145812).

References

1 Meena A K, Mishra G K, Rai P K, Rajagopal C, Nagar P N. Removal of heavy metal ions from aqueous solutions using carbon aerogel as an adsorbent. Journal of Hazardous Materials, 2005, 122(1-2): 161–170

2 Sartore L, Dey K. Preparation and heavy metal ions chelating properties of multifunctional polymer-grafted silica hybrid materials. Advances in Materials Science and Engineering, 2019, 2019: 1–11

3 Jiang N, Chang X, Zheng H, He Q, Hu Z. Selective solid-phase extraction of nickel(II) using a surface-imprinted silica gel sorbent. Analytica Chimica Acta, 2006, 577(2): 225–231

4 Ong D C, Pingul-Ong S M B, Kan C C, de Luna M D G. Removal of nickel ions from aqueous solutions by manganese dioxide derived from groundwater treatment sludge. Journal of Cleaner Production, 2018, 190: 443–451

5 Quni L, Ramazani A, Fardood T. An overview of carbon nanotubes role in heavy metals removal from wastewater. Frontiers of Chemical Science and Engineering, 2019, 13(2): 274–295

6 Nemati M, Hosseini S M, Parvizian F, Rafiei N, van der Bruggen B. Desalination and heavy metal ion removal from water by new ion exchange membrane modified by synthesized NiFe₂O₄/HAMPS nanocomposite. Ionics, 2019, 25(8): 3847–3857

7 Alyüz B, Veli S. Kinetics and equilibrium studies for the removal of nickel and zinc from aqueous solutions by ion exchange resins. Journal of Hazardous Materials, 2009, 167(1-3): 482–488

8 Mook W T, Aroua M K, Issabayeva G. Prospective applications of renewable energy based electrochemical systems in wastewater treatment: A review. Renewable & Sustainable Energy Reviews, 2014, 38: 36–46

9 Fu F, Wang Q. Removal of heavy metal ions from wastewaters: A review. Journal of Environmental Management, 2011, 92(3): 407–418

10 Fan H T, Fan X, Li J, Guo M, Zhang D, Yan F, Sun T. Selective removal of arsenic(V) from aqueous solution using a surface-ion-imprinted amine-functionalized silica gel sorbent. Industrial & Engineering Chemistry Research, 2012, 51(14): 5216–5223

11 Zeng J, Dong Z, Zhang Z, Liu Y. Preparation of a surface-grafted imprinted ceramic membrane for selective separation of molybdate anion from water solutions. Journal of Hazardous Materials, 2017, 333: 128–136

12 Behbahani M, Bagheri A, Taghizadeh M, Salarian M, Sadeghi O, Adlnasab L, Jalali K. Synthesis and characterisation of nano structure lead (II) ion-imprinted polymer as a new sorbent for selective extraction and preconcentration of ultra trace amounts of lead ions from vegetables, rice, and fish samples. Food Chemistry, 2013, 138(2-3): 2050–2056

13 Otero-Romaní J, Moreda-Piñeiro A, Bermejo-Barrera P, Martin-Esteban A. Inductively coupled plasma-optical emission spectrometry/mass spectrometry for the determination of Cu, Ni, Pb and Zn in seawater after ionic imprinted polymer based solid phase extraction. Talanta, 2009, 79(3): 723–729

14 Quirarte-Escalante C A, Soto V, de la Cruz W, Porras G R, Manríquez R, Gomez-Salazar S. Synthesis of hybrid adsorbents combining sol-gel processing and molecular imprinting applied to lead removal from aqueous streams. Chemistry of Materials, 2009, 21(8): 1439–1450

15 Li Z, Li J, Wang Y, Wei Y. Synthesis and application of surface-imprinted activated carbon sorbent for solid-phase extraction and determination of copper (II). Spectrochimica Acta. Part A: Molecular and Biomolecular Spectroscopy, 2014, 117: 422–427

16 Kong D, Zhang F, Wang K, Ren Z, Zhang W. Fast removal of Cr(VI) from aqueous solution using Cr(VI)-imprinted polymer particles. Industrial & Engineering Chemistry Research, 2014, 53(11): 4434–4441

17 Vatanpour V, Madaeni S S, Zinadini S, Rajabi H R. Development of ion imprinted technique for designing nickel ion selective membrane. Journal of Membrane Science, 2011, 373(1-2): 36–42

