Characterization of chlorine and heavy metals for the potential recycling of bottom ash from municipal solid waste incinerators as cement additives

Abstract

Industrial waste mixed with MSW is the main source of heavy metal in bottom ash.

Chlorine content in bottom ash is controlled both by plastic and kitchen waste.

Insoluble chlorine in Chinese MSWI bottom ash exists primarily as AlOCl.

Bottom ash is an inevitable by-product from municipal solid waste (MSW) incineration plants. Recycling it as additives for cement production is a promising disposal method. However, the heavy metals and chlorine are the main limiting factors because of the potential environmental risks and corrosion of cement kilns. Therefore, investigating heavy metal and chlorine characteristics of bottom ash is the significant prerequisite of its reuse in cement industries. In this study, a correlative analysis was conducted to evaluate the effect of the MSW components and collection mode on the heavy metal and chlorine characteristics in bottom ash. The chemical speciation of insoluble chlorine was also investigated by synchrotron X-ray diffraction analysis. The results showed that industrial waste was the main source of heavy metals, especially Cr and Pb, in bottom ash. The higher contents of plastics and kitchen waste lead to the higher chlorine level (0.6 wt.%–0.7 wt.%) of the bottom ash. The insoluble chlorine in the MSW incineration bottom ash existed primarily as AlOCl, which was produced under the high temperature (1250℃) in incinerators.

Graphical abstract

Keywords

Bottom ash / Chlorine / Heavy metals / Waste inputs / Synchrotron X-ray diffraction / AlOCl

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Higher Education Press and Springer-Verlag Berlin Heidelberg