Black Phosphorus/Nanocarbons Constructing a Dual-Carbon Conductive Network for High-Performance Sodium-Ion Batteries

Abstract

Black phosphorus has been recognized as a prospective candidate anode material for sodium-ion batteries (SIBs) due to its ultrahigh theoretical capacity of 2596 mA·h/g and high electric conductivity of ≈ 300 S/m. However, its large volume expansion and contraction during sodiation/desodiation lead to poor cycling stability. In this work, a BP/graphite nanoparticle/nitrogen-doped multiwalled carbon nanotubes (BP/G/CNTs) composite with a dual-carbon conductive network is successfully fabricated as a promising anode material for SIBs through a simple two-step mechanical milling process. The unique structure can mitigate the effect of volume changes and provide additional electron conduction pathways during cycles. Furthermore, the formation of P–O–C bonds helps maintain the intimate connection between phosphorus and carbon, thereby improving the cycling and rate performance. As a result, the BP/G/CNTs composite delivers a high initial Coulombic efficiency (89.6%) and a high specific capacity for SIBs (1791.3 mA·h/g after 100 cycles at 519.2 mA/g and 1665.2 mA·h/g after 100 cycles at 1298 mA/g). Based on these results, the integrated strategy of one- and two-dimensional carbon materials can guide other anode materials for SIBs.

Keywords

Sodium-ion batteries / Anode material / Black phosphorus / Ball milling / Carbon conductive network

References

[1] Tarascon JM, Armand M Issues and challenges facing rechargeable lithium batteries. Nature, 2001, 414(6861): 359-367.

[2] Wu HB, Chen JS, Hng HH, et al. Nanostructured metal oxide-based materials as advanced anodes for lithium-ion batteries. Nanoscale, 2012, 4(8): 2526-2542.

[3] Wu H, Cui Y Designing nanostructured Si anodes for high energy lithium ion batteries. Nano Today, 2012, 7(5): 414-429.

[4] Goodenough JB Electrochemical energy storage in a sustainable modern society. Energy Environ Sci, 2014, 7(1): 14-18.

[5] Pan HL, Hu YS, Chen LQ Room-temperature stationary sodium-ion batteries for large-scale electric energy storage. Energy Environ Sci, 2013, 6(8): 2338-2360.

[6] Yabuuchi N, Kubota K, Dahbi M, et al. Research development on sodium-ion batteries. Chem Rev, 2014, 114(23): 11636-11682.

[7] Zhou D, Li XG, Fan LZ, et al. Three-dimensional porous graphene-encapsulated CNT@SnO₂ composite for high-performance lithium and sodium storage. Electrochim Acta, 2017, 230: 212-221.

[8] Yang JQ, Zhou XL, Wu DH, et al. S-doped N-rich carbon nanosheets with expanded interlayer distance as anode materials for sodium-ion batteries. Adv Mater, 2017, 29(6): 1604108.

[9] Slater MD, Kim D, Lee E, et al. Sodium-ion batteries. Adv Funct Mater, 2013, 23(8): 947-958.

[10] Palomares V, Serras P, Villaluenga I, et al. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy Environ Sci, 2012, 5(3): 5884-5901.

[11] Li W, Yao C, Wu XL, et al. New development of lithium-sulfur batteries. J Mol Sci, 2013, 29(6): 448-460 (in Chinese)

[12] Song JX, Yu ZX, Gordin ML, et al. Chemically bonded phosphorus/graphene hybrid as a high performance anode for sodium-ion batteries. Nano Lett, 2014, 14(11): 6329-6335.

[13] Shen W, Wang C, Xu QJ, et al. Nitrogen-doping-induced defects of a carbon coating layer facilitate Na-storage in electrode materials. Adv Energy Mater, 2015, 5(1): 1400982.

[14] Liu WH, Wu XL Work mechanism and research progress of solid polymer electrolytes for lithium-ion batteries. J Mol Sci, 2016, 32(5): 379-395 (in Chinese)

[15] Wen Y, He K, Zhu YJ, et al. Expanded graphite as superior anode for sodium-ion batteries. Nat Commun, 2014, 5: 4033.

[16] Sheng MH, Zhang F, Ji BF, et al. A novel tin-graphite dual-ion battery based on sodium-ion electrolyte with high energy density. Adv Energy Mater, 2017, 7(7): 1601963.

[17] Song TB, Chen H, Xu QJ, et al. Black phosphorus stabilizing Na₂Ti₃O₇/C each other with an improved electrochemical property for sodium-ion storage. ACS Appl Mater Interfaces, 2018, 10(43): 37163-37171.

[18] Shin H, Zhang JY, Lu W A comprehensive study of black phosphorus-graphite composite anodes and HEMM synthesis conditions for improved cycle stability. J Electrochem Soc, 2019, 166(12): A2673-A2682.

[19] Fu YQ, Wei QL, Zhang GX, et al. Advanced phosphorus-based materials for lithium/sodium-ion batteries: recent developments and future perspectives. Adv Energy Mater, 2018, 8(13): 1703058.

[20] Aykol M, Doak JW, Wolverton C Phosphorus allotropes: stability of black versus red phosphorus re-examined by means of the van der Waals inclusive density functional method. Phys Rev B, 2017, 95(21): 214115.

[21] Zeng G, Hu X, Zhou BL, et al. Engineering graphene with red phosphorus quantum dots for superior hybrid anodes of sodium-ion batteries. Nanoscale, 2017, 9(38): 14722-14729.

