Preparation of titanium dioxide-double-walled carbon nanotubes and its application in flexible dye-sensitized solar cells

Cunxi CHENG, Jihuai WU, Yaoming XIAO, Yuan CHEN, Haijun YU, Ziying TANG, Jianming LIN, Miaoliang HUANG

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Front. Optoelectron. ›› 2012, Vol. 5 ›› Issue (2) : 224-230. DOI: 10.1007/s12200-012-0198-5
RESEARCH ARTICLE

Preparation of titanium dioxide-double-walled carbon nanotubes and its application in flexible dye-sensitized solar cells

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Abstract

Titanium dioxide-double-walled carbon nanotubes (TiO2-DWCNTs) with DWCNTs/TiO2 of 20 wt.% is prepared by a conventional sol-gel method. Doping the TiO2-DWCNTs in TiO2 photoanode, a flexible dye-sensitized solar cell (DSSC) is fabricated. The sample is characterized by scanning electron microscopy, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) absorption, ultraviolet-visible spectroscopy (UV-vis) absorption spectra,electrochemical impedance spectroscopy (EIS) technique and photovoltaic measurement. It is found that adding a certain amount of TiO2-DWCNTs can efficiently decrease the resistance of charge transport, improve dye adsorption. Under an optimal condition, a flexible DSSC contained with 0.50 wt.% TiO2-DWCNTs achieves a light-to-electric energy conversion efficiency of 3.89% under a simulate solar light irradiation of 100 mW·cm-2.

Keywords

flexible dye-sensitized solar cell (DSSC) / titanium dioxide (TiO2) / double-walled carbon nanotube (DWCNT) / sol-gel method

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Cunxi CHENG, Jihuai WU, Yaoming XIAO, Yuan CHEN, Haijun YU, Ziying TANG, Jianming LIN, Miaoliang HUANG. Preparation of titanium dioxide-double-walled carbon nanotubes and its application in flexible dye-sensitized solar cells. Front Optoelec, 2012, 5(2): 224‒230 https://doi.org/10.1007/s12200-012-0198-5

