Preparation and properties of hollow fibre nanofiltration membrane with continuous coffee-ring structure

Abstract

Polyamide (PA) hollow fibre composite nanofiltration (NF) membranes with a coffee-ring structure and beneficial properties were prepared by adding graphene oxide (GO) into the interfacial polymerization process. The presentation of the coffee-ring structure was attributed to the heterogeneous, finely dispersed multiphase reaction system and the “coffee-stain” effect of the GO solution. When the piperazine concentration was 0.4 wt-%, the trimesoyl chloride concentration was 0.3 wt-%, and the GO concentration was 0.025 wt-%, the prepared NF membranes showed the best separation properties. The permeate flux was 76 L·m⁻²·h⁻¹, and the rejection rate for MgSO₄ was 98.6% at 0.4 MPa. Scanning electron microscopy, atomic force microscopy, and attenuated total reflectance-Fourier transform infrared spectroscopy were used to characterize the chemical structure and morphology of the PA/GO NF membrane. The results showed that GO was successfully entrapped into the PA functional layer. Under neutral operating conditions, the PA/GO membrane showed typical negatively charged NF membrane separation characteristics, and the rejection rate decreased in the order of Na₂SO₄>MgSO₄>MgCl₂>NaCl. The PA/GO NF membrane showed better antifouling performance than the PA membrane.

Key words： GO; PA; interfacial polymerization; hollow fibre NF membrane

Acknowledgments

The authors gratefully acknowledge financial support from the Natural Science Foundation of Zhejiang Province (Grant No. LY19E030005) and MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Zhejiang University (No. 2017MSF 05). The authors also sincerely thank the Open Foundation from the Top Key Discipline of Environmental Science and Engineering, Zhejiang University of Technology (Grant No. 20150314).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11705-020-1943-8 and is accessible for authorized users.

References

1 Wei C J, Cheng Q, Lin L G, He Z F, Huang K, Ma S S, Chen L. One-step fabrication of recyclable polyimide nanofiltration membranes with high selectivity and performance stability by a phase inversion-based process. Journal of Materials Science, 2018, 53(15): 11104–11115

2 Miao J, Zhang R, Bai R. Development and characterization of quaternized poly(vinyl alcohol) composite nanofiltration membranes. Journal of Materials Science, 2016, 51(4): 1855–1863

3 Ahmad A L, Ooi B S, Wahab Mohammad A, Choudhury J P. Development of a highly hydrophilic nanofiltration membrane for desalination and water treatment. Desalination, 2004, 168: 215–221

4 Liang H W, Cao X, Zhang W J, Lin H T, Zhou F, Chen L F, Yu S H. Robust and highly efficient free-standing carbonaceous nanofiber membranes for water purification. Advanced Functional Materials, 2011, 21(20): 3851–3858

5 Zhang H J, Cai C C, Wu Y Z, Shao D D, Ye B H, Zhang Y, Liu J Y, Wang J, Jia X Y. Mitochondrial and endoplasmic reticulum pathways involved in microcystin-LR-induced apoptosis of the testes of male frog (Rana nigromaculata) in vivo. Journal of Hazardous Materials, 2013, 252-253: 382–389

6 Krivoshapkina E F, Vedyagin A A, Krivoshapkin P V. Preparation of catalytic membranes with a nanostructured layer based on alumina. Nanotechnologies in Russia, 2014, 9(7-8): 423–429

7 Jahanshahi M, Rahimpour A, Peyravi M. Developing thin film composite poly(piperazine-amide) and poly(vinyl-alcohol) nanofiltration membranes. Desalination, 2010, 257(1–3): 129–136

8 Liu L Y, Kang H, Wang W, Xu Z W, Mai W, Li J, Lv H M, Zhao L H, Qian X M. Layer-by-layer self-assembly of polycation/GO/OCNTs nanofiltration membrane with enhanced stability and flux. Journal of Materials Science, 2018, 53(15): 10879–10890

9 Tessier L, Bouchard P, Rahni M. Separation and purification of benzylpenicillin produced by fermentation using coupled ultrafiltration and nanofiltration technologies. Journal of Biotechnology, 2005, 116(1): 79–89

10 Wang K Y, Chung T S. The characterization of flat composite nanofiltration membranes and their applications in the separation of cephalexin. Journal of Membrane Science, 2005, 247(1-2): 37–50

11 Cheng S Y, Oatley D L, Williams P M, Wright C J. Positively charged nanofiltration membranes: Review of current fabrication methods and introduction of a novel approach. Advances in Colloid and Interface Science, 2011, 164(1-2): 12–20

12 Heshmati N, Wagner B, Cheng X, Scholz T, Kansy M, Eisenbrand G, Fricker G. Physicochemical characterization and in vitro permeation of an indirubin derivative. European Journal of Pharmaceutical Sciences, 2013, 50(3-4): 467–475

13 Yu L, Zhang Y, Zhang B, Liu J, Zhang H, Song C. Preparation and characterization of HPEI-GO/PES ultrafiltration membrane with antifouling and antibacterial properties. Journal of Membrane Science, 2013, 447: 452–462

