RESEARCH ARTICLE

Fabrication of bimetallic Cu–Zn adsorbents with high dispersion by using confined space for gas adsorptive separation

  • Yu-Chao Wang ,
  • Tian-Tian Li ,
  • Li Huang ,
  • Xiao-Qin Liu ,
  • Lin-Bing Sun
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  • State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials (SICAM), College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

Received date: 01 May 2022

Accepted date: 25 May 2022

Published date: 13 Dec 2022

Copyright

2022 Higher Education Press

Abstract

The number of active components and their dispersion degree are two key factors affecting the performance of adsorbents. Here, we report a simple but efficient strategy for dispersing active components by using a confined space, which is formed by mesoporous silica walls and templates in the as-prepared SBA-15 (AS). Such a confined space does not exist in the conventional support, calcined SBA-15, which does not contain a template. The Cu and Zn precursors were introduced to the confined space in the AS and were converted to CuO and ZnO during calcination, during which the template was also removed. The results show that up to 5 mmol·g–1 of CuO and ZnO can be well dispersed; however, severe aggregation of both oxides takes place in the sample derived from the calcined SBA-15 with the same loading. Confined space in the AS and the strong interactions caused by the abundant hydroxyl groups are responsible for the dispersion of CuO and ZnO. The bimetallic materials were employed for the adsorptive separation of propene and propane. The samples prepared from the as-prepared SBA-15 showed superior performance to their counterparts from the calcined SBA-15 in terms of both adsorption capacity of propene and selectivity for propene/propane.

Cite this article

Yu-Chao Wang , Tian-Tian Li , Li Huang , Xiao-Qin Liu , Lin-Bing Sun . Fabrication of bimetallic Cu–Zn adsorbents with high dispersion by using confined space for gas adsorptive separation[J]. Frontiers of Chemical Science and Engineering, 2022 , 16(11) : 1623 -1631 . DOI: 10.1007/s11705-022-2202-y

1 Introduction

Adsorptive separation plays a critical role in the chemical [15], pharmaceutical [68], energy [911] and environmental fields [1216]. Compared to other separation methods, adsorption has unique advantages; for example, it requires little energy and does not involve the introduction of new substances. The key point of adsorptive separation is the development of highly efficient adsorbents [1721]. Since the discovery of mesoporous materials [2224], such materials have been used as ideal carriers of adsorbents due to their unique physicochemical properties [2528]. Wu and Zhao [29] studied the adsorption capacity of various mesoporous materials. The results showed that mesoporous materials have high potential for applications in adsorption. These materials, such as MCM-41 and SBA-15, have large specific surface areas and high pore volumes [3034], but they have few active centers, so they are often used for physical adsorption. Thus, the modification of mesoporous materials has always been a common research topic.
Various methods for modifying mesoporous materials have been used [3537]. Yin et al. [38] loaded CuO on SBA-15 to adsorb thiophene. The results clearly showed that the adsorption performance was enhanced with metal loading. Shi et al. [39] introduced NiO into mesoporous materials, and the obtained materials exhibited excellent catalytic activity. With the continuous improvement of industrial requirements, more attention has been given to the development of bimetallic adsorbents. Wang et al. [40] prepared a Zn/Cu-BTC adsorbent for adsorption desulfurization. It was found that the introduction of Zn promoted the π-complexation adsorption of benzothiophene on Cu. Khan et al. [41] used the synergy between Cu and Ce in Cu–Ce/MIL-101 to improve the desulfurization performance. Danmaliki et al. [42] simultaneously introduced Ce and Fe nanoparticles in oxidized activated carbon. The results showed that the bimetallic adsorbent exhibited better adsorption performance than the Ce or Fe adsorbent alone. These results indicate that bimetallic sites play an important role in adsorptive separation.
The activity of adsorbents is closely related to the dispersion degree of the active components. In general, as-prepared mesoporous silica is first calcined to remove the template so that open pores that allow the accommodation of precursors can be obtained. There is a confined space with a special microenvironment between the template and silica walls in this mesoporous silica, as reported by Sun and coworkers [43]. In addition, a large number of hydroxyl groups, which should be able to interact with the active component, are present in such materials [44]. However, reports concerning the fabrication of bimetallic adsorbents by exploring the confined spaces in unmodified silica are very scarce.
Here, we report a facile but efficient strategy that utilizes the confined space in as-prepared SBA-15 (AS) to fabricate bimetallic adsorbents (Fig.1). Such a confined space is not present in calcined SBA-15 (CS), which no longer has a template. The Cu and Zn precursors were introduced to the confined space in the AS and were converted to CuO and ZnO during calcination, in which the template was removed simultaneously. Our results showed that the Cu–Zn bimetallic adsorbents derived from the AS had better-dispersed active components than their counterparts from CS, leading to better adsorptive separation performance for C3H6 and C3H8.
Fig.1 Formation of (a) aggregated CuO and ZnO via the conventional preparation process and (b) highly dispersed CuO and ZnO by using the confined space in AS.

