Synergistic Effect of Cocamidopropyl Betaine and Sodium Lauroyl Sarcosinate

Hongyuan Wei , Rui Zhang , Zhong Lei , Leping Dang

Transactions of Tianjin University ›› 2021, Vol. 27 ›› Issue (5) : 366 -376.

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Transactions of Tianjin University ›› 2021, Vol. 27 ›› Issue (5) : 366 -376. DOI: 10.1007/s12209-020-00244-w
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Synergistic Effect of Cocamidopropyl Betaine and Sodium Lauroyl Sarcosinate

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Abstract

In this study, we investigated the synergistic effect of a zwitterionic surfactant (cocamidopropyl betaine) and amino acid surfactant (sodium lauroyl sarcosinate) by measurements of surface tension, rheological properties, dynamic light scattering (DLS), and transmission electron microscopy (TEM). The results confirm the formation of wormlike micelles in the mixed system, which leads to superior surface activity as compared to that of an individual surfactant. Stable and dynamic viscoelastic measurements were also performed to explore the characteristics of wormlike micelles at different mole fractions, pH values, and temperatures. The results indicate that the strongest wormlike structure formed under the conditions of X 1 = 0.5, pH = 4.7, and C T = 600 mmol/L. The size and morphology of the mixed micelles were obtained by DLS and TEM. The results of this work offer insight into the interaction between zwitterionic and amino acid surfactants, which will contribute to the design of complex surfactants.

Keywords

Surfactant / Synergistic effect / Rheology / Wormlike micelles

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Hongyuan Wei, Rui Zhang, Zhong Lei, Leping Dang. Synergistic Effect of Cocamidopropyl Betaine and Sodium Lauroyl Sarcosinate. Transactions of Tianjin University, 2021, 27(5): 366-376 DOI:10.1007/s12209-020-00244-w

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References

[1]

Wydro P, Paluch M A study of the interaction of dodecyl sulfobetaine with cationic and anionic surfactant in mixed micelles and monolayers at the air/water interface. J Colloid Interface Sci, 2005, 286(1): 387-391.

[2]

Shrestha RG, Shrestha LK, Aramaki K Formation of wormlike micelle in a mixed amino-acid based anionic surfactant and cationic surfactant systems. J Colloid Interface Sci, 2007, 311(1): 276-284.

[3]

Różańska S Rheology of wormlike micelles in mixed solutions of cocoamidopropyl betaine and sodium dodecylbenzenesulfonate. Colloids Surf A Physicochem Eng Asp, 2015, 482: 394-402.

[4]

Bergström M Synergistic effects in mixtures of an anionic and a cationic surfactant. Langmuir, 2001, 17(4): 993-998.

[5]

Kanoje B, Padshala S, Parikh J, et al. Synergism and aggregation behaviour in an aqueous binary mixture of cationic–zwitterionic surfactants: physico-chemical characterization with molecular simulation approach. Phys Chem Chem Phys, 2018, 20(1): 670-681.

[6]

Wang XQ, Wang RT, Zheng Y, et al. Interaction between zwitterionic surface activity ionic liquid and anionic surfactant: Na+-driven wormlike micelles. J Phys Chem B, 2013, 117(6): 1886-1895.

[7]

Wei HY, Feng BH, Zhao GZ, et al. Effect of non-reactive powder particle properties on dry agglomeration in a high shear mixer. Trans Tianjin Univ, 2018, 24: 442-452.

[8]

Prajapati RR, Bhagwat SS Effect of foam boosters on the micellization and adsorption of sodium dodecyl sulfate. J Chem Eng Data, 2012, 57(12): 3644-3650.

[9]

Danov KD, Kralchevska SD, Kralchevsky PA, et al. Mixed solutions of anionic and zwitterionic surfactant (betaine): surface-tension isotherms, adsorption, and relaxation kinetics. Langmuir, 2004, 20(13): 5445-5453.

[10]

Li YP, Lv W, Cao XL, et al. Study of the synergistic effect of sodium dodecyl sulfate and betaine at the air/water and oil/water interfaces. Acta Chim Sin, 2014, 72(5): 615.

[11]

Ghosh S, Khatua D, Dey J Interaction between zwitterionic and anionic surfactants: spontaneous formation of zwitanionic vesicles. Langmuir, 2011, 27(9): 5184-5192.

[12]

Vashishat R, Chabba S, Mahajan RK Effect of surfactant head group on micellization and morphological transitions in drug-surfactant catanionic mixture: a multi-technique approach. Colloids Surf A Physicochem Eng Asp, 2016, 498: 206-217.

[13]

Roy S, Nayak RR, Dey J Stable vesicle formation through intra- and inter-chain aggregation of poly[sodium N-(11-acrylamidoundecanoyl)-L-valinate] in aqueous solution. Colloids Surf A Physicochem Eng Asp, 2006, 290(1–3): 62-69.

[14]

Lopez-Diaz D, Sarmiento-Gomez E, Garza C, et al. A rheological study in the dilute regime of the worm-micelle fluid made of zwitterionic surfactant (TDPS), anionic surfactant (SDS), and brine. J Colloid Interface Sci, 2010, 348(1): 152-158.

[15]

Ghosh S, Dey J Interaction of sodium N-lauroylsarcosinate with N-alkylpyridinium chloride surfactants: spontaneous formation of pH-responsive, stable vesicles in aqueous mixtures. J Colloid Interface Sci, 2011, 358(1): 208-216.

[16]

Bajpai AK, Shukla SK, Bhanu S, et al. Responsive polymers in controlled drug delivery. Prog Polym Sci, 2008, 33(11): 1088-1118.

