Kombucha SCOBY-based carbon and graphene oxide wrapped sulfur/polyacrylonitrile as a high-capacity cathode in lithium-sulfur batteries

Abstract

Hierarchically-porous carbon nano sheets were prepared as a conductive additive for sulfur/polyacrylonitrile (S/PAN) composite cathodes using a simple heat treatment. In this study, kombucha (that was derived from symbiotic culture of bacteria and yeast) carbon (KC) and graphene oxide (GO) were used as a carbon host matrix. These rational-designed S/PAN/KC/GO hybrid composites greatly suppress the diffusion of polysulfides by providing strong physical and chemical adsorption. The cathode delivered an initial discharge capacity of 1652 mAh·g⁻¹ at a 0.1 C rate and a 100^th cycle capacity of 1193 mAh·g⁻¹. The nano sheets with embedded hierarchical pores create a conductive network that provide effective electron transfer and fast electrochemical kinetics. Further, the nitrogen component of PAN can raise the affinity/interaction of the carbon host with lithium polysulfides, supporting the cyclic performance. The results exploit the cumulative contribution of both the conductive carbon matrix and PAN in the enhanced performance of the positive electrode.

Key words： sulfur cathode; kombucha SCOBY; graphene oxide; polyacrylonitrile; lithium-sulfur battery

Acknowledgements

All the authors from Alagappa University acknowledge the financial support by DST-SERB, New Delhi under the Physical sciences, grant sanctioned vide EMR/2016/006302. Also, all the authors gratefully acknowledge for extending the analytical facilities in the Department of Physics, Alagappa University under the PURSE and FIST programme, sponsored by Department of Science and Technology (DST), BSR of University Grants Commission (UGC), New Delhi, Government of India and Ministry of Human Resource Development RUSA-Phase 2.0 grant sanctioned vide Lt.No.F-24-51/2014 U Policy (TNMulti Gen), Department of Education, Government of India.

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://doi.org/10.1007/s11705-019-1897-x and is accessible for authorized users.

References

1 Armand M, Tarascon J M. Building better batteries. Nature, 2008, 451(7179): 652–657

2 Whittingham M S. Lithium batteries and cathode materials. Chemical Reviews, 2004, 104(10): 4271–4302

3 Scrosati B, Hassoun J, Sun Y K. Lithium-ion batteries. A look into the future. Energy & Environmental Science, 2011, 4(9): 3287–3295

4 Bruce P G, Freunberger S A, Hardwick L J, Tarascon J M. Li-O₂ and Li-S batteries with high energy storage. Nature Materials, 2012, 11(1): 19–29

5 Sivakumar M, Muruganantham R, Subadevi R. Investigations on the rate performance of LiFePO₄/CeO₂ composite materials via polyol technique for rechargeable lithium batteries. RSC Advances, 2015, 5(105): 86126–86136

6 Jayaprakash N, Shen J, Moganty S S, Corona A, Archer L A. Porous hollow carbon@ sulfur composites for high-ower lithium-sulfur batteries. Angewandte Chemie International Edition, 2011, 50(26): 5904–5908

7 Ji X, Nazar L F. Advances in Li-S batteries. Journal of Materials Chemistry, 2010, 20(44): 9821–9826

8 Liang C, Zhang X, Zhao Y, Tan T, Zhang Y, Chen Z. Preparation of hierarchical porous carbon from waterweed and its application in lithium/sulfur batteries. Energies, 2018, 11(6): 1535

9 Peng H J, Huang J Q, Zhao M Q, Zhang Q, Cheng X B, Liu X Y, Qian W Z, Wei F. Nanoarchitectured graphene/CNT@ porous carbon with extraordinary electrical conductivity and interconnected micro/mesopores for lithium-sulfur batteries. Advanced Functional Materials, 2014, 24(19): 2772–2781

10 Ji X, Lee K T, Nazar L F. A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nature Materials, 2009, 8(6): 500–506

11 Li Z, Zhang J, Guan B, Wang D, Liu L M, Lou X W D. A sulfur host based on titanium monoxide @ carbon hollow spheres for advanced lithium-sulfur batteries. Nature Communications, 2016, 7(1): 13065

12 Wu R, Chen S, Deng J, Huang X, Song Y, Gan R, Wan X, Wei Z. Hierarchically porous nitrogen-doped carbon as cathode for lithium-sulfur batteries. Journal of Energy Chemistry, 2018, 27(6): 1661–1667

13 Zhang J, Yang C P, Yin Y X, Wan L J, Guo Y G. Sulfur encapsulated in graphitic carbon nanocages for high-rate and long-cycle lithium-sulfur batteries. Advanced Materials, 2016, 28(43): 9539–9544

14 Zhang C, Lu C, Bi S, Hou Y, Zhang F, Cai M, He Y, Paasch S, Feng X, Brunner E, Zhuang X. S-enriched porous polymer derived N-doped porous carbons for electrochemical energy storage and conversion. Frontiers of Chemical Science and Engineering, 2018, 12(3): 346–357