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2 Experimental

2.1 Synthesis of Cu- and Zn-containing adsorbents

The precursors Cu(NO3)2·3H2O and Zn(NO3)2·6H2O were introduced to AS by solid-state grinding. The support AS and the precursors were put into a mortar. The mixture was ground manually under ambient conditions for approximately 30 min. The obtained solid was calcined in flowing air (20 mL·min–1) with a heating rate of 2 °C·min–1 at 400 °C for 2 h. The obtained sample was denoted xCu–yZn–AS (x and y represent the amount of CuO and ZnO in mmol·g–1, respectively). For example, 68 mg of Cu(NO3)2·3H2O and 84 mg of Zn(NO3)2·6H2O were introduced to 200 mg of the AS, followed by calcination to obtain the sample 3Cu–3Zn–AS. For comparison, Cu(NO3)2·3H2O and Zn(NO3)2·6H2O were also introduced to the CS via the process described above to obtain xCu–yZn–CS (x and y represent the amount of CuO and ZnO in mmol·g–1, respectively).

2.2 Gas adsorption test

The adsorption isotherms of C3H6 and C3H8 were obtained on an ASAP 2020 automatic surface area and porosity analyzer manufactured by Micromeritics (USA). The measurement was conducted at 0 °C, with pressure ranging from 0 to 100 kPa. The samples were pretreated for 3 h at 150 °C prior to testing.

3 Results and discussion

3.1 Dispersion of bimetallic oxides in confined space

The low-angle X-ray diffraction (XRD) patterns of the samples are shown in Fig.2. The carrier CS exhibits one strong diffraction peak with two weak peaks at 2θ values of 0.9°, 1.6° and 1.8°, which reflect two-dimensional hexagonal pore symmetry [45]. All samples are similar in appearance, revealing that the ordered mesostructure of SBA-15 was retained. In addition, the intensity of the diffraction line corresponding to the (100) crystal plane is lower in the Cu–Zn–CS samples than in Cu–Zn–AS, indicating that the formed CuO and ZnO blocked some of the pores, reducing the scattering difference. The d-spacings of Cu–Zn–AS samples also shift toward higher values compared to those of the CS samples. The unit cell constant was calculated to be 10.9 nm, which is higher than that of the CS samples (10.2 nm). This result indicates that the presence of Cu and Zn guests prevents the shrinkage of the framework during calcination.
Fig.2 Low-angle XRD patterns of CS, Cu–Zn–AS, and Cu–Zn–CS.

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All samples present a broad diffraction peak centered at 23° in the wide-angle XRD patterns (Fig.3); this peak corresponds to the amorphous silica walls. 3Cu–3Zn–AS and 5Cu–5Zn–AS are similar to the carrier. 7Cu–7Zn–AS, however, shows some diffraction peaks at the 2θ values of 36° and 39°, which are attributed to CuO, and those at 31°, 34° and 36° are attributed to ZnO. This finding demonstrates that when the content of CuO and ZnO was increased to 7 mmol·g–1, the active components were not well-dispersed throughout the pores. The 3Cu–3Zn–CS derived from the CS shows strong characteristic diffraction peaks attributed to CuO. With increasing loading, all Cu–Zn–CS samples display much stronger diffraction peaks than their Cu–Zn–AS analogs. Based on the above analysis, it is reasonable to conclude that the use of the confined space in the AS can promote the dispersion of bimetallic active components.
Fig.3 Wide-angle XRD patterns of CS, Cu–Zn–AS, and Cu–Zn–CS.

