Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal properties of epoxy nanocomposites

Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li

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Front. Chem. Sci. Eng. ›› 2021, Vol. 15 ›› Issue (5) : 1281-1295. DOI: 10.1007/s11705-020-2007-9
RESEARCH ARTICAL
RESEARCH ARTICAL

Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal properties of epoxy nanocomposites

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Abstract

Poor interfacial adhesion and dispersity severely obstruct the continued development of carbon nanotube (CNT)-reinforced epoxy (EP) for potential applications. Herein, hierarchical CNT nanohybrids using nickel phyllosilicate (Ni-PS) as surface decorations (CNT@Ni-PS) were synthesized, and the nanocomposites derived from varied mass fractions of EP and CNT@Ni-PS were prepared. The morphological structures, tribological performances, curing behaviors and thermal properties of EP/CNT@Ni-PS nanocomposites were carefully investigated. Results show that hierarchical CNT nanohybrids with homogeneous dispersion and well-bonded interfacial adhesion in the matrix are successfully obtained, presenting significantly improved thermal and tribological properties. Moreover, analysis on cure kinetics proves the excellent promotion of CNT@Ni-PS on the non-isothermal curing process, lowering the curing energy barrier steadily.

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Keywords

nickel phyllosilicate / surface decoration / tribological property / curing kinetics / thermal performance

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Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li. Synthesis of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal properties of epoxy nanocomposites. Front. Chem. Sci. Eng., 2021, 15(5): 1281‒1295 https://doi.org/10.1007/s11705-020-2007-9

