Recent Progress of Conductive Metal–Organic Frameworks for Electrochemical Energy Storage

Zhiyuan Sang; Yueyu Tong; Feng Hou; Ji Liang

doi:10.1007/s12209-022-00352-9

Transactions of Tianjin University ›› 2023, Vol. 29 ›› Issue (2) : 136 -150. DOI: 10.1007/s12209-022-00352-9

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Recent Progress of Conductive Metal–Organic Frameworks for Electrochemical Energy Storage

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¹ Key Laboratory for Advanced Ceramics and Machining Technology of Ministry of Education, School of Materials Science and Engineering, Tianjin University, 300350, Tianjin, China

² Institute for Superconducting and Electronic Materials, Australian Institute of Innovative Materials, University of Wollongong, Innovation Campus, Squires Way, 2500, North Wollongong, NSW, Australia

^d liangji@tju.edu.cn

Zhiyuan Sang received his Ph.D. degree from the School of Materials Science and Engineering in Tianjin University in 2020, and then worked as an assistant research fellow. His research focuses on nanomaterials for energy storage and conversion, including metal-ion batteries and electrocatalysis.

Yueyu Tong received her Ph.D. degree from the Institute for Superconducting and Electronic Materials, University of Wollongong, supervised by Prof. Shi Xue Dou and Prof. Ji Liang, and then worked as an associate research fellow. She is focusing on the design and fabrication of advanced nanomaterials for renewable energy conversion and storage.

A/Prof. Feng Hou received his Ph.D. degree from the Tianjin University in 2001. Later, he joined the faculty of School of Materials Science and Engineering in Tianjin University. His research interests focus on energy conversion and storage materials, including photo(electro)catalysts for water splitting/CO₂ reduction/nitrogen fixation, electrode materials for secondary batteries and supercapacitors.

Ji Liang received his Ph.D from the University of Adelaide in 2014. After a T. S. Ke fellowship in the Institute of Metal Research of the Chinese Academy of Sciences and a DECRA fellowship in the Institute for Superconducting and Electronic Materials of the University of Wollongong in Australia, he joined Tianjin University as a full professor. His research interests lie in the design of functional carbon-based materials for electrochemical catalysis and energy storage applications.

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Abstract

The development of reliable and low-cost energy storage systems is of considerable value in using renewable and clean energy sources, and exploring advanced electrodes with high reversible capacity, excellent rate performance, and long cycling life for Li/Na/Zn-ion batteries and supercapacitors is the key problem. Particularly because of their diverse structure, high specific surface area, and adjustable redox activity, electrically conductive metal–organic frameworks (c-MOFs) are considered promising candidates for these electrochemical applications, and a detailed overview of the recent progress of c-MOFs for electrochemical energy storage and their intrinsic energy storage mechanism helps realize a comprehensive and systematic understanding of this progress and further achieve highly efficient energy storage and conversion. Herein, the chemical structure of c-MOFs and their conductive mechanism are first introduced. Subsequently, a comprehensive summarization of the current applications of c-MOFs in energy storage systems, namely supercapacitors, LIBs, SIBs, and ZIBs, is presented. Finally, the prospects and challenges of c-MOFs toward much higher-performance energy storage devices are presented, which should illuminate the future scientific research and practical applications of c-MOFs in energy storage fields.

Keywords

Energy storage / Conductive metal–organic frameworks / Batteries / Supercapacitors

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Zhiyuan Sang, Yueyu Tong, Feng Hou, Ji Liang. Recent Progress of Conductive Metal–Organic Frameworks for Electrochemical Energy Storage. Transactions of Tianjin University, 2023, 29(2): 136-150 DOI:10.1007/s12209-022-00352-9

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