Frontiers of Chemical Science and Engineering >
S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion
Received date: 24 Feb 2018
Accepted date: 20 Mar 2018
Published date: 18 Sep 2018
Copyright
Porous polymers have been recently recognized as one of the most important precursors for fabrication of heteroatom-doped porous carbons due to the intrinsic porous structure, easy available heteroatom-containing monomers and versatile polymerization methods. However, the heteroatom elements in as-produced porous carbons are quite relied on monomers. So far, the manipulating of heteroatom in porous polymer derived porous carbons are still very rare and challenge. In this work, a sulfur-enriched porous polymer, which was prepared from a diacetylene-linked porous polymer, was used as precursor to prepare S-doped and/or N-doped porous carbons under nitrogen and/or ammonia atmospheres. Remarkably, S content can sharply decrease from 36.3% to 0.05% after ammonia treatment. The N content and specific surface area of as-fabricated porous carbons can reach up to 1.32% and 1508 m2·g−1, respectively. As the electrode materials for electrical double-layer capacitors, as-fabricated porous carbons exhibit high specific capacitance of up to 431.6 F·g−1 at 5 mV·s−1 and excellent cycling stability of 99.74% capacitance retention after 3000 cycles at 100 mV·s−1. Furthermore, as the electrochemical catalysts for oxygen reduction reaction, as-fabricated porous carbons presented ultralow half-wave-potential of 0.78 V versus RHE. This work not only offers a new strategy for manipulating S and N doping features for the porous carbons derived from S-containing porous polymers, but also paves the way for the structure-performance interrelationship study of heteroatoms co-doped porous carbon for energy applications.
Chao Zhang , Chenbao Lu , Shuai Bi , Yang Hou , Fan Zhang , Ming Cai , Yafei He , Silvia Paasch , Xinliang Feng , Eike Brunner , Xiaodong Zhuang . S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion[J]. Frontiers of Chemical Science and Engineering, 2018 , 12(3) : 346 -357 . DOI: 10.1007/s11705-018-1727-6
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