References

[1]
Liu S, Chevali V S, Xu Z, Hui D, Wang H. A review of extending performance of epoxy resins using carbon nanomaterials. Composites. Part B, Engineering, 2018, 136: 197–214
[2]
Wang H, Sun L, Wang R, Yan L, Zhu Y, Wang C, Wang E. Dopamine modification of multiwalled carbon nanotubes and its influences on the thermal, mechanical, and tribological properties of epoxy resin composites. Polymer Composites, 2017, 38(1): 116–125
[3]
Esposito L H, Ramos J A, Kortaberria G. Dispersion of carbon nanotubes in nanostructured epoxy systems for coating application. Progress in Organic Coatings, 2014, 77(9): 1452–1458
[4]
Li A, Li W, Ling Y, Gan W, Brady M A, Wang C. Effects of silica-coated carbon nanotubes on the curing behavior and properties of epoxy composites. RSC Advances, 2016, 6(28): 23318–23326
[5]
Zakaria M R, Akil H M, Kudus M H A, Othman M B H. Compressive properties and thermal stability of hybrid carbon nanotube-alumina filled epoxy nanocomposites. Composites. Part B, Engineering, 2016, 91: 235–242
[6]
Li X, Chen B, Jia Y, Li X, Yang J, Li C, Yan F. Enhanced tribological properties of epoxy-based lubricating coatings using carbon nanotubes-ZnS hybrid. Surface and Coatings Technology, 2018, 344: 154–162
[7]
Zhou K, Liu J, Shi Y, Jiang S, Wang D, Hu Y, Gui Z. MoS2 nanolayers grown on carbon nanotubes: an advanced reinforcement for epoxy composites. ACS Applied Materials & Interfaces, 2015, 7(11): 6070–6081
[8]
Hou Y, Hu W, Liu L, Gui Z, Hu Y. In-situ synthesized CNTs/Bi2Se3 nanocomposites by a facile wet chemical method and its application for enhancing fire safety of epoxy resin. Composites Science and Technology, 2018, 157: 185–194
[9]
Bian Z, Kawi S. Preparation, characterization and catalytic application of phyllosilicate: a review. Catalysis Today, 2020, 339: 3–23
[10]
Nie S, Jin D, Xu Y, Han C, Dong X, Yang J. Effect of a flower-like nickel phyllosilicate-containing iron on the thermal stability and flame retardancy of epoxy resin. Journal of Materials Research and Technology, 2020, 9(5): 10189–10197
[11]
Yang J, Liu Y, Xu Y, Nie S, Li Z. Property investigations of epoxy composites filled by nickel phyllosilicate-decorated graphene oxide. Journal of Materials Science, 2020, 55(24): 10593–10610
[12]
Qu J, Li W, Cao C Y, Yin X J, Zhao L, Bai J, Qin Z, Song W G. Metal silicate nanotubes with nanostructured walls as superb adsorbents for uranyl ions and lead ions in water. Journal of Materials Chemistry, 2012, 22(33): 17222–17226
[13]
Grassi G, Scala A, Piperno A, Iannazzo D, Lanza M, Milone C, Pistone A, Galvagno S. A facile and ecofriendly functionalization of multiwalled carbon nanotubes by an old mesoionic compound. Chemical Communications, 2012, 48(54): 6836–6838
[14]
Burattin P, Che M, Louis C. Characterization of the Ni(II) phase formed on silica upon deposition-precipitation. Journal of Physical Chemistry B, 1997, 101(36): 7060–7074
[15]
Zhang X, Zhao D, Luan D, Bi C. Fabrication and mechanical properties of multiwalled carbon nanotube/nanonickel reinforced epoxy resin composites. Applied Physics. A, Materials Science & Processing, 2016, 122(12): 1056
[16]
Li H B, Yu M H, Wang F X, Liu P, Liang Y, Xiao J, Wang C X, Tong Y X, Yang G W. Amorphous nickel hydroxide nanospheres with ultrahigh capacitance and energy density as electrochemical pseudocapacitor materials. Nature Communications, 2013, 4: 1894
[17]
Kermarec M, Carriat J, Burattin P, Che M, Decarreau A. FTIR identification of the supported phases produced in the preparation of silica-supported nickel catalysts. Journal of Physical Chemistry, 1994, 98(46): 12008–12017
[18]
Wu Y, Chang G, Zhao Y, Zhang Y. Preparation of hollow nickel silicate nanospheres for separation of His-tagged proteins. Dalton Transactions (Cambridge, England), 2014, 43(2): 779–783
[19]
Da Fonseca M G, Silva C R, Barone J S, Airoldi C. Layered hybrid nickel phyllosilicates and reactivity of the gallery space. Journal of Materials Chemistry, 2000, 10(3): 789–795
[20]
Gui C, Hao S, Liu Y, Qu J, Yang C, Yu Y, Wang Q, Yu Z. Carbon nanotube@layered nickel silicate coaxial nanocables as excellent anode materials for lithium and sodium storage. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(32): 16551–16559
[21]
Chabrol K, Gressier M, Pebere N, Menu M J, Martin F, Bonino J P, Marichal C, Brendle J. Functionalization of synthetic talc-like phyllosilicates by alkoxyorganosilane grafting. Journal of Materials Chemistry, 2010, 20(43): 9695–9706
[22]
Kim K, Kim Y, Nam J, Baeck S H, Park D W, Shim S E. Mechanical properties of silica-coated multi-walled carbon nanotube/epoxy composites. Polymer (Korea), 2016, 40(1): 117–123
[23]
Liu J, Yuen R K K, Hong N, Hu Y. The influence of mesoporous SiO2-graphene hybrid improved the flame retardancy of epoxy resins. Polymers for Advanced Technologies, 2018, 29(5): 1478–1486
[24]
Chen X, Wang L, Shi J, Shi H, Liu Y. Effect of barium sulfate nanoparticles on mechanical properties and crystallization behaviour of HDPE. Polymers & Polymer Composites, 2010, 18(3): 145–152
[25]
Baptista R, Mendao A, Rodrigues F, Figueiredo-Pina C G, Guedes M, Marat-Mendes R. Effect of high graphite filler contents on the mechanical and tribological failure behavior of epoxy matrix composites. Theoretical and Applied Fracture Mechanics, 2016, 85: 113–124
[26]
