FeNi doped porous carbon as an efficient catalyst for oxygen evolution reaction

Abstract

Polymer-derived porous carbon was used as a support of iron and nickel species with an objective to obtain an efficient oxygen reduction reaction (OER) catalyst. The surface features were extensively characterized using X-ray diffraction, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy. On FeNi-modified carbon the overpotential for OER was very low (280 mV) and comparable to that on noble metal catalyst IrO₂. The electrochemical properties have been investigated to reveal the difference between the binary alloy- and single metal-doped carbons. This work demonstrates a significant step for the development of low-cost, environmentally-friendly and highly-efficient OER catalysts.

Key words： OER; polystyrene salt; porous carbon; FeNi alloy; p/n junction

Acknowledgement

This work was supported by the National Natural Science Foundation of China (Grant Nos. 21421001, 21875118) and the 111 Project (Grant No. B12015).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11705-020-1965-2 and is accessible for authorized users.

References

1 Xie W F, Li Z H, Shao M F, Wei M. Layered double hydroxide-based core-shell nanoarrays for efficient electrochemical water splitting. Frontiers of Chemical Science and Engineering, 2018, 12(3): 537–554

2 Zhang Y, Xiao J, Lv Q Y, Wang S. Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes. Frontiers of Chemical Science and Engineering, 2018, 12(3): 494–508

3 Li K, Ren T Z, Yuan Z Y, Bandosz T J. Electrodeposited P-Co nanoparticles in deep eutectic solvents and their performance in water splitting. International Journal of Hydrogen Energy, 2018, 43(22): 10448–10457

4 Barati Darband G, Aliofkhazraei M, Rouhaghdam A S. Facile electrodeposition of ternary Ni-Fe-Co alloy nanostructure as a binder free, cost-effective and durable electrocatalyst for high-performance overall water splitting. Journal of Colloid and Interface Science, 2019, 547: 407–420

5 Kim J H, Youn D H, Kawashima K, Lin J, Lim H, Mullins C B. An active nanoporous Ni(Fe) OER electrocatalyst via selective dissolution of Cd in alkaline media. Applied Catalysis B: Environmental, 2018, 225: 1–7

6 Lim D, Oh E, Lim C, Shim S E, Baeck S H. Bimetallic NiFe alloys as highly efficient electrocatalysts for the oxygen evolution reaction. Catalysis Today, 2019, 352: 27–33

7 Qiao L L, Zhu A Q, Zeng W X, Dong R, Tan P F, Ding Z P, Gao P, Wang S Y, Pan J. Achieving electronic structure reconfiguration in metallic carbides for robust electrochemical water splitting. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2020, 8(5): 2453–2462

8 Wu D, Wei Y C, Ren X, Ji X Q, Liu Y W, Guo X D, Liu Z, Asiri A M, Wei Q, Sun X P. Co(OH)₂ nanoparticle-encapsulating conductive nanowires array: room-temperature electrochemical preparation for high-performance water oxidation electrocatalysis. Advanced Materials, 2018, 30(9): 1705366

9 Yang L, Xie L S, Ren X, Wang Z Q, Liu Z, Du G, Asiri A M, Yao Y D, Sun X P. Hierarchical CuCo₂S₄ nanoarrays for high-efficient and durable water oxidation electrocatalysis. Chemical Communications, 2018, 54(1): 78–81

10 Tong M M, Wang L, Yu P, Liu X, Fu H G. 3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active bifunctional electrocatalyst for hydrogen and oxygen evolution reactions. Frontiers of Chemical Science and Engineering, 2018, 12(3): 417–424

11 Aijaz A, Masa J, Rosler C, Xia W, Weide P, Botz A J R, Fischer R A, Schuhmann W, Muhler M. Co@Co₃O₄ encapsulated in carbon nanotube-grafted nitrogen-doped carbon polyhedra as an advanced bifunctional oxygen electrode. Angewandte Chemie International Edition, 2016, 55(12): 4087–4091

12 Zhang Z Y, Liu S S, Xiao F, Wang S. Facile synthesis of heterostructured nickel/nickel oxide wrapped carbon fiber: flexible bifunctional gas-evolving electrode for highly efficient overall water splitting. ACS Sustainable Chemistry & Engineering, 2017, 5(1): 529–536

