Frontiers of Chemical Science and Engineering >

2009 , Vol. 3 >Issue 2: 219 - 221

DOI: https://doi.org/10.1007/s11705-009-0058-z

RESEARCH ARTICLE

Study on a green synthesis of μ-oxo-bis[tetraarylphenylporphyrinatoiron]

  • Aixin WANG ,
  • Yuanbin SHE ,
  • Jing FAN
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  • Institute of Green Chemistry and Fine Chemicals, Beijing University of Technology, Beijing 100124, China

Received date: 17 May 2008

Accepted date: 15 Oct 2008

Published date: 05 Jun 2009

Copyright

2014 Higher Education Press and Springer-Verlag Berlin Heidelberg
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Abstract

A novel method for the synthesis of μ-oxo-bis[tetraarylporphyrinatoiron] ([TRPPFe]2O) based on the reaction between tetraarylporphyrinironchloride (TRPPFeCl) and H2O in toluene was investigated in this paper. Three kinds of [TRPPFe]2O were synthesized by this novel synthetic method, and their structures were characterized by elemental analysis, IR spectra and UV-Vis spectroscopy.

Key words： μ-oxo-bis[tetraarylphenylporphinatoiron]; green synthesis; water

Cite this article

Aixin WANG , Yuanbin SHE , Jing FAN . Study on a green synthesis of μ-oxo-bis[tetraarylphenylporphyrinatoiron][J]. Frontiers of Chemical Science and Engineering, 2009 , 3(2) : 219 -221 . DOI: 10.1007/s11705-009-0058-z

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grants Nos. 20776003 and 20576005) and the Key Project of Natural Science Foundation of Beijing (No. 2061001).

References

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