Micro-scale hierarchical photoanode for quantum-dot-sensitized solar cells based on TiO2 nanowires
Heng LI, Wei JING, Dapeng YU, Qing ZHAO
Micro-scale hierarchical photoanode for quantum-dot-sensitized solar cells based on TiO2 nanowires
This paper proposed a new architecture design for nanowire-based quantum-dot-sensitized solar cells to improve the photovoltaic performance. Microstructured rough substrate was used to increase the surface area of the photoanode without influence on charge carrier transport in the system. Compared to conventional devices, the short circuit current density and power conversion efficiency were enhanced by 50%. And the technology can be widely used in the photoelectrochemical (PEC) field, and it can be combined with other hierarchical nanostructures.
quantum-dot-sensitized solar cell (QDSSC) / hierarchical structure / TiO2 nanowires
[1] |
Grätzel M. Dye-sensitized solar cells. Journal of Photochemistry and Photobiology C, Photochemistry Reviews, 2003, 4(2): 145–153
CrossRef
Google scholar
|
[2] |
Rühle S, Shalom M, Zaban A. Quantum-dot-sensitized solar cells. ChemPhysChem, 2010, 11(11): 2290–2304
CrossRef
Pubmed
Google scholar
|
[3] |
Walter M G, Warren E L, McKone J R, Boettcher S W, Mi Q, Santori E A, Lewis N S. Solar water splitting cells. Chemical Reviews, 2010, 110(11): 6446–6473
CrossRef
Pubmed
Google scholar
|
[4] |
Wu J, Chen G, Yang H, Ku C, Lai J. Effects of dye adsorption on the electron transport properties in ZnO nanowire dye-sensitized solar cells. Applied Physics Letters, 2007, 90(21): 213109
CrossRef
Google scholar
|
[5] |
Baxter J, Aydil E. Nanowire-based dye-sensitized solar cells. Applied Physics Letters, 2005, 86(5): 053114
CrossRef
Google scholar
|
[6] |
Bierman M J, Jin S. Potential applications of hierarchical branching nanowires in solar energy conversion. Energy & Environmental Science, 2009, 2(10): 1050–1059
CrossRef
Google scholar
|
[7] |
Xu C, Wu J, Desai U V, Gao D. High-efficiency solid-state dye-sensitized solar cells based on TiO2-coated ZnO nanowire arrays. Nano Letters, 2012, 12(5): 2420–2424
CrossRef
Pubmed
Google scholar
|
[8] |
Wu X J, Zhu F, Mu C, Liang Y, Xu L, Chen Q, Chen R, Xu D. Electrochemical synthesis and applications of oriented and hierarchically quansi-1D semiconducting nanostructures. Coordination Chemistry Reviews, 2010, 254(9-10): 1135–1150
CrossRef
Google scholar
|
[9] |
Ko S H, Lee D, Kang H W, Nam K H, Yeo J Y, Hong S J, Grigoropoulos C P, Sung H J. Nanoforest of hydrothermally grown hierarchical ZnO nanowires for a high efficiency dye-sensitized solar cell. Nano Letters, 2011, 11(2): 666–671
CrossRef
Pubmed
Google scholar
|
[10] |
Sauvage F, Di Fonzo F, Li Bassi A, Casari C S, Russo V, Divitini G, Ducati C, Bottani C E, Comte P, Graetzel M. Hierarchical TiO2 photoanode for dye-sensitized solar cells. Nano Letters, 2010, 10(7): 2562–2567
CrossRef
Google scholar
|
[11] |
Law M, Greene L E, Radenovic A, Kuykendall T, Liphardt J, Yang P. ZnO-Al2O3 and ZnO-TiO2 core-shell nanowire dye-sensitized solar cells. Journal of Physical Chemistry B, 2006, 110(45): 22652–22663
CrossRef
Pubmed
Google scholar
|
[12] |
Lee Y, Chang C. Efficient polysulfide electrolyte for CdS quantum dot-sensitized solar cells. Journal of Power Sources, 2008, 185(1): 584–588
CrossRef
Google scholar
|
[13] |
Yu X Y, Liao J Y, Qiu K Q, Kuang D B, Su C Y. Dynamic study of highly efficient CdS/CdSe quantum dot-sensitized solar cells fabricated by electrodeposition. ACS Nano, 2011, 5(12): 9494–9500
CrossRef
Pubmed
Google scholar
|
[14] |
Zhao N, Osedach T P, Chang L Y, Geyer S M, Wanger D, Binda M T, Arango A C, Bawendi M G, Bulovic V. Colloidal PbS quantum dot solar cells with high fill factor. ACS Nano, 2010, 4(7): 3743–3752
CrossRef
Pubmed
Google scholar
|
[15] |
Zhang J, Gao J, Church C P, Miller E M, Luther J M, Klimov V I, Beard M C. PbSe quantum dot solar cells with more than 6% efficiency fabricated in ambient atmosphere. Nano Letters, 2014, 14(10): 6010–6015
CrossRef
Pubmed
Google scholar
|
[16] |
Zaban A, Micic O I, Gregg B A, Nozik A J. Photosensitization of nanoporous TiO2 electrodes with InP quantum dots. Langmuir, 1998, 14(12): 3153–3156
CrossRef
Google scholar
|
[17] |
Law M, Greene L E, Johnson J C, Saykally R, Yang P. Nanowire dye-sensitized solar cells. Nature Materials, 2005, 4(6): 455–459
CrossRef
Pubmed
Google scholar
|
[18] |
Liu B, Aydil E S.Growth of oriented single-crystalline rutile TiO2 nanorods on transparent conducting substrates for dye-sensitized solar cells. Journal of American Chemical Society, 2009, 131(11): 3985–3990
CrossRef
Google scholar
|
/
〈 | 〉 |