Frontiers of Chemical Science and Engineering >
Sustainable H2 production from ethanol steam reforming over a macro-mesoporous Ni/Mg-Al-O catalytic monolith
Received date: 06 Dec 2012
Accepted date: 12 May 2013
Published date: 05 Sep 2013
Copyright
A macro-meso-porous monolithic Ni-based catalyst was prepared via an impregnation route using polystyrene foam as the template and then used in the steam reforming of ethanol to produce a H2-rich gas. The Ni/Mg-Al catalyst has a hierarchically macro-meso-porous structure as indicated by photographs and scanning electron microscopy (SEM). The surface area of the catalyst was 230 m2∙g-1 and the Ni dispersion was 5.62%. Compared to the pelletized sample that was prepared without a template, the macro-meso-porous Ni/Mg-Al monolith exhibited superior reactivity in terms of H2 production and also had lower CH4 yields at 700ºC and 800ºC. Furthermore, the monolithic catalyst maintained excellent activity and H2 selectivity after 100-h on-stream at 700oC, as well as good resistance to coking and metal sintering.
Ruixue GU , Guangming ZENG , Jingjing SHAO , Yuan LIU , Johannes W. Schwank , Yongdan LI . Sustainable H2 production from ethanol steam reforming over a macro-mesoporous Ni/Mg-Al-O catalytic monolith[J]. Frontiers of Chemical Science and Engineering, 2013 , 7(3) : 270 -278 . DOI: 10.1007/s11705-013-1337-2
| 1 |
Breen J P, Ross J R H. Methanol reforming for fuel-cell applications: Development of zirconia-containing Cu–Zn–Al catalysts. Catalysis Today, 1999, 51(3-4): 521-533
|
| 2 |
Li Y D, Rui Z B, Xia C, Anderson M, Lin Y S. Performance of ionic-conducting ceramic/carbonate composite material as solid oxide fuel cell electrolyte and CO2 permeation membrane. Catalysis Today, 2009, 148(3-4): 303-309
|
| 3 |
Xia C, Li Y, Tian Y, Liu Q H, Wang Z M, Jia L J, Zhao Y C, Li Y D. Intermediate temperature fuel cell with a doped ceria-carbonate composite electrolyte. Journal of Power Sources, 2010, 195(10): 3149-3154
|
| 4 |
Cribb P H, Dove J E, Yamazaki S. A kinetic study of the oxidation of methanol using shock tube and computer simulation techniques. Combustion and Flame, 1992, 88(2): 186-200
|
| 5 |
Armor J N. The multiple roles for catalysis in the production of H2. Applied Catalysis A, General, 1999, 176(2): 159-176
|
| 6 |
Vaidya P D, Rodrigues A E. Insight into steam reforming of ethanol to produce hydrogen for fuel cells. Chemical Engineering Journal, 2006, 117(1): 39-49
|
| 7 |
Barroso M N, Galetti A E, Abello M C. Ni catalysts supported over MgAl2O4 modified with Pr for hydrogen production from ethanol steam reforming. Applied Catalysis A: General, 2011, 394(1-2): 124-131
|
| 8 |
Barroso M N, Gomez M E, Arrua L A, Abello M C. Hydrogen production by ethanol reforming over NiZnAl catalysts. Applied Catalysis A, General, 2006, 304: 116-123
|
| 9 |
Sehested J. Four challenges for nickel steam-reforming catalysts. Catalysis Today, 2006, 111(1-2): 103-110
|
| 10 |
Sun J, Qui X P, Wu F, Zhu W T. H2 from steam reforming of ethanol at low temperature over Ni/Y2O3, Ni/La2O3 and Ni/Al2O3 catalysts for fuel-cell application. International Journal of Hydrogen Energy, 2005, 30(4): 437-445
|
| 11 |
Fatsikostas A N, Kondarides D I, Verykios X E. Production of hydrogen for fuel cells by reformation of biomass-derived ethanol. Catalysis Today, 2002, 75(1-4): 145-155
|
| 12 |
Yang G H, Tsubaki N, Shamoto J, Yoneyama Y, Zhang Y. Confinement effect and synergistic function of H-ZSM-5/Cu-ZnO-Al2O3 capsule catalyst for one-step controlled synthesis. Journal of the American Chemical Society, 2010, 132(23): 8129-8136
|
| 13 |
Guliants V V, Carreon M A, Lin Y S. Ordered mesoporous and macroporous inorganic films and membranes. Journal of Membrane Science, 2004, 235(1-2): 53-72
|
| 14 |
Kucharczyk B, Tylus W, Kepiński L. Pd-based monolithic catalysts on metal supports for catalytic combustion of methane. Applied Catalysis B: Environmental, 2004, 49(1): 27-37
|
| 15 |
