Preparation, structure and properties of fluorescent nano-CdTe/poly (1, 4–butanediol-citrate) bioelastomer nanocomposite in-situ dispersion technique

Li JIANG, Aimiao QIN, Kunpeng JIANG, Lei LIAO, Xiulan WU, Chaojian WU

PDF(357 KB)
PDF(357 KB)
Front. Optoelectron. ›› 2013, Vol. 6 ›› Issue (4) : 452-457. DOI: 10.1007/s12200-013-0345-7
RESEARCH ARTICLE
RESEARCH ARTICLE

Preparation, structure and properties of fluorescent nano-CdTe/poly (1, 4–butanediol-citrate) bioelastomer nanocomposite in-situ dispersion technique

Author information +
History +

Abstract

Hydrophilic photoluminescent CdTe/poly (1, 4–butanediol-citrate) (PBC) bioelastomer nanocomposite was successfully synthesized by a two-step method and characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Uv-vis spectroscopy, photoluminescence (PL) spectroscopy and scanning electron microscope (SEM). The differential scanning calorimetry analysis shows that the bioelastomer nanocom-posites with different mass fractions of CdTe have low glass-transition temperature, which indicates that they possess elastic property in the range from room temperature to the expected applied temperature (37°C). The measurements of the hydrophilicity, in vitro degradation and PL show that the nanocomposite has good hydrophilicity, degradation and high fluorescence properties.

Keywords

bioelastomer / spectroscopy / biodegradable

Cite this article

Download citation ▾
Li JIANG, Aimiao QIN, Kunpeng JIANG, Lei LIAO, Xiulan WU, Chaojian WU. Preparation, structure and properties of fluorescent nano-CdTe/poly (1, 4–butanediol-citrate) bioelastomer nanocomposite in-situ dispersion technique. Front Optoelec, 2013, 6(4): 452‒457 https://doi.org/10.1007/s12200-013-0345-7

References

[1]
Liu Y F, Yu J S. In situ synthesis of highly luminescent glutathione-capped CdTe/ZnS quantum dots with biocompatibility. Journal of Colloid and Interface Science, 2010, 351(1): 1–9
CrossRef Pubmed Google scholar
[2]
Nag A, Kovalenko M V, Lee J S, Liu W Y, Spokoyny B, Talapin D V. Metal-free inorganic ligands for colloidal nanocrystals: S2-, HS-, Se2-, HSe-, Te2-, HTe-, TeS32-, OH-, and NH2- as surface ligands. Journal of the American Chemical Society, 2011, 133(27): 10612–10620
CrossRef Pubmed Google scholar
[3]
Qin A M, Zhou X S, Qiu Y F, Fang Y P, Su C Y, Yang S H. Periodically twinned nanotowers and nanodendrites of mercury selenide synthesized via a solution-liquid-solid route. Advanced Materials, 2008, 20(4): 768–773
CrossRef Google scholar
[4]
Qin A M, Fang Y P, Su C Y. Hydrothermal synthesis of HgTe rod-shaped nanocrystals. Materials Letters, 2007, 61(1): 126–129
CrossRef Google scholar
[5]
Zhao D M, Sun L G, Wang Y J, Du Y H, Wang C. Preparation and application of CdTe nanocrystals. Progress in Chemistry, 2012, 24(7): 1277–1293
[6]
Mahesh S, Gopal A, Thirumalai R, Ajayaghosh A. Light-induced Ostwald ripening of organic nanodots to rods. Journal of the American Chemical Society, 2012, 134(17): 7227–7230
CrossRef Pubmed Google scholar
[7]
Liu Z Q, Liu S P, Yan S G, Yin P F, He Y Q. Interaction between GSH-CdTe QDs and L-aspartic acid and its analytical application. Acta Chimica Sinica, 2011, 69(24): 2969–2974
CrossRef Google scholar
[8]
Ding T, Xu Y Q, Gu H, Liang Y R, Fang X M, Zhang L Q. Properties of poly(ethylene glycol)-based bioelastomers. Journal of Applied Polymer Science, 2010, 118(4): 2442–2447
CrossRef Google scholar
[9]
Zhang Y, Wu L B, Li B G. Synthesis and characterization of biodegradable crosslinked polymers from 5-hydroxylevulinic acid and α,ω-diols. Journal of Applied Polymer Science, 2010, 117(6): 3315–3321
CrossRef Google scholar
[10]
Wen H Y, Dong C Y, Dong H Q, Shen A J, Xia W J, Cai X J, Song Y, Li X, Li Y, Shi D. Engineered redox-responsive PEG detachment mechanism in PEGylated nano-graphene oxide for intracellular drug delivery. Small, 2012, 8(5): 760–769
CrossRef Google scholar
[11]
Liu Q Y, Jiang L, Shi R, Zhang L Q. Synthesis, preparation, in vitro degradation, and application of novel degradable bioelastomers-a review. Progress in Polymer Science, 2012, 37(5): 715–765
CrossRef Google scholar
[12]
Zhang Y, Tran R T, Qattan I S, Tsai Y T, Tang L, Liu C, Yang J. Fluorescence imaging enabled urethane-doped citrate-based biodegradable elastomers. Biomaterials, 2013, 34(16): 4048–4056
CrossRef Pubmed Google scholar

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 21063005, 50968005 and 51163003), and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry (No. 20091341)

RIGHTS & PERMISSIONS

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg
AI Summary AI Mindmap
PDF(357 KB)

Accesses

Citations

Detail

Sections
Recommended

/