18 Sun J, Wu L, Li Y. Removal of lead ions from polyether sulfone/Pb(II)-imprinted multi-walled carbon nanotubes mixed matrix membrane. Journal of the Taiwan Institute of Chemical Engineers, 2017, 78: 219–229

19 Zeng J, Zhang Z, Zhou H, Liu G, Liu Y, Zeng L, Jian J, Yuan Z. Ion-imprinted poly(methyl methacrylate-vinyl pyrrolidone)/poly(vinylidene fluoride) blending membranes for selective removal of ruthenium(III) from acidic water solutions. Polymers for Advanced Technologies, 2019, 30(7): 1865–1877

20 He J, Liu A, Paul C J. Introduction and demonstration of a novel Pb(II)-imprinted polymeric membrane with high selectivity and reusability for treatment of lead contaminated water. Journal of Colloid and Interface Science, 2015, 439: 162–169

21 Magnenet C, Jurin F E, Lakard S, Buron C C, Lakard B. Polyelectrolyte modification of ultrafiltration membrane for removal of copper ions. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 2013, 435: 170–177

22 Zhou H, Xun R, Wu K, Zhou Z, Yu B, Tang Y, Li N. Polyurethane membrane with temperature-and pH-controllable permeability for amino-acids. Macromolecular Research, 2015, 23(1): 94–99

23 Emani S, Uppaluri R, Purkait M K. Cross flow microfiltration of oil-water emulsions using kaolin based low cost ceramic membranes. Desalination, 2014, 341: 61–71

24 Shu F, Wang M, Pang J, Yu P. A free-standing superhydrophobic film for highly efficient removal of water from turbine oil. Frontiers of Chemical Science and Engineering, 2019, 13(2): 393–399

25 Dong S, Kim E S, Alpatova A, Noguchi H, Liu Y, El-Din M G. Treatment of oil sands process-affected water by submerged ceramic membrane microfiltration system. Separation and Purification Technology, 2014, 138: 198–209

26 Manikandan N A, Pakshirajan K, Pugazhenthi G. A novel ceramic membrane assembly for the separation of polyhydroxybutyrate rich Ralstonia eutropha biomass from culture broth. Process Safety and Environmental Protection, 2019, 126: 106–118

27 Pan Y, Wang T, Sun H, Wang W. Preparation and application of titanium dioxide dynamic membranes in microfiltration of oil-in-water emulsions. Separation and Purification Technology, 2012, 89: 78–83

28 Zhao Y, Tan Y, Wong F S, Fane A G, Xu N. Formation of Mg(OH)₂ dynamic membranes for oily water separation: Effects of operating conditions. Desalination, 2006, 191(1-3): 344–350

29 Chu H, Zhang Y, Zhou X, Dong B. Bio-enhanced powder-activated carbon dynamic membrane reactor for municipal wastewater treatment. Journal of Membrane Science, 2013, 433: 126–134

30 Chu H Q, Cao D W, Jin W, Dong B Z. Characteristics of bio-diatomite dynamic membrane process for municipal wastewater treatment. Journal of Membrane Science, 2008, 325(1): 271–276

31 Chu L, Li S. Filtration capability and operational characteristics of dynamic membrane bioreactor for municipal wastewater treatment. Separation and Purification Technology, 2006, 51(2): 173–179

32 Wang L, Liu H, Zhang W, Yu T, Jin Q, Fu B, Liu H. Recovery of organic matters in wastewater by self-forming dynamic membrane bioreactor: Performance and membrane fouling. Chemosphere, 2018, 203: 123–131

33 Lu D, Cheng W, Zhang T, Lu X, Liu Q, Jiang J, Ma J. Hydrophilic Fe₂O₃ dynamic membrane mitigating fouling of support ceramic membrane in ultrafiltration of oil/water emulsion. Separation and Purification Technology, 2016, 165: 1–9

34 Buhani N, Narsito , Nuryono, Kunarti E S. Production of metal ion imprinted polymer from mercapto-silica through sol-gel process as selective adsorbent of cadmium. Desalination, 2010, 251(1-3): 83–89

35 Zeng J, Zheng L, Sun X, He Q. Application of cross-flow microfiltration for purifying solvent naphtha with ceramic membranes. Chemical Engineering & Technology, 2011, 34(5): 718–726