13 Cheng N Y, Liu Q, Tian J Q, Sun X P, He Y Q, Zhai S Y, Asiri A M. Nickel oxide nanosheets array grown on carbon cloth as a high-performance three-dimensional oxygen evolution electrode. International Journal of Hydrogen Energy, 2015, 40(32): 9866–9871

14 Zhang R, Wang Z, Hao S, Ge R X, Ren X, Qu F L, Du G, Asiri A M, Zheng B Z, Sun X P. Surface amorphization: a simple and effective strategy toward boosting the electrocatalytic activity for alkaline water oxidation. ACS Sustainable Chemistry & Engineering, 2017, 5(10): 8518–8522

15 Ai L H, Tian T, Jiang J. Ultrathin graphene layers encapsulating nickel nanoparticles derived metal-organic frameworks for highly efficient electrocatalytic hydrogen and oxygen evolution reactions. ACS Sustainable Chemistry & Engineering, 2017, 5(6): 4771–4777

16 Wang J, Gao D F, Wang G X, Miao S, Wu H H, Li J Y, Bao X H. Cobalt nanoparticles encapsulated in nitrogen-doped carbon as a bifunctional catalyst for water electrolysis. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(47): 20067–20074

17 Hines D, Bagreev A, Bandosz T J. Surface properties of porous carbon obtained from polystyrene sulfonic acid-based organic salts. Langmuir, 2004, 20(8): 3388–3397

18 Jagiello J, Olivier J P. A simple two-dimensional NLDFT model of gas adsorption in finite carbon pores. Application to pore structure analysis. Journal of Physical Chemistry C, 2009, 113(45): 19382–19385

19 Zhang X J, Chen Y F, Wang B, Chen M L, Yu B, Wang X Q, Zhang W L, Yang D X. FeNi nanoparticles embedded porous nitrogen-doped nanocarbon as efficient electrocatalyst for oxygen evolution reaction. Electrochimica Acta, 2019, 321(20): 134720

20 Zhang X, Xu H M, Li X X, Li Y Y, Yang T B, Liang Y Y. Facile synthesis of nickel-iron/nanocarbon hybrids as advanced electrocatalysts for efficient water splitting. ACS Catalysis, 2016, 6(2): 580–588

21 Zhou Q W, Pu J, Sun X L, Zhu C, Li J C, Wang J, Chang S Z, Zhang H G. In situ surface engineering of nickel inverse opal for enhanced overall electrocatalytic water splitting. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2017, 5(28): 14873–14880

22 Kapalka A, Foti G, Comninellis C. Determination of the Tafel slope for oxygen evolution on boron-doped diamond electrodes. Electrochemistry Communications, 2008, 10(4): 607–610

23 Zhong D, Liu L, Li D, Wei C, Wang Q, Hao G, Zhao Q, Li J. Facile and fast fabrication of iron-phosphate supported on nickel foam as a highly efficient and stable oxygen evolution catalyst. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2017, 5(35): 18627–18633

24 Lu B A, Cao D X, Wang P, Wang G L, Gao Y Y. Oxygen evolution reaction on Ni-substituted Co₃O₄ nanowire array electrodes. International Journal of Hydrogen Energy, 2011, 36(1): 72–78

25 Huang J. Diffusion impedance of electroactive materials, electrolytic solutions and porous electrodes: Warburg impedance and beyond. Electrochimica Acta, 2018, 281: 170–188

26 Cao X L, Ren T Z, Yuan Z Y, Bandosz T J. CaTiO₃ perovskite in the framework of activated carbon and its effect on enhanced electrochemical capacitance. Electrochimica Acta, 2018, 268: 73–81

27 Chen Z X, Han Y Q, Li T X, Zhang X W, Wang T Q, Zhang Z L. Preparation and electrochemical performances of doped MXene/poly(3,4-ethylenedioxythiophene) composites. Materials Letters, 2018, 220: 305–308

28 Lian J Q, Wu Y H, Zhang H A, Gu S Y, Zeng Z W, Ye X Y. One-step synthesis of amorphous Ni-Fe-P alloy as bifunctional electrocatalyst for overall water splitting in alkaline medium. International Journal of Hydrogen Energy, 2018, 43(29): 12929–12938