15 Radhika G, Subadevi R, Krishnaveni K, Liu W R, Sivakumar M. Synthesis and electrochemical performance of PEG-MnO₂-sulfur composites cathode materials for lithium sulfur batteries. Journal of Nanoscience and Nanotechnology, 2018, 18(1): 127–131

16 Wang K, Pang J, Li L, Zhou S, Li Y, Zhang T. Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation. Frontiers of Chemical Science and Engineering, 2018, 12(3): 376–382

17 Gong G, Pyo J, Mathew A P, Oksman K. Tensile behavior, morphology and viscoelastic analysis of cellulose nanofiber-reinforced (CNF) polyvinyl acetate (PVAc). Composites. Part A, Applied Science and Manufacturing, 2011, 42(9): 1275–1282

18 Li W, Zhang Q, Zheng G, Seh Z W, Yao H, Cui Y. Understanding the role of different conductive polymers in improving the nanostructured sulfur cathode performance. Nano Letters, 2013, 13(11): 5534–5540

19 Kong L, Li B Q, Peng H J, Zhang R, Xie J, Huang J Q, Zhang Q. Porphyrin-derived graphene-based nanosheets enabling strong polysulfide chemisorption and rapid kinetics in lithium-sulfur batteries. Advanced Energy Materials, 2018, 8(20): 1800849

20 Fu Y, Manthiram A. Orthorhombic bipyramidal sulfur coated with polypyrrole nanolayers as a cathode material for lithium-sulfur batteries. Journal of Physical Chemistry C, 2012, 116(16): 8910–8915

21 Zhou W, Xiao X, Cai M, Yang L. Polydopamine-coated, nitrogen-doped, hollow carbon-sulfur double-layered core-shell structure for improving lithium-sulfur batteries. Nano Letters, 2014, 14(9): 5250–5256

22 Zhang Y, Zhao Y, Yermukhambetova A, Bakenov Z, Chen P. Ternary sulfur/polyacrylonitrile/Mg_0.6Ni_0.4O composite cathodes for high performance lithium/sulfur batteries. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2013, 1(2): 295–301

23 Krishnaveni K, Subadevi R, Sivakumar M. A solution-processed binary composite as a cathode material in lithium-sulfur batteries. Applied Physics. A, Materials Science & Processing, 2019, 125(7): 469

24 Wei S, Ma L, Hendrickson K E, Tu Z, Archer L A. Metal-sulfur battery cathodes based on PAN-sulfur composites. Journal of the American Chemical Society, 2015, 137(37): 12143–12152

25 Balakumar K, Sathish R, Kalaiselvi N. Exploration of microporous bio-carbon scaffold for efficient utilization of sulfur in lithium-sulfur system. Electrochimica Acta, 2016, 209: 171–182

26 Balakumar K, Kalaiselvi N. High sulfur loaded carbon aerogel cathode for lithium-sulfur batteries. RSC Advances, 2015, 5(43): 34008–34018

27 Chen M, Jiang S, Huang C, Xia J, Wang X, Xiang K, Zeng P, Zhang Y, Jamil S. Synergetic effects of multifunctional composites with more efficient polysulfide immobilization and ultrahigh sulfur content in lithium-sulfur batteries. ACS Applied Materials & Interfaces, 2018, 10(16): 13562–13572

28 Wang Z, Dong Y, Li H, Zhao Z, Wu H B, Hao C, Liu S, Qiu J, Lou X W. Enhancing lithium-sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide. Nature Communications, 2014, 5(1): 5002

29 Krishnaveni K, Subadevi R, Sivakumar M, Raja M, Prem Kumar T. Synthesis and characterization of graphene oxide capped sulfur/polyacrylonitrile composite cathode by simple heat treatment. Journal of Sulfur Chemistry, 2019, 40(4): 377–388

30 Shi Y, Lv W, Niu S, He Y, Zhou G, Chen G, Li B, Yang Q H, Kang F. A carbon-sulfur hybrid with pomegranate-like structure for lithium-sulfur batteries. Chemistry, an Asian Journal, 2016, 11(9): 1343–1347

31 Rajkumar P, Diwakar K, Radhika G, Krishnaveni K, Subadevi R, Sivakumar M. Effect of silicon dioxide in sulfur/carbon black composite as a cathode material for lithium sulfur batteries. Vacuum, 2019, 161: 37–48

32 Wang J, Yang J, Wan C, Du K, Xie J, Xu N. Sulfur composite cathode materials for rechargeable lithium batteries. Advanced Functional Materials, 2003, 13(6): 487–492

33 Yin L, Wang J, Lin F, Yang J, Nuli Y. Polyacrylonitrile/graphene composite as a precursor to a sulfur-based cathode material for high-rate rechargeable Li-S batteries. Energy & Environmental Science, 2012, 5(5): 6966–6972

