Frontiers of Chemical Science and Engineering >
Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation
Received date: 04 Mar 2012
Accepted date: 29 Apr 2012
Published date: 05 Sep 2012
Copyright
Multiple-effect membrane distillation (MEMD) using a hollow fiber-based air-gap membrane distillation module was experimentally examined for concentrating dilute aqueous hydrochloric acid. The effects of the hot and cold feed-in temperatures, and the feed-in volumetric flow rates on the performance of the MEMD process were studied. The performance was evaluated using the performance ratio (PR), the average selectivity of water over HCl (βavg) and the permeation flux (N). Two types of porous fibers made from polypropylene were used to fabricate the MEMD modules. The experimental data indicated that hollow fibers with high porosity were preferred for the MEMD process. The PR, βavg and N all decreased as the feed concentration increased. When the feed concentration was below 12 wt-%, the PR was 6.0 – 9.6 and βavg was 10 – 190. When the concentration of HCl reached 18 wt-%, the PR and βavg were about 4.4 and 2.3, respectively. However, βavg sharply decreased to around 1.0 when the feed was further concentrated. During an operational stability test that lasted for 30 days, the performance of the MEMD modules remained good.
Rongling LIU , Yingjie QIN , Xiaojun LI , Liqiang LIU . Concentrating aqueous hydrochloric acid by multiple-effect membrane distillation[J]. Frontiers of Chemical Science and Engineering, 2012 , 6(3) : 311 -321 . DOI: 10.1007/s11705-012-1207-3
| 1 |
Guo Z C, Fu Z X. Current situation of energy consumption and measures taken for energy saving in the iron and steel industry in China. Energy, 2010, 35(11): 4356–4360
|
| 2 |
Zhang Y G, Zhao X W, Jin X X. Membrane disposition technology of steel pickling waste acid liquor resource utilization. Industrial Water Treatment, 2006, 26(12): 18–20 (in Chinese)
|
| 3 |
Agrawal A, Sahu K K. An overview of the recovery of acid from spent acidic solutions from steel and electroplating industries. Journal of Hazardous Materials, 2009, 171(1-3): 61–75
|
| 4 |
Miesiac I. Removal of zinc(II) and iron(II) from spent hydrochloric acid by means of anionic resins. Industrial & Engineering Chemistry Research, 2005, 44(4): 1004–1011
|
| 5 |
Regel-Rosocka M. A review on methods of regeneration of steel processing. Journal of Hazardous Materials, 2010, 177(1-3): 57–69
|
| 6 |
Alexandratos S D. Ion-exchange resins: a retrospective from industrial and engineering chemistry research. Industrial & Engineering Chemistry Research, 2009, 48(1): 388–398
|
| 7 |
Marañón E, Suárez F, Alonso F, Fernández Y, Sastre H. Preliminary study of iron removal from hydrochloric pickling liquor by ion exchange. Industrial & Engineering Chemistry Research, 1999, 38(7): 2782–2786
|
| 8 |
Xu J, Lu S G, Fu D. Recovery of hydrochloric acid from the waste acid solution by diffusion dialysis. Journal of Hazardous Materials, 2009, 165(1-3): 832–837
|
| 9 |
Luo J Y, Wu C M, Xu T W, Wu Y H. Diffusion dialysis-concept, principle and applications. Journal of Membrane Science, 2011, 366(1-2): 1–16
|
| 10 |
Kang M S, Yoo K S, Oh S J, Moon S H. A lumped parameter model to predict hydrochloric acid recovery in diffusion dialysis. Journal of Membrane Science, 2001, 188(1): 61–70
|
| 11 |
Rohman F S, Othman M R, Aziz N. Modeling of batch electrodialysis for hydrochloric acid recovery. Chemical Engineering Journal, 2010, 162(2): 466–479
|
| 12 |
Rohman F S, Aziz N. Optimization of batch electrodialysis for hydrochloric acid recovery using orthogonal collocation method. Desalination, 2011, 275(1-3): 37–49