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N2 adsorption and desorption isotherms provide other important information. As shown in Fig.4, all samples display a type IV isotherm with an H1 hysteresis loop, which indicates that all samples retain their regular mesoporous structure. Compared to the AS-derived samples, the CS-derived samples show a tail at the desorption stage, which is more obvious with the increase in Cu and Zn loading. In addition, the hysteresis loop decreases when the loading is increased. The pore size distributions show that all the AS-derived samples have a pore size similar to that of the carrier, and this pore size is higher than that of the CS-derived samples. In addition, the specific surface areas of the AS-derived samples are larger than their counterparts derived from CS (Tab.1). Based on the above results, it is reasonable to conclude that the active components in the Cu–Zn–CS aggregate and the active components in Cu–Zn–AS are more highly dispersed.
Tab.1 Textual parameters of the samples CS, Cu–Zn–AS, and Cu–Zn–CS
Sample SBET/(m2·g–1) a) VP/(cm3·g–1) Dp/nm
CS 814 0.938 8.14
3Cu–3Zn–AS 429 0.707 7.98
5Cu–5Zn–AS 303 0.540 7.82
7Cu–7Zn–AS 233 0.440 7.68
3Cu–3Zn–CS 290 0.520 7.44
5Cu–5Zn–CS 221 0.397 7.40
7Cu–7Zn–CS 168 0.323 7.26

a) SBET: total specific surface area from Brunner–Emmett–Teller (BET) method.

Fig.4 (a) N2 adsorption−desorption isotherms and the corresponding (b) pore size distributions of CS, Cu–Zn–AS, and Cu–Zn–CS (Curves were plotted offset for clarity).

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Fig.5 shows typical transmission electron microscope (TEM) images of the Cu–Zn–AS and Cu–Zn–CS. An ordered mesoporous structure can be seen in the images. This result reflects that after Cu and Zn are loaded, the structure of the carrier is not destroyed. Moreover, no aggregated particles can be seen in the TEM image of the 3Cu–3Zn–AS, which indicates that Cu and Zn are highly dispersed. The elemental mapping image of the 3Cu–3Zn–AS also shows that Cu and Zn are evenly distributed. Conversely, aggregation of CuO and ZnO can be observed in the TEM image of the 3Cu–3Zn–CS; this finding is consistent with the previous XRD results. Hence, it is obvious that the samples prepared using confined space have better dispersion.
Fig.5 Bright-field and dark-field TEM images as well as elemental mapping of the samples (a) 3Cu–3Zn–AS and (b) 3Cu–3Zn–CS.

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In short, based on the XRD, N2 adsorption, and TEM results, the AS-derived samples have better-dispersed active components than the CS-derived samples. This finding suggests that the confined space between the template and silica walls can promote the dispersion of active components.

3.2 Proposed mechanism for dispersion

Based on the abovementioned results, it is apparent that CuO and ZnO can be well dispersed by using the confined space in the AS. To explore the dispersion mechanism, the samples were examined by thermal gravity (TG) before calcination, and the results are shown in Fig.6. The decomposition of template P123 in AS occurred at approximately 190 °C, which is a lower decomposition temperature than that of pure P123 (210 °C). The reason for the low temperature is that silica walls can catalyze the decomposition of the template. However, the decomposition temperature of P123 in the 3Cu–3Zn–AS sample is 250 °C, which is obviously higher than that of pure P123. Other samples also show a similar trend (Figs. S1 and S2, cf. Electronic Supplementary Material, ESM). This result indicates that the Cu and Zn precursors were successfully introduced into the confined space of the AS, and they separated the P123 template from the silica walls and hindered the catalysis of the silica walls and the decomposition of P123. For the CS-derived samples, two derivative thermogravimetry (DTG) peaks are present at 180 and 280 °C; these peaks appear due to the conversion of Zn and Cu precursors to their respective oxides. The presence of confined space in the AS was also explored by measuring the N2 adsorption. Some nitrogen can adsorb onto the AS, and the pore size distribution was observed (Fig. S3, cf. ESM). After the introduction of the Cu and Zn precursors, the adsorption amount decreased obviously, and the pore size distributions become invisible. This result reflects the introduction of precursors to the confined space.
Fig.6 (a, c, e) TG and (b, d, f) DTG curves of Cu–Zn–AS and Cu–Zn–CS before calcination.

