High-yield production of porous carbon spheres derived from enzymatic hydrolysis lignin for zinc ion hybrid capacitors

  • Tao Huang 1 ,
  • Xihong Zu 1 ,
  • Jianhui Ma 1 ,
  • Wenbin Jian 1 ,
  • Xueqing Qiu , 1,3 ,
  • Wenli Zhang , 1,2,3
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  • 1. Guangdong Provincial Key Laboratory of Plant Resources Biorefinery, School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China
  • 2. School of Advanced Manufacturing, Guangdong University of Technology, Jieyang 522000, China
  • 3. Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory), Jieyang 515200, China
cexqqiu@scut.edu.cn
wlzhang@gdut.edu.cn; hiteur@163.com

Received date: 17 Oct 2023

Accepted date: 21 Nov 2023

Copyright

2024 Higher Education Press

Abstract

The widespread implementation of supercapacitors is hindered by the limited energy density and the pricey porous carbon electrode materials. The cost of porous carbon is a significant factor in the overall cost of supercapacitors, therefore a high carbon yield could effectively mitigate the production cost of porous carbon. This study proposes a method to produce porous carbon spheres through a spray drying technique combined with a carbonization process, utilizing renewable enzymatic hydrolysis lignin as the carbon source and KOH as the activation agent. The purpose of this study is to examine the relationship between the quantity of activation agent and the development of morphology, pore structure, and specific surface area of the obtained porous carbon materials. We demonstrate that this approach significantly enhances the carbon yield of porous carbon, achieving a yield of 22% in contrast to the conventional carbonization-activation method (9%). The samples acquired through this method were found to contain a substantial amount of mesopores, with an average pore size of 1.59 to 1.85 nm and a mesopore ratio of 25.6%. Additionally, these samples showed high specific surface areas, ranging from 1051 to 1831 m2·g−1. Zinc ion hybrid capacitors with lignin-derived porous carbon cathode exhibited a high capacitance of 279 F·g−1 at 0.1 A·g−1 and an energy density of 99.1 Wh·kg−1 when the power density was 80 kW·kg−1. This research presents a novel approach for producing porous carbons with high yield through the utilization of a spray drying approach.

Cite this article

Tao Huang , Xihong Zu , Jianhui Ma , Wenbin Jian , Xueqing Qiu , Wenli Zhang . High-yield production of porous carbon spheres derived from enzymatic hydrolysis lignin for zinc ion hybrid capacitors[J]. Frontiers of Chemical Science and Engineering, 2024 , 18(2) : 22 . DOI: 10.1007/s11705-024-2387-3

Competing interests

The authors declare that they have no competing interests.

Acknowledgements

The authors acknowledge the financial support from the National Natural Science Foundation of China (Grant No. 22108044), the Research and Development Program in Key Fields of Guangdong Province (Grant No. 2020B1111380002), and the Basic Research and Applicable Basic Research in Guangzhou City (Grant No. 202201010290).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at http://doi.org/10.1007/s11705-024-2387-3 and is accessible for authorized users.
1
Yang Y , Bremner S , Menictas C , Kay M . Battery energy storage system size determination in renewable energy systems: a review. Renewable & Sustainable Energy Reviews, 2018, 91: 109–125

DOI

2
Zhao H , Wu Q , Hu S , Xu H , Rasmussen C N . Review of energy storage system for wind power integration support. Applied Energy, 2015, 137: 545–553

DOI

3
Liu S , Yin Y , Ni D , Hui K S , Ma M , Park S , Hui K N , Ouyang C Y , Jun S C . New insight into the effect of fluorine doping and oxygen vacancies on electrochemical performance of Co2MnO4 for flexible quasi-solid-state asymmetric supercapacitors. Energy Storage Materials, 2019, 22: 384–396

DOI

4
Liu S , Kang L , Jun S C . Challenges and strategies toward cathode materials for rechargeable potassium-ion batteries. Advanced Materials, 2021, 33(47): 2004689

DOI

5
Yoo H D , Han S D , Bayliss R D , Gewirth A A , Genorio B , Rajput N N , Persson K A , Burrell A K , Cabana J . “Rocking-chair”-type metal hybrid supercapacitors. ACS Applied Materials & Interfaces, 2016, 8(45): 30853–30862