|
| 13 |
Wiśniewski J, Wiśniewska G, Winnicki T. Application of bipolar electrodialysis to the recovery of acids and bases from water solutions. Desalination, 2004, 169(1): 11–20
|
| 14 |
Tomaszewska M, Gryta M, Morawski A W. Study on the concentration of acid by membrane distillation. Journal of Membrane Science, 1995, 102(15): 113–122
|
| 15 |
Tomaszewska M, Gryta M, Morawski A W. The influence of salt in solutions on hydrochloric acid recovery by membrane distillation. Separation and Purification Technology, 1998, 14(1-3): 183–188
|
| 16 |
Tomaszewska M, Gryta M, Morawski A W. Recovery of hydrochloric acid from metal pickling solutions by membrane distillation. Separation and Purification Technology, 2001, 22–23, 591–600
|
| 17 |
Tomaszewska M, Gryta M, Morawski A W. Mass transfer of HCl and H2O across the hydrophobic membrane during membrane distillation. Journal of Membrane Science, 2000, 166(2): 149–157
|
| 18 |
Tang J J, Zhou K G. Hydrochloric acid recovery from rare earth chloride solutions by vacuum membrane distillation. Rare Metals, 2006, 25(3): 287–292
|
| 19 |
Guillén-Burrieza E, Blanco J, Zaragoza G, Alarcón D C, Palenzuela P, Ibarra M, Gernjak W. Experimental analysis of an air gap membrane distillation solar desalination pilot system. Journal of Membrane Science, 2011, 379(1-2): 386–396
|
| 20 |
Fiorini P, Sciubba E. Thermoeconomic analysis of a MSF desalination plant. Desalination, 2005, 182(1-3): 39–51
|
| 21 |
Gilron J, Song L M, Sirkar K K. Design for cascade of crossflow direct contact membrane distillation. Industrial & Engineering Chemistry Research, 2007, 46(8): 2324–2334
|
| 22 |
Lee H Y, He F, Song L M, Gilron J, Sirkar K K. Desalination with a cascade of cross-flow hollow fiber membrane distillation devices integrated with a heat exchanger. AIChE Journal. American Institute of Chemical Engineers, 2011, 57(7): 1780–1795
|
| 23 |
Gore W L, Gore R W, Gore D W. US Patent, <patent>4545862</patent>, 1985–<month>08</month>–<day>10</day>
|
| 24 |
Koschikowski J, Wieghaus M, Rommel M. Solar thermal-driven desalination plants based on membrane distillation. Desalination, 2003, 156(1-3): 295–304
|
| 25 |
Guijt C M, Meindersma G W, Reith T, de Haan A B. Air gap membrane distillation 2. Model validation and hollow fibre module performance analysis. Separation and Purification Technology, 2005, 43(3): 245–255
|
| 26 |
Cheng L H, Wu P C, Chen J H. Numerical simulation and optimal design of AGMD-based hollow fiber modules for desalination. Industrial & Engineering Chemistry Research, 2009, 48(10): 4948–4959
|
| 27 |
Hanemaaijer J H, van Heuven J W. US Patent, <patent>6716355</patent>, 2004–<month>04</month>–<day>06</day>
|
| 28 |
Alklaibi A, Lior N. Heat and mass transfer resistance analysis of membrane distillation. Journal of Membrane Science, 2006, 282(1-2): 362–369
|
| 29 |
Banat F A, Simandl J. Membrane distillation for dilute ethanol: Separation from aqueous streams. Journal of Membrane Science, 1999, 163(2): 333–348
|
| 30 |
Perry R H, Green D W. Perry’s Chemical Engineers’ Handbook. New York: McGraw-Hill, 1997, 2–76
|
| 31 |
Abu Al-Rub F A, Banat F, Bani-Melhem K. Sensitivity analysis of air gap membrane distillation. Separation and Purification Technology, 2003, 38(15): 3645–3667
|
| 32 |
Wormald C J. Water-hydrogen chloride association. Second virial cross coefficients for water-hydrogen chloride from gas phase excess enthalpy measurements. Journal of Chemical Thermodynamics, 2003, 35(3): 417–431
|
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