Indoor carbonyl compounds in an academic building in Beijing, China: concentrations and influencing factors

Chuanjia JIANG, Pengyi ZHANG

PDF(189 KB)
PDF(189 KB)
Front. Environ. Sci. Eng. ›› 2012, Vol. 6 ›› Issue (2) : 184-194. DOI: 10.1007/s11783-011-0309-3
RESEARCH ARTICLE
RESEARCH ARTICLE

Indoor carbonyl compounds in an academic building in Beijing, China: concentrations and influencing factors

Author information +
History +

Abstract

Carbonyl compounds in indoor air are of great concern for their adverse health effects. Between February and May, 2009, concentrations of 13 carbonyl compounds were measured in an academic building in Beijing, China. Total concentration of the detected carbonyls ranged from 20.7 to 189.1 μg·m-3, and among them acetone and formaldehyde were the most abundant, with mean concentrations of 26.4 and 22.6 μg·m-3, respectively. Average indoor concentrations of other carbonyls were below 10 μg·m-3. Principal component analysis identified a combined effect of common indoor carbonyl sources and ventilation on indoor carbonyl levels. Diurnal variations of the carbonyl compounds were investigated in one office room, and carbonyl concentrations tended to be lower in the daytime than at night, due to enhanced ventilation. Average concentrations of carbonyl compounds in the office room were generally higher in early May than in late February, indicating the influence of temperature. Carbonyl source emission rates from both the room and human occupants were estimated during two lectures, based on one-compartment mass balance model. The influence of human occupants on indoor carbonyl concentrations varies with environmental conditions, and may become significant in the case of a large human occupancy.

Keywords

carbonyl compounds / indoor air / ventilation / human occupancy / source emission rate (SER) / principal component analysis (PCA)

Cite this article

Download citation ▾
Chuanjia JIANG, Pengyi ZHANG. Indoor carbonyl compounds in an academic building in Beijing, China: concentrations and influencing factors. Front Envir Sci Eng, 2012, 6(2): 184‒194 https://doi.org/10.1007/s11783-011-0309-3