DOI

6
Iqbal M Z , Aziz U . Supercapattery: merging of battery-supercapacitor electrodes for hybrid energy storage devices. Journal of Energy Storage, 2022, 46: 103823

DOI

7
Xu R H , Ma P P , Liu G F , Qiao Y , Hu R Y , Liu L Y , Demir M , Jiang G H . Dual-phase coexistence design and advanced electrochemical performance of Cu2MoS4 electrode materials for supercapacitor application. Energy & Fuels, 2023, 37(8): 6158–6167

DOI

8
Jiao Z , Chen Y , Du M , Demir M , Yan F , Zhang Y , Wang C , Gu M , Zhang X , Zou J . In-situ formation of morphology-controlled cobalt vanadate on coo urchin-like microspheres as asymmetric supercapacitor electrode. Journal of Alloys and Compounds, 2023, 958: 170489

DOI

9
Hu R Y , Liu L Y , He J H , Zhou Y , Wu S B , Zheng M X , Demir M , Ma P P . Preparation and electrochemical properties of bimetallic carbide Fe3Mo3C/Mo2C@carbon nanotubes as negative electrode material for supercapacitor. Journal of Energy Storage, 2023, 72: 108656

DOI

10
Aydın H , Kurtan Ü , Üstün B , Koç S N , Akgül E , Demir M . A review on the recent advancement of metal-boride derived nanostructures for supercapacitors. Journal of Energy Storage, 2023, 72: 108306

DOI

11
Tang H , Yao J , Zhu Y . Recent developments and future prospects for zinc-ion hybrid capacitors: a review. Advanced Energy Materials, 2021, 11(14): 2003994

DOI

12
Wang Y , Sun S , Wu X , Liang H , Zhang W . Status and opportunities of zinc ion hybrid capacitors: focus on carbon materials, current collectors, and separators. Nano-Micro Letters, 2023, 15(1): 78

DOI

13
Liu Y , Wu L . Recent advances of cathode materials for zinc-ion hybrid capacitors. Nano Energy, 2023, 109: 108290

DOI

14
Sui D , Wu M , Shi K , Li C , Lang J , Yang Y , Zhang X , Yan X , Chen Y . Recent progress of cathode materials for aqueous zinc-ion capacitors: carbon-based materials and beyond. Carbon, 2021, 185: 126–151

DOI

15
Javed M S , Najam T , Hussain I , Idrees M , Ahmad A , Imran M , Shah S S A , Luque R , Han W . Fundamentals and scientific challenges in structural design of cathode materials for zinc-ion hybrid supercapacitors. Advanced Energy Materials, 2023, 13(3): 2202303

DOI

16
Yin J , Zhang W , Alhebshi N A , Salah N , Alshareef H N . Electrochemical zinc ion capacitors: fundamentals, materials, and systems. Advanced Energy Materials, 2021, 11(21): 2100201

DOI

17
Wang L , Peng M , Chen J , Tang X , Li L , Hu T , Yuan K , Chen Y . High energy and power zinc ion capacitors: a dual-ion adsorption and reversible chemical adsorption coupling mechanism. ACS Nano, 2022, 16(2): 2877–2888

DOI

18
Jian W , Zhang W , Wei X , Wu B , Liang W , Wu Y , Yin J , Lu K , Chen Y , Alshareef H N . . Engineering pore nanostructure of carbon cathodes for zinc ion hybrid supercapacitors. Advanced Functional Materials, 2022, 32(49): 2209914

DOI

19
Zhang W , Yin J , Jian W , Wu Y , Chen L , Sun M , Schwingenschlögl U , Qiu X , Alshareef H N . Supermolecule-mediated defect engineering of porous carbons for zinc-ion hybrid capacitors. Nano Energy, 2022, 103: 107827

DOI

20
Lee D W , Jin M H , Park J H , Lee Y J , Choi Y C . Flexible synthetic strategies for lignin-derived hierarchically porous carbon materials. ACS Sustainable Chemistry & Engineering, 2018, 6(8): 10454–10462