29 Li X H, Antonietti M. Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott-Schottky heterojunctions for catalysis. Chemical Society Reviews, 2013, 42(16): 6593–6604

30 Yang H B, Miao J W, Hung S F, Chen J Z, Tao H B, Wang X Z, Zhang L P, Chen R, Gao J J, Chen H M, Dai L, Liu B. Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: development of highly efficient metal-free bifunctional electrocatalyst. Science Advances, 2016, 2(4): e1501122

31 Lu C L, Xu S P, Liu C H. The role of K₂CO₃ during the chemical activation of petroleum coke with KOH. Journal of Analytical and Applied Pyrolysis, 2010, 87(2): 282–287

32 Pinilla J L, Arcelus-Arrillaga P, Puron H, Millan M. Selective catalytic steam cracking of anthracene using mesoporous Al₂O₃ supported Ni-based catalysts doped with Na, Ca or K. Applied Catalysis A, 2013, 459: 17–25

33 Zha M, Pei C, Wang Q, Hu G, Feng L. Electrochemical oxygen evolution reaction efficiently boosted by selective fluoridation of FeNi₃ alloy/oxide hybrid. Journal of Energy Chemistry, 2020, 47: 166–171

34 Li G L, Xu X C, Yang B B, Cao S, Wang X Y, Fu X D, Shi Y T, Yan Y, Song X D, Hao C. Micelle-template synthesis of a 3D porous FeNi alloy and nitrogen-codoped carbon material as a bifunctional oxygen electrocatalyst. Electrochimica Acta, 2020, 331(20): 135375

35 Yang T T, Meng L R, Han S W, Hou J H, Wang S S, Wang X Z. Simultaneous reductive and sorptive removal of Cr(VI) by activated carbon supported β-FeOOH. RSC Advances, 2017, 7(55): 34687–34693

36 Seredych M, Rodriguez-Castellon E, Bandosz T J. New Cu_xS_y/nanoporous carbon composites as efficient oxygen reduction catalysts in alkaline medium. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2014, 2(47): 20164–20176

37 Andreeva A Y, Sukhikh T S, Kozlova S G, Konchenko S N. Exchange interactions and XPS O1s spectra in polynuclear lanthanide complexes with dibenzoylmethanide and 4-hydroxy-2,1,3-benzothiadiazole. Journal of Molecular Structure, 2018, 1166: 190–194

38 Pietrzak R, Wachowska H. The influence of oxidation with HNO₃ on the surface composition of high-sulphur coals: XPS study. Fuel Processing Technology, 2006, 87(11): 1021–1029

39 Ma T, Yuan M W, Islam S M, Li H F, Ma S L, Sun G B, Yang X J. FeNi₃ alloy nanocrystals grown on graphene: controllable synthesis, in-depth characterization and enhanced electromagnetic performance. Journal of Alloys and Compounds, 2016, 678: 468–477

40 Abellan G, Prima-Garcia H, Coronado E. Graphene enhances the magnetoresistance of FeNi₃ nanoparticles in hierarchical FeNi₃-graphene nanocomposites. Journal of Materials Chemistry. C, Materials for Optical and Electronic Devices, 2016, 4(11): 2252–2258

41 Wang H Q, Fan X P, Zhang X H, Huang Y G, Wu Q, Pan Q C, Li Q Y. In situgrowth of NiO nanoparticles on carbon paper as a cathode for rechargeable Li-O₂ batteries. RSC Advances, 2017, 7(38): 23328–23333

42 Zhang G, Wang G C, Liu H J, Qu J H, Li J H. Rapidly catalysis of oxygen evolution through sequential engineering of vertically layered FeNi structure. Nano Energy, 2018, 43: 359–367

43 Zhao J X, Li X H, Cui G W, Sun X P. Highly-active oxygen evolution electrocatalyzed by an Fe-doped NiCr₂O₄ nanoparticle film. Chemical Communications, 2018, 54(43): 5462–5465

44 Corrigan D A. The catalysis of the oxygen evolution reaction by iron impurities in thin film nickel oxide electrodes. ChemInform, 1987, 18(22): 377–384

45 Lei W, Guo J P, Wu Z X, Xuan C J, Xiao W P, Wang D L. Highly nitrogen and sulfur dual-doped carbon microspheres for supercapacitors. Science Bulletin, 2017, 62(14): 1011–1017