36 Chang X, Jiang N, Zheng H, He Q, Hu Z, Zhai Y, Cui Y. Solid-phase extraction of iron(III) with an ion-imprinted functionalized silica gel sorbent prepared by a surface imprinting technique. Talanta, 2007, 71(1): 38–43

37 Liu J, Wu X, Li Y, Cui W, Liang Y. Modified silica gel surface with chelating ligand for effective mercury ions adsorption. Surfaces and Interfaces, 2018, 12: 108–115

38 Lu Y K, Yan X P. An imprinted organic-inorganic hybrid sorbent for selective separation of cadmium from aqueous solution. Analytical Chemistry, 2004, 76(2): 453–457

39 Tarley C R T, Andrade F N, Santana H D, Zaia D A M, Beijo L A, Segatelli M G. Ion-imprinted polyvinylimidazole-silica hybrid copolymer for selective extraction of Pb(II): Characterization and metal adsorption kinetic and thermodynamic studies. Reactive & Functional Polymers, 2012, 72(1): 83–91

40 Zeng J, Chen H, Yuan X, Guo Q, Yu X. A ion-imprinted chitosan/Al₂O₃ composite material for selective separation of copper(II). Desalination and Water Treatment, 2014, 55(5): 1–11

41 Lü H, An H, Xie Z. Ion-imprinted carboxymethyl chitosan-silica hybrid sorbent for extraction of cadmium from water samples. International Journal of Biological Macromolecules, 2013, 56(5): 89–93

42 Dinu M V, Dinu I A, Lazar M M, Dragan E S. Chitosan-based ion-imprinted cryo-composites with excellent selectivity for copper ions. Carbohydrate Polymers, 2018, 186: 140–149

43 Wang Z, Kong D, Qiao N, Wang N, Wang Q, Liu H, Zhou Z, Ren Z. Facile preparation of novel layer-by-layer surface ion-imprinted composite membrane for separation of Cu²⁺ from aqueous solution. Applied Surface Science, 2018, 457: 981–990

44 Fallah N, Taghizadeh M, Hassanpour S. Selective adsorption of Mo(VI) ions from aqueous solution using a surface-grafted Mo(VI) ion imprinted polymer. Polymer, 2018, 144: 80–91

45 Zeng J, Lv C, Liu G, Zhang Z, Dong Z, Liu J, Wang Y. A novel ion-imprinted membrane induced by amphiphilic block copolymer for selective separation of Pt(IV) from aqueous solutions. Journal of Membrane Science, 2019, 572: 428–441

46 Saleem M, Alibardi L, Lavagnolo M C, Cossu R, Spagni A. Effect of filtration flux on the development and operation of a dynamic membrane for anaerobic wastewater treatment. Journal of Environmental Management, 2016, 180: 459–465

47 Wu S E, Hwang K J, Cheng T W, Lin Y C, Tung K L. Dynamic membranes of powder-activated carbon for removing microbes and organic matter from seawater. Journal of Membrane Science, 2017, 541: 189–197

48 Zeng J, Zhang Z, Dong Z, Ren P, Li Y, Liu X. Fabrication and characterization of an ion-imprinted membrane via blending poly(methyl methacrylate-co-2-hydroxyethyl methacrylate) with polyvinylidene fluoride for selective adsorption of Ru(III). Reactive & Functional Polymers, 2017, 115: 1–9

49 Zhang X, Wang Z, Wu Z, Lu F, Tong J, Zang L. Formation of dynamic membrane in an anaerobic membrane bioreactor for municipal wastewater treatment. Chemical Engineering Journal, 2010, 165(1): 175–183

50 Li L, Xu G, Yu H, Xing J. Dynamic membrane for micro-particle removal in wastewater treatment: Performance and influencing factors. Science of the Total Environment, 2018, 627: 332–340

51 Wang K, Tian Z, Yin N. Significantly enhancing Cu(II) adsorption onto Zr-MOFs through novel cross-flow disturbance of ceramic membrane. Industrial & Engineering Chemistry Research, 2018, 57(10): 3773–3780

52 Dong Z, Zeng J, Zhou H, Lv C, Ma Y, Zeng J. Selective removal of tungstate anions from aqueous solutions by surface anion-imprinted ceramic membranes. Journal of Chemical Technology and Biotechnology (Oxford, Oxfordshire), 2019, 94(3): 942–954