References

[1]
Weng M L, Zhu L Z, Yang K, Chen S G. Levels and health risks of carbonyl compounds in selected public places in Hangzhou, China. Journal of Hazardous Materials, 2009, 164(2-3): 700-706
CrossRef Pubmed Google scholar
[2]
Zhang J, Lioy P J,He Q C. Characteristics of aldehydes: concentrations, sources, and exposures for indoor and outdoor residential microenvironments. Environmental Science & Technology, 1994, 28(1): 146-152
CrossRef Google scholar
[3]
Reiss R, Ryan P B, Tibbetts S J, Koutrakis P. Measurement of organic acids, aldehydes, and ketones in residential environments and their relation to ozone. Journal of the Air & Waste Management Association, 1995, 45(10): 811-822
Pubmed
[4]
Subramanian P, Breuer G M, Reynolds S J. Low molecular weight carbonyls in large midwestern office buildings. International Journal of Environmental Analytical Chemistry, 2000, 76(3): 215-239
CrossRef Google scholar
[5]
Sawant A A, Na K, Zhu X N, Cocker K, Butt S, Song C, Cocker D R III. Characterization of PM2.5 and selected gas-phase compounds at multiple indoor and outdoor sites in Mira Loma, California. Atmospheric Environment, 2004, 38(37): 6269-6278
CrossRef Google scholar
[6]
Sax S N, Bennett D H, Chillrud S N, Kinney P L, Spengler J D. Differences in source emission rates of volatile organic compounds in inner-city residences of New York City and Los Angeles. Journal of Exposure Analysis and Environmental Epidemiology, 2004, 14(Suppl 1): S95-S109
CrossRef Pubmed Google scholar
[7]
Liu W, Zhang J, Zhang L, Turpin B J, Welsel C P, Morandi M T, Stock T H, Colome S, Korn L R. Estimating contributions of indoor and outdoor sources to indoor carbonyl concentrations in three urban areas of the United States. Atmospheric Environment, 2006, 40(12): 2202-2214
CrossRef Google scholar
[8]
Báez A, Padilla H, García R, Torres M C, Rosas I, Belmont R. Carbonyl levels in indoor and outdoor air in Mexico City and Xalapa, Mexico. Science of the Total Environment, 2003, 302(1-3): 211-226
CrossRef Pubmed Google scholar
[9]
Jurvelin J A, Edwards R D, Vartiainen M, Pasanen P, Jantunen M J. Residential indoor, outdoor, and workplace concentrations of carbonyl compounds: relationships with personal exposure concentrations and correlation with sources. Journal of the Air & Waste Management Association, 2003, 53(5): 560-573
Pubmed
[10]
Santarsiero A, Fuselli S. Indoor and outdoor air carbonyl compounds correlation elucidated by principal component analysis. Environmental Research, 2008, 106(2): 139-147
CrossRef Pubmed Google scholar
[11]
Ohura T, Amagai T, Senga Y, Fusaya M. Organic air pollutants inside and outside residences in Shimizu, Japan: levels, sources and risks. Science of the Total Environment, 2006, 366(2-3): 485-499
CrossRef Pubmed Google scholar
[12]
Clarisse B, Laurent A M, Seta N, Le Moullec Y, El Hasnaoui A, Momas I. Indoor aldehydes: measurement of contamination levels and identification of their determinants in Paris dwellings. Environmental Research, 2003, 92(3): 245-253
CrossRef Pubmed Google scholar
[13]
Marchand C, Buillot B, Le Calve S, Mirabel P. Aldehyde measurements in indoor environments in Strasbourg (France). Atmospheric Environment, 2006, 40(7): 1336-1345
CrossRef Google scholar
[14]
Marchand C, Le Calve S, Mirabel P, Glasser N, Casset A, Schneider N, de Blay F. Concentrations and determinants of gaseous aldehydes in 162 homes in Strasbourg (France). Atmospheric Environment, 2008, 42(3): 505-516
CrossRef Google scholar
[15]
Dassonville C, Demattei C, Laurent A M, Le Moullec Y, Seta N, Momas I. Assessment and predictor determination of indoor aldehyde levels in Paris newborn babies’ homes. Indoor Air, 2009, 19(4): 314-323
CrossRef Pubmed Google scholar
[16]
Cavalcante R M, Campelo C S, Barbosa M J, Silveira E R, Carvalho T V, Nascimento R F. Determination of carbonyl compounds in air and cancer risk assessment in an academic institute in Fortaleza, Brazil. Atmospheric Environment, 2006, 40(29): 5701-5711
CrossRef Google scholar
[17]
Feng Y L, Wen S, Wang X M, Sheng G Y, He Q S, Tang J H, Fu J M. Indoor and outdoor carbonyl compounds in the hotel ballrooms in Guangzhou, China. Atmospheric Environment, 2004, 38(1): 103-112
CrossRef Google scholar
[18]
Lü H X, Wen S, Feng Y L, Wang X N, Bi X H, Sheng G Y, Fu J M. Indoor and outdoor carbonyl compounds and BTEX in the hospitals of Guangzhou, China. Science of the Total Environment, 2006, 368(2-3): 574-584
CrossRef Pubmed Google scholar
[19]
Wang B, Lee S C, Ho K F, Kang Y M. Characteristics of emissions of air pollutants from burning of incense in temples, Hong Kong. Science of the Total Environment, 2007, 377(1): 52-60
CrossRef Pubmed Google scholar
[20]
Pang X B, Mu Y J. Characteristics of carbonyl compounds in public vehicles of Beijing city: concentrations, sources, and personal exposures. Atmospheric Environment, 2007, 41(9): 1819-1824
CrossRef Google scholar
[21]
Wang B, Lee S C, Ho K F. Characteristics of carbonyls: concentrations and source strengths for indoor and outdoor residential microenvironments in China. Atmospheric Environment, 2007, 41(13): 2851-2861
CrossRef Google scholar
[22]
US Environmental Protection Agency (US EPA). Compendium Method TO-11A. Determination of Formaldehyde in Ambient Air Using Adsorbent Cartridge followed by High Performance Liquid Chromatography (HPLC) [Active Sampling Methodology], 1999
[23]
Gilbert N L, Guay M, David Miller J, Judek S, Chan C C, Dales R E. Levels and determinants of formaldehyde, acetaldehyde, and acrolein in residential indoor air in Prince Edward Island, Canada. Environmental Research, 2005, 99(1): 11-17