DOI

21
Gan M J , Niu Y Q , Qu X J , Zhou C H . Lignin to value-added chemicals and advanced materials: extraction, degradation, and functionalization. Green Chemistry, 2022, 24(20): 7705–7750

DOI

22
Kai D , Tan M J , Chee P L , Chua Y K , Yap Y L , Loh X J . Towards lignin-based functional materials in a sustainable world. Green Chemistry, 2016, 18(5): 1175–1200

DOI

23
Zhu J , Yan C , Zhang X , Yang C , Jiang M , Zhang X . A sustainable platform of lignin: from bioresources to materials and their applications in rechargeable batteries and supercapacitors. Progress in Energy and Combustion Science, 2020, 76: 100788

DOI

24
Zhu J Y , Pan X J . Woody biomass pretreatment for cellulosic ethanol production: technology and energy consumption evaluation. Bioresource Technology, 2010, 101(13): 4992–5002

DOI

25
Chen W , Wang X , Hashisho Z , Feizbakhshan M , Shariaty P , Niknaddaf S , Zhou X . Template-free and fast one-step synthesis from enzymatic hydrolysis lignin to hierarchical porous carbon for CO2 capture. Microporous and Mesoporous Materials, 2019, 280: 57–65

DOI

26
Jung K A , Woo S H , Lim S R , Park J M . Pyrolytic production of phenolic compounds from the lignin residues of bioethanol processes. Chemical Engineering Journal, 2015, 259: 107–116

DOI

27
Guo N , Li M , Sun X , Wang F , Yang R . Enzymatic hydrolysis lignin derived hierarchical porous carbon for supercapacitors in ionic liquids with high power and energy densities. Green Chemistry, 2017, 19(11): 2595–2602

DOI

28
Shi F , Tong Y , Li H , Li J , Cong Z , Zhai S , An Q , Wang K . Synthesis of oxygen/nitrogen/sulfur codoped hierarchical porous carbon from enzymatically hydrolyzed lignin for high-performance supercapacitors. Journal of Energy Storage, 2022, 52: 104992

DOI

29
Zhu J , Qiu X , Sun S , Huang T , Huang Z , Zhao L , Zu X , Zhang W . Combined sustainable production technology of calcium chloride and lignin-derived porous carbon electrode materials. Journal of Cleaner Production, 2023, 419: 138201

DOI

30
Liu X , Zuo S , Cui N , Wang S . Investigation of ammonia/steam activation for the scalable production of high-surface area nitrogen-containing activated carbons. Carbon, 2022, 191: 581–592

DOI

31
Xu M , Yu Q , Liu Z , Lv J , Lian S , Hu B , Mai L , Zhou L . Tailoring porous carbon spheres for supercapacitors. Nanoscale, 2018, 10(46): 21604–21616

DOI

32
Tan S , Chen X , Zhai S , Ebrahimi A , Langrish T , Chen Y . Spray drying assisted synthesis of porous carbons from whey powders for capacitive energy storage. Energy, 2018, 147: 308–316

DOI

33
Kwon H N , Park G D , Kang Y C , Roh K C . Fabrication of bimodal micro-mesoporous amorphous carbon-graphitic carbon-reduced graphene oxide composite microspheres prepared by pilot-scale spray drying and their application in supercapacitors. Carbon, 2019, 144: 591–600

DOI

34
Tian H , Wang T , Zhang F , Zhao S , Wan S , He F , Wang G . Tunable porous carbon spheres for high-performance rechargeable batteries. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2018, 6(27): 12816–12841

DOI

35
Cai T , Xing W , Liu Z , Zeng J , Xue Q , Qiao S , Yan Z . Superhigh-rate capacitive performance of heteroatoms-doped double shell hollow carbon spheres. Carbon, 2015, 86: 235–244

DOI

36
Li X F , Xu Q , Fu Y , Guo Q X . Preparation and characterization of activated carbon from kraft lignin via KOH activation. Environmental Progress & Sustainable Energy, 2014, 33(2): 519–526

DOI

37
Pan Z Z , Dong L , Lv W , Zheng D , Li Z , Luo C , Zheng C , Yang Q H , Kang F . A hollow spherical carbon derived from the spray drying of corncob lignin for high-rate-performance supercapacitors. Chemistry, an Asian Journal, 2017, 12(5): 503–506