[17]

Zhou M, Li SS, Zhang Z, et al. Synthesis of oligomer betaine surfactant (DDTPA) and rheological properties of wormlike micellar solution system. J Taiwan Inst Chem Eng, 2016, 66: 1-11.

[18]

Chu ZL, Dreiss CA, Feng YJ Smart wormlike micelles. Chem Soc Rev, 2013, 42(17): 7174-7203.

[19]

Xv Y, Wang F, Hou QF, et al. Strategy for synthesizing novel acetamidines as CO2-triggered switchable surfactants via acetimidates. Trans Tianjin Univ, 2019, 25: 237-244.

[20]

Stukan MR, Boek ES, Padding JT, et al. Flow of wormlike micelles in an expansion–contraction geometry. Soft Matter, 2008, 4(4): 870-879.

[21]

Müller T, Krämer C, Pritzel C, et al. Influence of cocamidopropyl betaine on the formation and carbonation of portlandite—a microscopy study. Constr Build Mater, 2018, 163: 793-797.

[22]

Abdel-Rahem RA, Reger M, Hloucha M, et al. Rheology of aqueous solutions containing SLES, CAPB, and microemulsion: influence of cosurfactant and salt. J Dispers Sci Technol, 2014, 35(1): 64-75.

[23]

Shao WY, Zhang JY, Wang K, et al. Cocamidopropyl betaine-assisted foam separation of freshwater microalgae Desmodesmus brasiliensis. Biochem Eng J, 2018, 140: 38-46.

[24]

Erfani A, Flynn NH, Ramsey JD, et al. Increasing protein stability by association with zwitterionic amphiphile cocamidopropyl betaine. J Mol Liq, 2019, 295: 111631.

[25]

Bajani D, Gharai D, Dey J A comparison of the self-assembly behaviour of sodium N-lauroyl sarcosinate and sodium N-lauroyl glycinate surfactants in aqueous and aqueo-organic media. J Colloid Interface Sci, 2018, 529: 314-324.

[26]

Staszak K, Wieczorek D, Michocka K Effect of sodium chloride on the surface and wetting properties of aqueous solutions of cocamidopropyl betaine. J Surfact Deterg, 2015, 18(2): 321-328.

[27]

Patra N, Ray D, Aswal VK, et al. Exploring physicochemical interactions of different salts with sodium N-dodecanoyl sarcosinate in aqueous solution. ACS Omega, 2018, 3(8): 9256-9266.

[28]

Sehgal P, Doe H, Wimmer R, et al. Mixed monolayer and micelle formation of cationic and zwitterionic surfactant of identical hydrocarbon tail in an aqueous medium: interfacial tension, fluorescence probe, dynamic light scattering, and viscosity studies. J Dispers Sci Technol, 2008, 29(3): 327-334.

[29]

Rosen MJ Surfactants and interfacial phenomena, 1989 Hoboken Wiley

[30]

Mahajan RK, Sharma R Analysis of interfacial and micellar behavior of sodium dioctyl sulphosuccinate salt (AOT) with zwitterionic surfactants in aqueous media. J Colloid Interface Sci, 2011, 363(1): 275-283.

[31]

Kabir-Ud-din SM, Dar AA Interaction of a cationic gemini surfactant with conventional surfactants in the mixed micelle and monolayer formation in aqueous medium. J Colloid Interface Sci, 2009, 333(2): 605-612.

[32]

Geng T, Zhang CQ, Jiang YJ, et al. Synergistic effect of binary mixtures contained newly cationic surfactant: interaction, aggregation behaviors and application properties. J Mol Liq, 2017, 232: 36-44.

[33]

Israelachvili JN, Mitchell DJ, Ninham BW Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers. J Chem Soc Faraday Trans, 1976, 2(72): 1525.

[34]

Tanford C Structures in an aqueous world. (Book reviews: the hydrophobic effect. formation of micelles and biological membranes). Science, 1974, 184(4136): 559-560.

[35]

Cates ME, Candau SJ Statics and dynamics of worm-like surfactant micelles. J Phys Condens Matter, 1990, 2(33): 6869-6892.

[36]

Georgieva GS, Anachkov SE, Lieberwirth I, et al. Synergistic growth of giant wormlike micelles in ternary mixed surfactant solutions: effect of octanoic acid. Langmuir, 2016, 32(48): 12885-12893.

[37]

Roy S, Dey J Effect of hydrogen-bonding interactions on the self-assembly formation of sodium N-(11-acrylamidoundecanoyl)-L-serinate, L-asparaginate, and L-glutaminate in aqueous solution. J Colloid Interface Sci, 2007, 307(1): 229-234.

[38]

Wei HY, Lu JL, Gu C, et al. Visualization of wormlike micelle fluid flow in a mixing tank. Trans Tianjin Univ, 2018, 24(4): 308-317.

[39]

Moore JE, McCoy TM, de Campo L, et al. Wormlike micelle formation of novel alkyl-tri(ethylene glycol)-glucoside carbohydrate surfactants: structure–function relationships and rheology. J Colloid Interface Sci, 2018, 529: 464-475.

[40]

Cox WP, Merz EH Correlation of dynamic and steady flow viscosities. J Polym Sci, 1958, 28(118): 619-622.

[41]

López-Díaz D, García-Mateos I, Velázquez MM Synergism in mixtures of zwitterionic and ionic surfactants. Colloids Surf A Physicochem Eng Asp, 2005, 270–271: 153-162.

[42]

Candau SJ, Hirsch E, Zana R, et al. Network properties of semidilute aqueous KBr solutions of cetyltrimethylammonium bromide. J Colloid Interface Sci, 1988, 122: 430-440.

[43]

Raghavan SR, Kaler EW Highly viscoelastic wormlike micellar solutions formed by cationic surfactants with long unsaturated tails. Langmuir, 2001, 17(2): 300-306.

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