Yi H, Chen C, Zhong F, Xu Z. Preparation of aluminum oxide-coated carbon nanotubes and the properties of composite epoxy coatings research. High Performance Polymers, 2014, 26(3): 255–264
[27]
Yuan J, Zhang Z, Yang M, Guo F, Men X, Liu W. Surface modification of hybrid-fabric composites with amino silane and polydopamine for enhanced mechanical and tribological behaviors. Tribology International, 2017, 107: 10–17
[28]
Wang Q H, Zhang X R, Pei X Q. Study on the friction and wear behavior of basalt fabric composites filled with graphite and nano-SiO2. Materials & Design, 2010, 31(3): 1403–1409
[29]
Pawlak Z, Kaldonski T, Pai R, Bayraktare E, Oloyede A. A comparative study on the tribological behaviour of hexagonal boron nitride (H-BN) as lubricating micro-particles—an additive in porous sliding bearings for a car clutch. Wear, 2009, 267(5): 1198–1202
[30]
Yu J, Zhao W, Wu Y, Wang D, Feng R. Tribological properties of epoxy composite coatings reinforced with functionalized C-BN and H-BN nanofillers. Applied Surface Science, 2018, 434: 1311–1320
[31]
Zhao Z, Ji J. Synthesis and tribological behaviors of epoxy/phosphazene-microspheres coatings under dry sliding condition. Advanced Engineering Materials, 2014, 16(8): 988–995
[32]
Choi J H, Song H J, Jung J, Yu J W, You N, Goh M. Effect of crosslink density on thermal conductivity of epoxy/carbon nanotube nanocomposites. Journal of Applied Polymer Science, 2017, 134(4): 44253
[33]
Dasari A, Yu Z Z, Mai Y W. Fundamental aspects and recent progress on wear/scratch damage in polymer nanocomposites. Materials Science and Engineering R Reports, 2009, 63(2): 31–80
[34]
Zhou T, Wang X, Liu X, Xiong D. Influence of multi-walled carbon nanotubes on the cure behavior of epoxy-imidazole system. Carbon, 2009, 47(4): 1112–1118
[35]
Singh A K, Panda B P, Mohanty S, Nayak S K, Gupta M K. Study on metal decorated oxidized multiwalled carbon nanotube (MWCNT)-epoxy adhesive for thermal conductivity applications. Journal of Materials Science Materials in Electronics, 2017, 28(12): 8908–8920
[36]
Liu Y F, Zhao M, Shen S G, Gao J G. Curing kinetics of tetrabromo-bisphenol—A epoxy resin with diaminodiphenyl methane. Acta Physico-Chimica Sinica, 1998, 14(10): 927–931
[37]
Gillham J K. Formation and properties of thermosetting and high Tg polymeric materials. Polymer Engineering and Science, 1986, 26(20): 1429–1433
[38]
Yarahmadi E, Didehban K, Sari M G, Saeb M R, Shabanian M, Aryanasab F, Zarrintaj P, Paran S M R, Mozafari M, Rallini M, Development and curing potential of epoxy/starch-functionalized graphene oxide nanocomposite coatings. Progress in Organic Coatings, 2018, 119: 194–202
[39]
Kissinger H E. Reaction kinetics in differential thermal analysis. Analytical Chemistry, 1957, 29(11): 1702–1706
[40]
Vyazovkin S, Mititelu A, Sbirrazzuoli N. Kinetics of epoxy-amine curing accompanied by the formation of liquid crystalline structure. Macromolecular Rapid Communications, 2003, 24(18): 1060–1065
[41]
Jain R, Choudhary V, Narula A. Studies on the curing kinetics of epoxy resins using mixture of nadic/or maleic anhydride and 4, 4′-diaminodiphenyl sulfone. Journal of Thermal Analysis and Calorimetry, 2007, 90(2): 495–501
[42]
Wan J, Gan B, Li C, Molina-Aldareguia J, Li Z, Wang X, Wang D Y. A novel biobased epoxy resin with high mechanical stiffness and low flammability: synthesis, characterization and properties. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(43): 21907–21921
[43]
Friedman H L. Kinetics of thermal degradation of char-forming plastics from thermogravimetry. Application to a phenolic plastic. Journal of Polymer Science Part C: Polymer Symposia, 1964, 6(1): 183–195
[44]
Starink M. The determination of activation energy from linear heating rate experiments: a comparison of the accuracy of isoconversion methods. Thermochimica Acta, 2003, 404(1-2): 163–176
[45]
Zhang J, Dong H, Tong L, Meng L, Chen Y, Yue G. Investigation of curing kinetics of sodium carboxymethyl cellulose/epoxy resin system by differential scanning calorimetry. Thermochimica Acta, 2012, 549: 63–68
[46]
Lu L, Xia L, Zengheng H, Xingyue S, Yi Z, Pan L. Investigation on cure kinetics of epoxy resin containing carbon nanotubes modified with hyper-branched polyester. RSC Advances, 2018, 8(52): 29830–29839
[47]
Xu W, Wang X, Liu Y, Li W, Chen R. Improving fire safety of epoxy filled with graphene hybrid incorporated with zeolitic imidazolate framework/layered double hydroxide. Polymer Degradation & Stability, 2018, 154: 27–36
[48]
Che Y, Sun Z, Zhan R, Wang S, Zhou S, Huang J. Effects of graphene oxide sheets-zirconia spheres nanohybrids on mechanical, thermal and tribological performances of epoxy composites. Ceramics International, 2018, 44(15): 18067–18077
[49]
Kim H, Abdala A A, Macosko C W. Graphene/polymer nanocomposites. Macromolecules, 2010, 43(16): 6515–6530

Acknowledgments

The authors gratefully acknowledge the National Natural Science Foundation of China (Grant No. 51775001), Natural Science Foundation of Anhui Province (Grant No. 1908085J20), University Synergy Innovation Program of Anhui Province (Grant No. GXXT-2019-027) and the Leading Talents Project in Colleges and Universities of Anhui Province.

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Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11705-020-2007-9 and is accessible for authorized users.

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