14 Peng X, Jin J, Nakamura Y, Ohno T, Ichinose I. Ultrafast permeation of water through protein-based membranes. Nature Nanotechnology, 2009, 4(6): 353–357

15 Cai Z J, Zhu C, Xiong P, Guo J, Zhao K Y. Calcium alginate-coated electrospun polyhydroxybutyrate/carbon nanotubes composite nanofibers as nanofiltration membrane for dye removal. Journal of Materials Science, 2018, 53(20): 14801–14820

16 Zhou D, Zhu L, Fu Y, Zhu M, Xue L. Development of lower cost seawater desalination processes using nanofiltration technologies—A review. Desalination, 2015, 376(1219): 109–116

17 Wang L, Corriou J P, Castel C, Favre E. A critical review of cyclic transient membrane gas separation processes: State of the art, opportunities and limitations. Journal of Membrane Science, 2011, 383(1-2): 170–188

18 Bernardo P, Drioli E, Golemme G. Membrane gas separation: A review/state of the art. Industrial & Engineering Chemistry Research, 2009, 48(10): 4638–4663

19 Wu M, Yuan J, Wu H, Su Y, Yang H, You X, Zhang R, He X, Khan N A, Kasher R, Jiang Z. Ultrathin nanofiltration membrane with polydopamine-covalent organic framework interlayer for enhanced permeability and structural stability. Journal of Membrane Science, 2019, 576: 131–141

20 Kim E S, Yu Q, Deng B. Plasma surface modification of nanofiltration (NF) thin-film composite (TFC) membranes to improve anti organic fouling. Applied Surface Science, 2011, 257(23): 9863–9871

21 Zhao Y, Li N, Xia S. Polyamide nanofiltration membranes modified with Zn-Al layered double hydroxides for natural organic matter removal. Composites Science and Technology, 2016, 132: 84–92

22 Safarpour M, Vatanpour V, Khataee A, Esmaeili M. Development of a novel high flux and fouling-resistant thin film composite nanofiltration membrane by embedding reduced graphene oxide/TiO₂. Separation and Purification Technology, 2015, 154: 96–107

23 Zarrabi H, Yekavalangi M E, Vatanpour V, Shockravi A, Safarpour M. Improvement in desalination performance of thin film nanocomposite nanofiltration membrane using amine-functionalized multiwalled carbon nanotube. Desalination, 2016, 394: 83–90

24 Kamada T, Ohara T, Shintani T, Tsuru T. Controlled surface morphology of polyamide membranes via the addition of co-solvent for improved permeate flux. Journal of Membrane Science, 2014, 467: 303–312

25 Lai G S, Lau W J, Goh P S, Ismail A F, Yusof N, Tan Y H. Graphene oxide incorporated thin film nanocomposite nanofiltration membrane for enhanced salt removal performance. Desalination, 2016, 387: 14–24

26 Tan Z, Chen S, Peng X, Zhang L, Gao C. Polyamide membranes with nanoscale Turing structures for water purification. Science, 2018, 360(6388): 518–521

27 Kondo S, Miura T. Reaction-diffusion model as a framework for understanding biological pattern formation. Science, 2010, 329(5999): 1616–1620

28 Zimmermann R. Condensation Polymers: By Interfacial and Solution Methods. Von P. W. Morgan. John Wiley & Sons, New York London-Sydney 1965. 1. Angewandte Chemie, 1966, 78(16): 787

29 Bánsági T, Vanag V K, Epstein I R. Tomography of reaction-diffusion microemulsions reveals three-dimensional turing patterns. Science, 2011, 331(6022): 1309–1312

30 Tompkins N, Li N, Girabawe C, Heymann M, Ermentrout G B, Epstein I R, Fraden S. Testing Turing’s theory of morphogenesis in chemical cells. Proceedings of the National Academy of Sciences of the United States of America, 2014, 111(12): 4397–4402

31 Ding R, Zhang H, Li Y, Wang J, Shi B, Mao H, Dang J, Liu J. Graphene oxide-embedded nanocomposite membrane for solvent resistant nanofiltration with enhanced rejection ability. Chemical Engineering Science, 2015, 138: 227–238

32 Qin Y, Liu H L, Liu Y M, Chen M X, Chen K K, Huang Y, Xiao C F. Design of a novel interfacial enhanced GO-PA/APVC nanofiltration membrane with stripe-like structure. Journal of Membrane Science, 2020, 604: 118064

33 Anand A, Unnikrishnan B, Mao J Y, Lin H J, Huang C C. Graphene-based nanofiltration membranes for improving salt rejection, water flux and antifouling—A review. Desalination, 2018, 429: 119–133

34 Bano S, Mahmood A, Kim S J, Lee K H. Graphene oxide modified polyamide nanofiltration membrane with improved flux and antifouling properties. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(5): 2065–2071

35 Hu R, Zhang R, He Y, Zhao G, Zhu H. Graphene oxide-in-polymer nanofiltration membranes with enhanced permeability by interfacial polymerization. Journal of Membrane Science, 2018, 564: 813–819