Giroux T, Hwang S, Liu Y, Ruettinger W, Shore L. Monolithic structures as alternatives to particulate catalysts for the reforming of hydrocarbons for hydrogen generation. Applied Catalysis B: Environmental, 2005, 56(1-2): 95-110
|
| 16 |
Ryu J H, Lee K Y, La H, Kim H J, Yang J, Jung H. Ni catalyst wash-coated on metal monolith with enhanced heat-transfer capability for steam reforming. Journal of Power Sources, 2007, 171(2): 499-505
|
| 17 |
Wu P Y, Li X J, Ji S F, Lang B, Habimana F, Li C Y. Steam reforming of methane to hydrogen over Ni-based metal monolith catalysts. Catalysis Today, 2009, 146(1-2): 82-86
|
| 18 |
Imhof A, Pine D J. Ordered macroporous materials by emulsion templating. Nature, 1997, 389(6654): 948-951
|
| 19 |
Imhof A, Pine D J. Uniform macroporous ceramics and plastics by emulsion templating. Advanced Materials, 1998, 10(9): 697-700
|
| 20 |
Holland B T, Blanford C F, Stein A. Synthesis of macroporous minerals with highly ordered three-dimensional arrays of spheroidal voids. Science, 1998, 281(5376): 538-540
|
| 21 |
Stein A, Schroden R C. Colloidal crystal templating of three-dimensionally ordered macroporous solids: materials for photonics and beyond. Current Opinion in Solid State and Materials Science, 2001, 5(6): 553-564
|
| 22 |
Maekawa H, Esquena J, Bishop S, Solans C, Chmelka B F. Meso/macroporous inorganic oxide monoliths from polymer foams. Advanced Materials, 2003, 15(78): 591-596
|
| 23 |
Li F, Wang Z, Ergang N S, Fyfe C A, Stein A. Controlling the shape and alignment of mesopores by confinement in colloidal crystals: Designer pathways to silica monoliths with hierarchical porosity. Langmuir, 2007, 23(7): 3996-4004
|
| 24 |
Chen S L, Dong P, Xu K, Qi Y, Wang D. Large pore heavy oil processing catalysts prepared using colloidal particles as templates. Catalysis Today, 2007, 125(3-4): 143-148
|
| 25 |
Zhang Y, Zhao C Y, Liang H, Liu Y. Macroporous monolithic Pt/g-Al2O3 and K-Pt/g-Al2O3 catalysts used for preferential oxidation of CO. Catalysis Letters, 2009, 127(3-4): 339-347
|
| 26 |
Ren J, Du Z J, Zhang C, Li H Q. Macroporous titania monolith prepared via sol-gel process with polymer foam as the template. Chinese Journal of Chemistry, 2006, 24(7): 955-960
|
| 27 |
Freni S, Cavallaro S, Mondello N, Spadaro L, Frusteri F. Steam reforming of ethanol on Ni/MgO catalysts: H2 production for MCFC. Journal of Power Sources, 2002, 108(1-2): 53-57
|
| 28 |
Liang H, Zhang Y, Liu Y. Monolithic macroporous catalysts—A new route for miniaturization of water-gas shift reactor. Journal of Natural Gas Chemistry, 2009, 18(4): 436-440
|
| 29 |
He L, Berntsen H, Ferna’ndez E O, Walmsley J C, Blekkan E A, Chen D. Co-Ni Catalysts Derived from Hydrotalcite-Like Materials for Hydrogen Production by Ethanol Steam Reforming. Topics in Catalysis, 2009, 52(3): 206-217Co-Ni catalysts derived from hydrotalcite-like materials for hydrogen production by ethanol steam reforming
|
| 30 |
Wang C G, Wang T J, Ma L L, Gao Y, Wu C Z. Steam reforming of biomass raw fuel gas over NiO-MgO solid solution cordierite monolith catalyst. Energy Conversion and Management, 2010, 51(3): 446-450
|
| 31 |
Hwang C P, Ye C Y. Platinum-oxide species formed by oxidation of platinum crystallites supported on alumina. Journal of Molecular Catalysis A Chemical, 1996, 112(2): 295-302
|
| 32 |
Yang J, Ryu J H, Lee K Y, Jung N J, Park J C, Chun D H, Kim H J, Yang J H, Lee H T, Cho I, Jung H. Combined pre-reformer/reformer system utilizing monolith catalysts for hydrogen production. International Journal of Hydrogen Energy, 2011, 36(15): 8850-8856
|
| 33 |
Coleman L J I, Epling W, Hudgins R R, Croset E. Ni/Mg-Al mixed oxide catalyst for the steam reforming of ethanol. Applied Catalysis A, General, 2009, 363(1-2): 52-63
|
| 34 |
Flytzani-Stephanopoulos M, Voecks G E, Charng T. Modelling of heat transfer in non-adiabatic monolith reactors and experimental comparisons of metal monoliths with packed beds. Chemical Engineering Science, 1986, 41(5): 1203-1212
|
/
| 〈 |
|
〉 |