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In addition, the abundant Si–OH groups in the AS favor the dispersion of active components. The samples were monitored by IR before and after calcination, and the results are shown in Fig.7. The bands located at 285–3000 and 1350–1500 cm–1, which are caused by C–H stretching and bending vibrations, can be attributed to P123. The band at 960 cm–1 originates from the stretching vibration of Si–OH. After calcination, the relative intensity of the peak corresponding to Si–OH in the carrier decreases, and the vibration peak corresponding to the C–H bond in template P123 disappears due to the decomposition of P123. In addition, when the Cu and Zn precursors were introduced to the carrier AS, the antisymmetric stretching vibration of the N–O bond appeared at 1380 cm–1 and disappeared after calcination. This result suggests that calcination leads not only to the decomposition of the template in the channel but also to the conversion of the nitrate precursors. Based on the above analysis, the confined space and strong interactions caused by the abundant hydroxyl groups are responsible for the good dispersion of CuO and ZnO.
Fig.7 Infrared spectra of Cu–Zn–AS and Cu–Zn–CS (a) before and (b) after calcination.

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3.3 Adsorption performance of the resultant materials

C3H6 is one of the most important chemical raw materials, and the separation of C3H6 and C3H8 is key for its production. Because their molecular size is similar and the difference in their volatilities is small, their separation by distillation is quite energy intensive. Much attention has been given to the separation of C3H6 from C3H8 by using adsorption. The resultant Cu–Zn bimetallic adsorbents were employed in the separation of C3H6 from C3H8, and the results are shown in Fig.8. The sample 3Cu–3Zn–AS adsorbed 41.5 cm3·g–1 C3H6 and 30.2 cm3·g–1 C3H8 under 100 kPa, while under the same conditions, the sample 3Cu–3Zn–CS only adsorbed 39.2 cm3·g–1 C3H6 and 21.6 cm3·g–1 C3H8. In addition, as the loading of Cu and Zn was increased, the adsorption of C3H6 and C3H8 on the AS-derived sample surpassed that of the CS-derived analogs. To further study the adsorption behavior of Cu–Zn bimetallic adsorbents, we estimated the adsorption selectivity of the Cu–Zn bimetallic adsorbents based on the ideal adsorbed solution theory, as shown in Fig.9. All AS-derived samples were more selective than CS-derived samples. In particular, when the C3H6 molar fraction was 0.1, the selectivity for C3H6 over C3H8 on 5Cu–5Zn–AS was 3.5, which is obviously higher than that on 5Cu–5Zn–CS (2.4). These results thus demonstrate that the AS-derived samples, which had better-dispersed active components, exhibited better adsorption performance.
Fig.8 Adsorption isotherms of C3H6 and C3H8 over the samples (a, c, e) Cu–Zn–AS and (b, d, f) Cu–Zn–CS.

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Fig.9 Selectivity of C3H6 over C3H8 on the samples (a) 3Cu–3Zn–AS and 3Cu–3Zn–CS, (b) 5Cu–5Zn–AS and 5Cu–5Zn–CS, and (c) 7Cu–7Zn–AS and 7Cu–7Zn–CS.

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4 Conclusions

A simple but efficient strategy has been designed to disperse CuO and ZnO by utilizing the confined space between silica walls and the template in unmodified mesoporous silica. Up to 5 mmol·g–1 of CuO and ZnO can be well dispersed in SBA-15, whereas noticeable aggregation takes place in the counterpart prepared from the conventional support, which does not contain confined spaces. The plentiful hydroxyl groups on the surface also play a necessary role. The resultant bimetallic adsorbents derived from the AS exhibit better performance in the selective adsorption of C3H6 over C3H8 in comparison with their counterparts from the CS. The present strategy may enable us to fabricate functional materials decorated with various active components with high dispersion for different applications.

Acknowledgements

We acknowledge the financial support of this work by the National Natural Science Foundation of China (Grant Nos. 22125804, 22078155, and 21878149).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-022-2202-y and is accessible for authorized users.
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