Visible-light-driven heterostructured g-C₃N₄/Bi-TiO₂ floating photocatalyst with enhanced charge carrier separation for photocatalytic inactivation of Microcystis aeruginosa

Abstract

• Bi doping in TiO₂ enhanced the separation of photo-generated electron-hole.

• The performance of photocatalytic degradation of MC-LR was improved.

• Coexisting substances have no influence on algal removal performance.

• The key reactive oxygen species were h⁺ and ^•OH in the photocatalytic process.

The increase in occurrence and severity of cyanobacteria blooms is causing increasing concern; moreover, human and animal health is affected by the toxic effects of Microcystin-LR released into the water. In this paper, a floating photocatalyst for the photocatalytic inactivation of the harmful algae Microcystis aeruginosa (M. aeruginosa) was prepared using a simple sol-gel method, i.e., coating g-C₃N₄ coupled with Bi-doped TiO₂ on Al₂O₃-modified expanded perlite (CBTA for short). The impact of different molar ratios of Bi/Ti on CBTA was considered. The results indicated that Bi doping in TiO₂ inhibited photogenerated electron-hole pair recombination. With 6 h of visible light illumination, 75.9% of M. aeruginosa (initial concentration= 2.7 × 10⁶ cells/L) and 83.7% of Microcystin-LR (initial concentration= 100 μg/L) could be removed with the addition of 2 g/L CBTA-1% (i.e., Bi/Ti molar ratio= 1%). The key reactive oxygen species (ROSs) in the photocatalytic inactivation process are h⁺ and ^•OH. The induction of the Bi⁴⁺/Bi³⁺ species by the incorporation of Bi could narrow the bandgap of TiO₂, trap electrons, and enhance the stability of CBTA-1% in the solutions with coexisting environmental substances.

Graphical abstract

Keywords

Bi doping / Visible light / Algal removal / Charge carrier separation

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