Applications of Transition Metal (Fe, Co, Ni)-Based Metal–Organic Frameworks and their Derivatives in Batteries and Supercapacitors

Abstract

Metal–organic frameworks (MOFs), which are generally considered to be crystalline materials comprising metal centers and organic ligands, have attracted growing attention because of their controllable structures and high porosity. MOFs based on transition metals (Fe, Co, Ni) are highly efficient electrode materials for electrochemical energy storage. In this review, the characteristics of Fe-MOFs, Co-MOFs, Ni-MOFs, and their derivatives are summarized, and the relationships between the structures and performance are unveiled in depth. Additionally, their applications in lithium–ion batteries, lithium–sulfur batteries, and supercapacitors are discussed. This review sheds light on the development of MOFs and their derivatives to realize excellent electrochemical performance.

Keywords

Transition metal-based MOFs / Lithium–ion batteries / Lithium–sulfur batteries / Supercapacitors

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