DOI

38
Chen Y , Zhang G , Zhang J , Guo H , Feng X , Chen Y . Synthesis of porous carbon spheres derived from lignin through a facile method for high performance supercapacitors. Journal of Materials Science and Technology, 2018, 34(11): 2189–2196

DOI

39
Wang C , Wang X , Lu H , Li H , Zhao X S . Cellulose-derived hierarchical porous carbon for high-performance flexible supercapacitors. Carbon, 2018, 140: 139–147

DOI

40
Wang L , Li H , Li M , Zhang L , Zhang H , Liu Z Y , Zhu W . Trace nitrogen-doped hierarchical porous biochar nanospheres: waste corn roots derived superior adsorbents for high concentration single and mixed organic dyes removal. Nano Research, 2023, 16(2): 1846–1858

DOI

41
Li G , Gao X , Wang K , Cheng Z . Porous carbon nanospheres with high edlc capacitance. Diamond and Related Materials, 2018, 88: 12–17

DOI

42
Wang L , Peng M , Chen J , Hu T , Yuan K , Chen Y . Eliminating the micropore confinement effect of carbonaceous electrodes for promoting Zn-ion storage capability. Advanced Materials, 2022, 34(39): 2203744

DOI

43
Yang J , Wu H , Zhu M , Ren W , Lin Y , Chen H , Pan F . Optimized mesopores enabling enhanced rate performance in novel ultrahigh surface area meso-/microporous carbon for supercapacitors. Nano Energy, 2017, 33: 453–461

DOI

44
Yoo Y , Park G D , Kang Y C . Carbon microspheres with micro- and mesopores synthesized via spray pyrolysis for high-energy-density, electrical-double-layer capacitors. Chemical Engineering Journal, 2019, 365: 193–200

DOI

45
Li C , Li Y , Shao Y , Zhang L , Zhang S , Wang S , Li B , Cui Z , Tang Y , Hu X . Activation of biomass with volatilized KOH. Green Chemistry, 2023, 25(7): 2825–2839

DOI

46
Fu F , Zhao B , Yang D , Wang H , Yan M , Li Z , Qin Y , Qiu X . Insights into gas-exfoliation and the in-situ template mechanism of zinc compound for lignin-derived supercapacitive porous carbon. ACS Applied Energy Materials, 2021, 4(12): 13617–13626

DOI

47
Shao Y , Sun Z , Tian Z , Li S , Wu G , Wang M , Tong X , Shen F , Xia Z , Tung V . . Regulating oxygen substituents with optimized redox activity in chemically reduced graphene oxide for aqueous Zn-ion hybrid capacitor. Advanced Functional Materials, 2021, 31(6): 2007843

DOI

48
Wu J , Liu R , Li M , Luo X , Lai W , Zhang X , Li D , Yu F , Chen Y . Boosting effects of hydroxyl groups on porous carbon for improved aqueous zinc-ion capacitors. Journal of Energy Storage, 2022, 48: 103996

DOI

49
Yin J , Zhang W , Wang W , Alhebshi N A , Salah N , Alshareef H N . Electrochemical zinc ion capacitors enhanced by redox reactions of porous carbon cathodes. Advanced Energy Materials, 2020, 10(37): 2001705

DOI

50
Zhao L , Jian W , Zhu J , Zhang X , Wen F , Fei X , Chen L , Huang S , Yin J , Chodankar N R . . Molten salt self-template synthesis strategy of oxygen-rich porous carbon cathodes for zinc ion hybrid capacitors. ACS Applied Materials & Interfaces, 2022, 14(38): 43431–43441

DOI

51
Hu M , Ye Z , Zhang Q , Xue Q , Li Z , Wang J , Pan Z . Towards understanding the chemical reactions between KOH and oxygen-containing groups during KOH-catalyzed pyrolysis of biomass. Energy, 2022, 245: 123286

DOI

52
Zhou W , Bai B , Chen G , Ma L , Yan B . Thermogravimetric characteristics and kinetics of sawdust pyrolysis catalyzed by potassium salt during the process of hydrogen preparation. International Journal of Hydrogen Energy, 2019, 44(30): 15863–15870

DOI

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