Highly dispersed Pd nanoparticles in situ reduced and stabilized by nitrogen-alkali lignin-doped phenolic nanospheres and their application in vanillin hydrodeoxygenation

  • Xue Gu ,
  • Yu Qin ,
  • Jiahui Wei ,
  • Bing Yuan ,
  • Fengli Yu ,
  • Liantao Xin ,
  • Congxia Xie ,
  • Shitao Yu
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  • State Key Laboratory Base of Eco-chemical Engineering, College of Chemistry and Molecular Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
yuanbing@qust.edu.cn
yushitaoqust@126.com

Received date: 17 Mar 2024

Accepted date: 08 May 2024

Copyright

2024 Higher Education Press

Abstract

Herein, we introduced a nitrogen-alkali lignin-doped phenolic resin (N@ALnPR) to produce palladium nanoparticles through an in situ reduction of palladium in an aqueous phase, without the need for additional reagents or a reducing atmosphere. The phenolic resin nanospheres and the resulting palladium nanoparticles were extensively characterized. Alkali lignin created a highly conducive environment for nitrogen incorporation, dispersion, reduction, and stabilization of palladium, leading to a distinct catalytic performance of palladium nanoparticles in vanillin hydrodeoxygenation. Under specific conditions of 1 mmol of vanillin, 40 mg of catalyst, 1 MPa H2, 90 °C, and 3 h, the optimized Pd/N@AL30PR catalyst exhibited a nearly complete conversion of vanillin, 98.9% selectivity toward p-creosol, and good stability for multiple reuses. Consequently, an environmentally friendly lignin-based catalyst was developed and used for the efficient hydrodeoxygenation conversion of lignin-based platform compounds.

Cite this article

Xue Gu , Yu Qin , Jiahui Wei , Bing Yuan , Fengli Yu , Liantao Xin , Congxia Xie , Shitao Yu . Highly dispersed Pd nanoparticles in situ reduced and stabilized by nitrogen-alkali lignin-doped phenolic nanospheres and their application in vanillin hydrodeoxygenation[J]. Frontiers of Chemical Science and Engineering, 2024 , 18(11) : 127 . DOI: 10.1007/s11705-024-2478-1

Competing interests

The authors declare that they have no competing interests.

Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant Nos. 31870554 and 32071710).
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