CrossRef Pubmed Google scholar
[24]
Seaman V Y, Bennett D H, Cahill T M. Origin, occurrence, and source emission rate of acrolein in residential indoor air. Environmental Science & Technology, 2007, 41(20): 6940-6946
CrossRef Pubmed Google scholar
[25]
Nazaroff W W, Cass G R. Mathematical modeling of chemically reactive pollutants in indoor air. Environmental Science & Technology, 1986, 20(9): 924-934
CrossRef Google scholar
[26]
Ongwandee M, Moonrinta R, Panyametheekul S, Tangbanluekal C, Morrison G. Concentrations and strengths of formaldehyde and acetaldehyde in office buildings in Bangkok, Thailand. Indoor and Built Environment, 2009, 18(6): 569-575
CrossRef Google scholar
[27]
Seaman V Y, Charles M J, Cahill T M. A sensitive method for the quantification of acrolein and other volatile carbonyls in ambient air. Analytical Chemistry, 2006, 78(7): 2405-2412
CrossRef Pubmed Google scholar
[28]
Weschler C J. Ozone in indoor environments: concentration and chemistry. Indoor Air, 2000, 10(4): 269-288
CrossRef Pubmed Google scholar
[29]
Phillips M, Herrera J, Krishnan S, Zain M, Greenberg J, Cataneo R N. Variation in volatile organic compounds in the breath of normal humans. Journal of Chromatography. B, Analytical Technologies in the Biomedical and Life Sciences, 1999, 729(1-2): 75-88
CrossRef Pubmed Google scholar
[30]
Curran A M, Rabin S I, Prada P A, Furton K G. Comparison of the volatile organic compounds present in human odor using SPME-GC/MS. Journal of Chemical Ecology, 2005, 31(7): 1607-1619
CrossRef Pubmed Google scholar
[31]
Weisel C P, Alimokhtari S, Sanders P F. Indoor air VOC concentrations in suburban and rural New Jersey. Environmental Science & Technology, 2008, 42(22): 8231-8238
CrossRef Pubmed Google scholar
[32]
Petrick L, Dubowski Y. Heterogeneous oxidation of squalene film by ozone under various indoor conditions. Indoor Air, 2009, 19(5): 381-391
CrossRef Pubmed Google scholar
[33]
Wisthaler A, Weschler C J. Reactions of ozone with human skin lipids: sources of carbonyls, dicarbonyls, and hydroxycarbonyls in indoor air. In: Proceedings of the National Academy of Sciences of the United States of America, 2010, 107(15): 6568-6575
CrossRef Pubmed Google scholar
[34]
Pandrangi L S, Morrison G C. Ozone interactions with human hair: ozone uptake rates and product formation. Atmospheric Environment, 2008, 42(20): 5079-5089
CrossRef Google scholar
[35]
Wisthaler A, Tamás G, Wyon D P, Strøm-Tejsen P, Space D, Beauchamp J, Hansel A, Märk T D, Weschler C J. Products of ozone-initiated chemistry in a simulated aircraft environment. Environmental Science & Technology, 2005, 39(13): 4823-4832
CrossRef Pubmed Google scholar
[36]
Coleman B K, Destaillats H, Hodgson A T, Nazaroff W W. Ozone consumption and volatile byproduct formation from surface reactions with aircraft cabin materials and clothing fabrics. Atmospheric Environment, 2008, 42(4): 642-654
CrossRef Google scholar
[37]
Turner C, Spanel P, Smith D. A longitudinal study of ammonia, acetone and propanol in the exhaled breath of 30 subjects using selected ion flow tube mass spectrometry, SIFT-MS. Physiological Measurement, 2006, 27(4): 321-337
CrossRef Pubmed Google scholar
[38]
Kinoyama M, Nitta H, Watanabe A, Ueda H. Acetone and isoprene concentrations in exhaled breath in healthy subjects. Journal of Health Science, 2008, 54(4): 471-477
CrossRef Google scholar
[39]
Schwarz K, Pizzini A, Arendacka B, Zerlauth K, Filipiak W, Schmid A, Dzien A, Neuner S, Lechleitner M, Scholl-Burgi S, Miekisch W, Schubert J, Unterkofler K, Witkovsky V, Gastl G, Amann A. Breath acetone-aspects of normal physiology related to age and gender as determined in a PTR-MS study. Journal of Breath Research, 2009, 3(2): 027003
[40]
Naitoh K, Tsuda T, Nose K, Kondo T, Takasu A, Hirabayashi T. New measurement of hydrogen gas and acetone vapor in gases emanating from human skin. Instrumentation Science & Technology, 2002, 30(3): 267-280
CrossRef Google scholar
[41]
Sekine Y, Toyooka S, Watts S F. Determination of acetaldehyde and acetone emanating from human skin using a passive flux sampler—HPLC system. Journal of Chromatography. B, Analytical Technologies in the Biomedical and Life Sciences, 2007, 859(2): 201-207
CrossRef Pubmed Google scholar
[42]
Nazaroff W W. Inhalation intake fraction of pollutants from episodic indoor emissions. Building and Environment, 2008, 43(3): 269-277
CrossRef Google scholar
[43]
Weschler C J, Wisthaler A, Cowlin S, Tamás G, Strøm-Tejsen P, Hodgson A T, Destaillats H, Herrington J, Zhang J J, Nazaroff W W. Ozone-initiated chemistry in an occupied simulated aircraft cabin. Environmental Science & Technology, 2007, 41(17): 6177-6184
CrossRef Pubmed Google scholar
[44]
Lin Y M, Dueker S R, Jones A D, Ebeler S E, Clifford A J. Protocol for collection and HPLC analysis of volatile carbonyl compounds in breath. Clinical Chemistry, 1995, 41(7): 1028-1032
Pubmed
[45]
Fuchs P, Loeseken C, Schubert J K, Miekisch W. Breath gas aldehydes as biomarkers of lung cancer. International Journal of Cancer, 2010, 126(11): 2663-2670
Pubmed

Acknowledgements

This work was funded by the Special Fund of State Key Joint Laboratory of Environmental Simulation and Pollution Control of China (No. 08Y02ESPCT).

RIGHTS & PERMISSIONS

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg
AI Summary AI Mindmap
PDF(189 KB)

Accesses

Citations

Detail

Sections
Recommended

/