Characterization of spectra of lignin from midribs of tobacco at THz frequencies
Tongfu SU, Bin YU, Pengyu HAN, Guozhong ZHAO, Changrong GONG
Characterization of spectra of lignin from midribs of tobacco at THz frequencies
The functions of the chemicals are closely related with their compositions and structures. In this paper, we report the characterization of different lignin in the midribs of tobacco leaves using terahertz (THz) time-domain spectroscopy in the frequency range of 0.3 to 2 THz. These lignins are extracted from tobacco leaves grown in different regions. Lignin in midribs of tobacco leaves from the south region and the north region show distinctively different refractive indexes and absorption coefficients at THz frequency. The differences at THz range are found to be correlated with their chemical compositions, which are obtained by way of X-ray micro-analysis. This clearly verifies that it is possible to employ THz time-domain spectroscopy as a tool for identifying the functions of the chemicals and analyzing their chemical compositions.
terahertz (THz) spectroscopy / lignin / X-ray microanalysis / midribs of tobacco / scanning electron microscope (SEM)
[1] |
Mittleman D M, Gupta M, Neelamani R, Baraniuk R G, Rudd J V, Koch M. Recent advances in terahertz imaging. Applied Physics B: Lasers and Optics, 1999, 68(6): 1085-1094
|
[2] |
Hoshina H, Hayashi A, Miyoshi N, Miyamaru F, Otani C. Terahertz pulsed imaging of frozen biological tissues. Applied Physics Letters, 2009, 94(12): 123901
|
[3] |
Nagel M, Richter F, Haring-Bolivar P, Kurz H. A functionalized THz sensor for marker-free DNA analysis. Physics in Medicine and Biology, 2003, 48(22): 3625-3636
|
[4] |
Woodward R M, Wallace V P, Arnone D D, Linfield E H, Pepper M. Terahertz pulsed imaging of skin cancer in the time and frequency domain. Journal of Biological Physics, 2003, 29(2-3): 257-259
|
[5] |
Kawase K, Ogawa Y, Watanabe Y, Inoue H. Non-destructive terahertz imaging of illicit drugs using spectral fingerprints. Optics Express, 2003, 11(20): 2549-2554
|
[6] |
Bigourd D, Cuisset A, Hindle F, Matton S, Fertein E, Bocquet R, Mouret G. Detection and quantification of multiple molecular species in mainstream cigarette smoke by continuous-wave terahertz spectroscopy. Optics Letters, 2006, 31(15): 2356-2358
|
[7] |
Globus T, Woolard D, Crowe T W, Khromova T, Gelmont B, Hesler J. Terahertz Fourier transform characterization of biological materials in a liquid phase. Journal of Physics D: Applied Physics, 2006, 39(15): 3405-3413
|
[8] |
Markelz A G, Whitmire S E. Terahertz applications to biomolecular sensing. International Journal of High Speed Electronics and Systems, 2003, 13(4): 951-967
|
[9] |
Krumbholz N, Hochrein T, Vieweg N, Hasek T, Kretschmer K, Bastian M, Mikulics M, Koch M. Monitoring polymeric compounding processes inline with THz time-domain spectroscopy. Polymer Testing, 2009, 28(1): 30-35
|
[10] |
Taday P F, Bradley I V, Arnone D D, Pepper M. Using terahertz pulse spectroscopy to study the crystalline structure of a drug: a case study of the polymorphs of ranitidine hydrochloride. Journal of Pharmaceutical Sciences, 2003, 92(4): 831-838
|
[11] |
Chan T L J, Bjarnason J E, Lee A W M, Celis M A, Brown E R. Attenuation contrast between biomolecular and inorganic materials at terahertz frequencies. Applied Physics Letters, 2004, 85(13): 2523-2525
|
[12] |
Knab J R, Chen J Y, Ye S J, He Y F, Markelz A G. Protein conformational dynamics measured with terahertz time domain spectroscopy. In: Proceedings of Joint 31st International Conference on Infrared Millimeter Waves and 14th International Conference on Terahertz Electronics, 2006, 183
|
[13] |
Su T F, Jia X F, Zhao G Z, Han P Y, Li Y L, Gong C R. A study on terahertz absorption spectra of alcohol and water midribs of tobacco. Journal of Instrumental Analysis, 2008, 27(5): 458-462 (in Chinese)
|
[14] |
Su T F, Jia X F, Zhao G Z, Han P Y, Wang Y J, Li Y L, Zhou B, Song C P, Chang J F, Gong C R. Characterization of original and expanded leaf-roots of tobacco by terahertz spectroscopy and X-ray microanalysis. Materials Letters, 2008, 62(17-18): 2779-2782
|
[15] |
Png G M, Flook R, Ng B W-H, Abbott D. Terahertz spectroscopy of snap-frozen human brain tissue: an initial study. Electronics Letters, 2009, 45(7): 343-345
|
[16] |
Yang J H, Huang B. Progress in application of modification and high additional value of lignin. Subtropical Agricultural Research, 2006, 2(3): 226-230 (in Chinese)
|
[17] |
LI X F. Researches and developments in oilfield chemicals derived from lignin. Oilfield Chemistry, 2006, 23(2): 180-183 (in Chinese)
|
[18] |
Jiang Y, Satoh K, Aratsu C, Kobayashi N, Unten S, Kakuta H, Kikuchi H, Nishikawa H, Ochiai K, Sakagami H. Combination effect of lignin F and natural products. Anticancer Research, 2001, 21(2A): 965-970
|
[19] |
Filov V A, Reztsova V V, Kil’maeva N E, Petukhov D V, Pinchuk B T. An experimental study of the antitumor properties of olipifat. Voprosy Onkologii, 2000, 46(3): 332-336
|
[20] |
Shi X X, Zhao G Z. Analysis of time-resolved terahertz spectroscopy of explosives. Modem Scientific Instruments, 2006, 2(2): 48-50 (in Chinese)
|
/
〈 | 〉 |