References

[1]
O’Regan B, Grätzel M. A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature, 1991, 353(24): 737–739
CrossRef Google scholar
[2]
Grätzel M. Recent advances in sensitized mesoscopic solar cells. Accounts of Chemical Research, 2009, 42(11): 1788–1798
CrossRef Pubmed Google scholar
[3]
Lindstrom H, Holmberg A, Magnusson E, Malmqvist L, Hagfeldt A. A new method to make dye-sensitized nanocrystalline solar cells at room temperature. Journal of Photochemistry and Photobiology A: chemistry, 2001, 145(1–2): 107–112
[4]
Longo C, Freitas J, DePaoli M A. Performance and stability of TiO2/dye solar cells assembled with flexible electrodes and a polymer electrolyte. Journal of Photochemistry and Photobiology A: Chemistry, 2003, 159(1): 33–39
CrossRef Google scholar
[5]
Lindstrom H, Holmberg A, Magnusson E, Lindquist S E, Malmqvist L, Hagfeldt A. A new method for manufacturing nanostructured electrodes on plastic substrates. Nano Letters, 2001, 1(2): 97– 100
CrossRef Google scholar
[6]
Lee T Y, Alegaonkar P S, Yoo J B. Fabrication of dye sensitized solar cell using TiO2 coated carbon nanotubes. Thin Solid Films, 2007, 515(12): 5131–5135
CrossRef Google scholar
[7]
Muduli S, Lee W, Dhas V, Mujawar S, Dubey M, Vijayamohanan K, Han S H, Ogale S. Enhanced conversion efficiency in dye-sensitized solar cells based on hydrothermally synthesized TiO2/MWCNT nanocomposites. ACS Applied Materical and interfaces, 2009, 1(9): 2030–2035
[8]
Ha B, Shin D H, Park J, Lee C J. Electronic structure and field emission properties of double-walled carbon nanotubes synthesized by hydrogen arc discharge. Journal of Physical Chemistry C, 2008, 112(2): 430–435
CrossRef Google scholar
[9]
Endo M, Muramatsu H, Hayashi T, Kim Y A, Terrones M, Dresselhaus M S. Nanotechnology: ‘Buckypaper’ from coaxial nanotubes. Nature, 2005, 433(7025): 476–478
CrossRef Pubmed Google scholar
[10]
Cheng C X, Wu J H, Xiao Y M, Chen Y, Fan L Q, Huang M L, Lin J M, Wang J L, Tang Z Y, Yue G T. Polyvinyl pyrrolidone aided preparation of TiO2 films used in flexible dye-sensitized solar cells. Electrochimica Acta, 2011, 56(21): 7256–7260
CrossRef Google scholar
[11]
Gao B, Chen G Z, Li G. Carbon nanotubes/titanium dioxide (CNTs/TiO2) nanocomposites prepared by conventional and novel surfactant wrapping sol–gel methods exhibiting enhanced photocatalytic activity. Applied Catalysis B: Environmental, 2009, 89(3–4): 503–509
CrossRef Google scholar
[12]
Grätzel M. Perspectives for dye-sensitized nanocrystalline solar cells. Progress in Photovoltaics: Research and Applications, 2000, 8(1): 171–185
CrossRef Google scholar
[13]
Brozena A H, Moskowitz J, Shao B, Deng S, Liao H, Gaskell K J, Wang Y H. Outer wall selectively oxidized, water-soluble double-walled carbon nanotubes. Journal of the American Chemical Society, 2010, 132(11): 3932–3938
CrossRef Pubmed Google scholar
[14]
Yu Y, Yu J C, Yu J G, Kwok Y C, Che Y K, Zhao J C, Ding L, Ge W K, Wong P K. Enhancement of photocatalytic activity of mesoporous TiO2 by using carbon nanotubes Appl. Catal. A, 2005, 289(2): 186–196
CrossRef Google scholar
[15]
Wu J H, Li P J, Hao S C, Yang H X, Lan Z. A polyblend electrolyte(PVP/PEG+KI+I2) for dye-sensitized nanocrystalline TiO2 solar cells. Electrochimica Acta, 2007, 52(17): 5334–5338
CrossRef Google scholar
[16]
Jitianu A, Cacciaguerra T, Benoit R, Delpeux S, Béguin F, Bonnamy S. Synthesis and characterization of carbon nanotubes-TiO2 nanocomposites. Carbon, 2004, 42(5–6): 1147–1151
CrossRef Google scholar
[17]
Yen C Y, Lin Y F, Hung C H, Tseng Y H, Ma C C, Chang M C, Shao H. The effects of synthesis procedures on the morphology and photocatalytic activity of multi-walled carbon nanotubes/TiO2 nanocomposites. Nanotechnology, 2008, 19(4): 045604
CrossRef Pubmed Google scholar
[18]
Yen C Y, Lin Y F, Liao S H, Weng C C, Huang C C, Hsiao Y H, Ma C C, Chang M C, Shao H, Tsai M C, Hsieh C K, Tsai C H, Weng F B. Preparation and properties of a carbon nanotube-based nanocomposite photoanode for dye-sensitized solar cells. Nanotechnology, 2008, 19(37): 375305
CrossRef Pubmed Google scholar
[19]
Sawatsuk T, Chindaduang A, Sae-kung C, Pratontep S, Tumcharern G. Dye-sensitized solar cells based on TiO2-MWCNTs composite electrodes: Performance improvement and their mechanisms. Diamond and Related Materials, 2009, 18(2–3): 524–527
CrossRef Google scholar
[20]
Lee K M, Hu C W, Chen H W, Ho K C. Incorporating carbon nanotube in a low-temperature fabrication process for dye-sensitized TiO2 solar cells. Solar Energy Materials and Solar Cells, 2008, 92(12): 1628–1633
CrossRef Google scholar
[21]
Zhang D S, Downing J A, Knorr F J, McHale J L. Room-temperature preparation of nanocrystalline TiO2 films and the influence of surface properties on dye-sensitized solar energy conversion. Journal of Physical Chemistry B, 2006, 110(43): 21890–21898
[22]
Hsu C P, Lee K M, Huang J T W, Lin C Y, Lee C H, Wang L P, Tsai S Y, Ho K C. EIS analysis on low temperature fabrication of TiO2 porous films for dye-sensitized solar cells. Electrochimica Acta, 2008, 53(25): 7514–7522

Acknowledgements

This work was supported by the National High Technology Research and Development Program of China (No. 2009AA03Z217), and the National Natural Science Foundation of China (Grant Nos. 90922028, 50842027).

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2014 Higher Education Press and Springer-Verlag Berlin Heidelberg
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