[22] Li LK, Yu YJ, Ye GJ, et al. Black phosphorus field-effect transistors. Nat Nanotechnol, 2014, 9(5): 372-377.

[23] Zhang YK, Tao HC, Li JH, et al. Achieving a high-performance P/C anode through P–O–C bond for sodium ion batteries. Ionics, 2020, 26(7): 3377-3385.

[24] Sun J, Lee HW, Pasta M, et al. A phosphorene-graphene hybrid material as a high-capacity anode for sodium-ion batteries. Nat Nanotechnol, 2015, 10(11): 980-985.

[25] Vanni M, Serrano-Ruiz M, Telesio F, et al. Black phosphorus/palladium nanohybrid: unraveling the nature of P-Pd interaction and application in selective hydrogenation. Chem Mater, 2019, 31(14): 5075-5080.

[26] Li L, Zhang D, Deng JP, et al. Electrochemical exfoliation of two-dimensional layered black phosphorus and applications. J Energy Chem, 2020, 49: 365-374.

[27] Tian Y, Wang HD, Li HN, et al. Recent advances in black phosphorus/carbon hybrid composites: from improved stability to applications. J Mater Chem A, 2020, 8(9): 4647-4676.

[28] Ramireddy T, Xing T, Rahman MM, et al. Phosphorus-carbon nanocomposite anodes for lithium-ion and sodium-ion batteries. J Mater Chem A, 2015, 3(10): 5572-5584.

[29] Liu HW, Tao L, Zhang YQ, et al. Bridging covalently functionalized black phosphorus on graphene for high-performance sodium-ion battery. ACS Appl Mater Interfaces, 2017, 9(42): 36849-36856.

[30] Haghighat-Shishavan S, Nazarian-Samani M, Nazarian-Samani M, et al. Strong, persistent superficial oxidation-assisted chemical bonding of black phosphorus with multiwall carbon nanotubes for high-capacity ultradurable storage of lithium and sodium. J Mater Chem A, 2018, 6(21): 10121-10134.

[31] Fu YJ, Zhang LY, Chen G Preparation of a carbon nanotube-copper nanoparticle hybrid by chemical reduction for use in the electrochemical sensing of carbohydrates. Carbon, 2012, 50(7): 2563-2570.

[32] Song JX, Yu ZX, Gordin ML, et al. Advanced sodium ion battery anode constructed via chemical bonding between phosphorus, carbon nanotube, and cross-linked polymer binder. ACS Nano, 2015, 9(12): 11933-11941.

[33] Amrute AP, De Bellis J, Felderhoff M, et al. Mechanochemical synthesis of catalytic materials. Chem A Eur J, 2021, 27(23): 6819-6847.

[34] Hanlon D, Backes C, Doherty E, et al. Liquid exfoliation of solvent-stabilized few-layer black phosphorus for applications beyond electronics. Nat Commun, 2015, 6: 8563.

[35] Jeong JH, Lee JS, Roh KC, et al. Multimodal porous carbon derived from ionic liquids: correlation between pore sizes and ionic clusters. Nanoscale, 2017, 9(38): 14672-14681.

[36] Kim HK, Bak SM, Lee SW, et al. Scalable fabrication of micron-scale graphene nanomeshes for high-performance supercapacitor applications. Energy Environ Sci, 2016, 9(4): 1270-1281.

[37] Shi Y, Yi ZB, Kuang YP, et al. Constructing stable covalent bonding in black phosphorus/reduced graphene oxide for lithium ion battery anodes. Chem Commun, 2020, 56(78): 11613-11616.

[38] Wang H, Wang L, Wang L, et al. Phosphorus particles embedded in reduced graphene oxide matrix to enhance capacity and rate capability for capacitive potassium-ion storage. Chemistry, 2018, 24(52): 13897-13902.

[39] Zhang YP, Wang LL, Xu H, et al. Black phosphorus: 3D chemical cross-linking structure of black phosphorus@CNTs hybrid as a promising anode material for lithium ion batteries. Adv Funct Mater, 2020, 30(12): 2070074.

[40] Chizari K, Deneuve A, Ersen O, et al. Nitrogen-doped carbon nanotubes as a highly active metal-free catalyst for selective oxidation. Chemsuschem, 2012, 5(1): 102-108.

[41] Palaniselvam T, Goktas M, Anothumakkool B, et al. Sodium storage and electrode dynamics of tin-carbon composite electrodes from bulk precursors for sodium-ion batteries. Adv Funct Mater, 2019, 29(18): 1900790.

[42] Qiao Y, Ma MY, Liu Y, et al. First-principles and experimental study of nitrogen/sulfur co-doped carbon nanosheets as anodes for rechargeable sodium ion batteries. J Mater Chem A, 2016, 4(40): 15565-15574.

[43] Muñoz-Sandoval E, Cortes-López AJ, Flores-Gómez B, et al. Carbon sponge-type nanostructures based on coaxial nitrogen-doped multiwalled carbon nanotubes grown by CVD using benzylamine as precursor. Carbon, 2017, 115: 409-421.

[44] Qian JF, Wu XY, Cao YL, et al. High capacity and rate capability of amorphous phosphorus for sodium ion batteries. Angew Chem Int Ed Engl, 2013, 52(17): 4633-4636.

[45] Zhou FC, Ouyang LZ, Liu JW, et al. Chemical bonding black phosphorus with TiO₂ and carbon toward high-performance lithium storage. J Power Sources, 2020, 449: 227549.