36 Cheng C, Li P, Zhang T, Wang X, Hsiao B S. Enhanced pervaporation performance of polyamide membrane with synergistic effect of porous nanofibrous support and trace graphene oxide lamellae. Chemical Engineering Science, 2019, 196: 265–276

37 Lian H, Qi L, Luo J, Zhang R, Hu K. Uniform droplet printing of graphene micro-rings based on multiple droplets overwriting and coffee-ring effect. Applied Surface Science, 2019, 499: 143826

38 Eom D S, Chang J, Song Y W, Lim J A, Han J T, Kim H, Cho K. Coffee-ring structure from dried graphene derivative solutions: A facile one-step fabrication route for all graphene-based transistors. Journal of Physical Chemistry C, 2014, 118(46): 27081–27090

39 Lin L, Lopez R, Ramon G Z, Coronell O. Investigating the void structure of the polyamide active layers of thin-film composite membranes. Journal of Membrane Science, 2016, 497: 365–376

40 Fang W, Shi L, Wang R. Mixed polyamide-based composite nanofiltration hollow fiber membranes with improved low-pressure water softening capability. Journal of Membrane Science, 2014, 468: 52–61

41 Hu M, Mi B. Enabling graphene oxide nanosheets as water separation membranes. Environmental Science & Technology, 2013, 47(8): 3715–3723

42 Zhao C, Xu X, Chen J, Yang F. Effect of graphene oxide concentration on the morphologies and antifouling properties of PVDF ultrafiltration membranes. Journal of Environmental Chemical Engineering, 2013, 1(3): 349–354

43 Wang Z, Yu H, Xia J, Zhang F, Li F, Xia Y, Li Y. Novel GO-blended PVDF ultrafiltration membranes. Desalination, 2012, 299: 50–54

44 Kong X, Zhang Y, Zeng S Y, Zhu B K, Zhu L P, Fang L F, Matsuyama H. Incorporating hyperbranched polyester into cross-linked polyamide layer to enhance both permeability and selectivity of nanofiltration membrane. Journal of Membrane Science, 2016, 518: 141–149

45 Yin J, Kim E S, Yang J, Deng B. Fabrication of a novel thin-film nanocomposite (TFN) membrane containing MCM-41 silica nanoparticles (NPs) for water purification. Journal of Membrane Science, 2012, 423-424: 238–246

46 Kim E S, Deng B. Fabrication of polyamide thin-film nano-composite (PA-TFN) membrane with hydrophilized ordered mesoporous carbon (H-OMC) for water purifications. Journal of Membrane Science, 2011, 375(1-2): 46–54

47 Joshi R K, Carbone P, Wang F C, Kravets V G, Su Y, Grigorieva I V, Wu H A, Geim A K, Nair R R. Precise and ultrafast molecular sieving through graphene oxide membranes. Science, 2014, 343(6172): 752–754

48 Ambre J P, Dhopte K B, Nemade P R, Dalvi V H. High flux hyperbranched starch-graphene oxide piperazinamide composite nanofiltration membrane. Journal of Environmental Chemical Engineering, 2019, 7(6): 103300

49 Kang Y, Obaid M, Jang J, Kim I S. Sulfonated graphene oxide incorporated thin film nanocomposite nanofiltration membrane to enhance permeation and antifouling properties. Desalination, 2019, 470: 114125

50 Shao W, Liu C, Ma H, Hong Z, Xie Q, Lu Y. Fabrication of pH-sensitive thin-film nanocomposite nanofiltration membranes with enhanced performance by incorporating amine-functionalized graphene oxide. Applied Surface Science, 2019, 487: 1209–1221

51 Wen P, Chen Y, Hu X, Cheng B, Liu D, Zhang Y, Nair S. Polyamide thin film composite nanofiltration membrane modified with acyl chlorided graphene oxide. Journal of Membrane Science, 2017, 535: 208–220

52 Li H, Shi W, Du Q, Zhou R, Zhang H, Qin X. Improved separation and antifouling properties of thin-film composite nanofiltration membrane by the incorporation of cGO. Applied Surface Science, 2017, 407: 260–275

53 Ma T, Su Y, Li Y, Zhang R, Liu Y, He M, Li Y, Dong N, Wu H, Jiang Z. Fabrication of electro-neutral nanofiltration membranes at neutral pH with antifouling surface via interfacial polymerization from a novel zwitterionic amine monomer. Journal of Membrane Science, 2016, 503: 101–109

54 Li Y, Su Y, Zhao X, He X, Zhang R, Zhao J, Fan X, Jiang Z. Antifouling, high-flux nanofiltration membranes enabled by dual functional polydopamine. ACS Applied Materials & Interfaces, 2014, 6(8): 5548–5557

55 Szabó T, Tombácz E, Illés E, Dékány I. Enhanced acidity and pH-dependent surface charge characterization of successively oxidized graphite oxides. Carbon, 2006, 44(3): 537–545