Frontiers of Chemical Science and Engineering >
Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic application
Received date: 23 Oct 2021
Accepted date: 12 Jan 2022
Published date: 17 Oct 2022
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The current work describes the synthesis of a new bio-waste derived cellulosic-carbon supported-palladium nanoparticles enriched magnetic nanocatalyst (Pd/Fe3O4@C) using a simple multi-step process under aerobic conditions. Under mild reaction conditions, the Pd/Fe3O4@C magnetic nanocatalyst demonstrated excellent catalytic activity in the Hiyama cross-coupling reaction for a variety of substrates. Also, the Pd/Fe3O4@C magnetic nanocatalyst exhibited excellent catalytic activity up to five recycles without significant catalytic activity loss in the Hiyama cross-coupling reaction. Also, we explored the use of Pd/Fe3O4@C magnetic nanocatalyst as an electrocatalyst for hydrogen evolution reaction. Interestingly, the Pd/Fe3O4@C magnetic nanocatalyst exhibited better electrochemical activity compared to bare carbon and magnetite (Fe3O4 nanoparticles) with an overpotential of 293 mV at a current density of 10 mA·cm–2.
Vishal Kandathil , Akshay Moolakkil , Pranav Kulkarni , Alaap Kumizhi Veetil , Manjunatha Kempasiddaiah , Sasidhar Balappa Somappa , R. Geetha Balakrishna , Siddappa A. Patil . Pd/Fe3O4 supported on bio-waste derived cellulosic-carbon as a nanocatalyst for C–C coupling and electrocatalytic application[J]. Frontiers of Chemical Science and Engineering, 2022 , 16(10) : 1514 -1525 . DOI: 10.1007/s11705-022-2158-y
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