34 Wang J, Yang J, Xie J, Xu N. A novel conductive polymer-sulfur composite cathode material for rechargeable lithium batteries. Advanced Materials, 2002, 14(13-14): 963–965

35 Yin L, Wang J, Yang J, Nuli Y. A novel pyrolyzed polyacrylonitrile-sulfur@ MWCNT composite cathode material for high-rate rechargeable lithium/sulfur batteries. Journal of Materials Chemistry, 2011, 21(19): 6807–6810

36 Krishnaveni K, Subadevi R, Raja M. Sulfur/PAN/acetylene black composite prepared by a solution processing technique for lithium-sulfur batteries. Journal of Applied Polymer Science, 2018, 135(34): 46598

37 Wei W, Wang J, Zhou L, Yang J, Schumann B, Nuli Y. CNT enhanced sulfur composite cathode material for high rate lithium battery. Electrochemistry Communications, 2011, 13(5): 399–402

38 Ye J, He F, Nie J, Cao Y, Yang H, Ai X. Sulfur/carbon nanocomposite-filled polyacrylonitrile nanofibers as a long life and high capacity cathode for lithium-sulfur batteries. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2015, 3(14): 7406–7412

39 Krishnaveni K, Subadevi R, Radhika G, Premkumar T, Raja M, Liu W R, Sivakumar M. Carbon wrapping effect on sulfur/polyacrylonitrile composite cathode materials for lithium sulfur batteries. Journal of Nanoscience and Nanotechnology, 2018, 18(1): 121–126

40 Kim J W, Ocon J D, Park D W, Lee J. Enhanced reversible capacity of Li-S battery cathode based on graphene oxide. Journal of Energy Chemistry, 2013, 22(2): 336–340

41 Ji L, Rao M, Zheng H, Zhang L, Li Y, Duan W, Guo J, Cairns E J, Zhang Y. Graphene oxide as a sulfur immobilizer in high performance lithium/sulfur cells. Journal of the American Chemical Society, 2011, 133(46): 18522–18525

42 Li K, Wang B, Su D, Park J, Ahn H, Wang G. Enhance electrochemical performance of lithium sulfur battery through a solution-based processing technique. Journal of Power Sources, 2012, 202: 389–393

43 Hwang T H, Jung D S, Kim J S, Kim B G, Choi J W. One-dimensional carbon-sulfur composite fibers for Na-S rechargeable batteries operating at room temperature. Nano Letters, 2013, 13(9): 4532–4538

44 Johra F T, Lee J W, Jung W G. Facile and safe graphene preparation on solution based platform. Journal of Industrial and Engineering Chemistry, 2014, 20(5): 2883–2887

45 Gurunathan S, Han J W, Dayem A A, Eppakayala V, Kim J H. Oxidative stress-mediated antibacterial activity of graphene oxide and reduced graphene oxide in Pseudomonas aeruginosa. International Journal of Nanomedicine, 2012, 7: 5901

46 Guo J, Xu Y, Wang C. Sulfur-impregnated disordered carbon nanotubes cathode for lithium-sulfur batteries. Nano Letters, 2011, 11(10): 4288–4294

47 Lee J T, Zhao Y, Thieme S, Kim H, Oschatz M, Borchardt L, Magasinski A, Cho W I, Kaskel S, Yushin G. Sulfur-infiltrated micro- and mesoporous silicon carbide-derived carbon cathode for high-performance lithium sulfur batteries. Advanced Materials, 2013, 25(33): 4573–4579

48 Yushin G, Dash R, Jagiello J, Fischer J E, Gogotsi Y. Carbide-derived carbons: Effect of pore size on hydrogen uptake and heat of adsorption. Advanced Functional Materials, 2006, 16(17): 2288–2293

49 Rehman S, Tang T, Ali Z, Huang X, Hou Y. Integrated design of MnO₂@ carbon hollow nanoboxes to synergistically encapsulate polysulfides for empowering lithium sulfur batteries. Small, 2017, 13(20): 1700087

50 Ni L, Wu Z, Zhao G, Sun C, Zhou C, Gong X, Diao G. Core-shell structure and interaction mechanism of g-MnO₂ coated sulfur for improved lithium-sulfur batteries. Small, 2017, 13(14): 1603466

51 Pang Q, Tang J, Huang H, Liang X, Hart C, Tam K C, Nazar L F. A nitrogen and sulfur dual-doped carbon derived from polyrhodanine@ cellulose for advanced lithium-sulfur batteries. Advanced Materials, 2015, 27(39): 6021–6028

52 Zhao J, Pei S, Ren W, Gao L, Cheng H M. Efficient preparation of large-area graphene oxide sheets for transparent conductive films. ACS Nano, 2010, 4(9): 5245–5252

53 Zhou G, Yin L C, Wang D W, Li L, Pei S, Gentle I R, Li F, Cheng H M. Fibrous hybrid of graphene and sulfur nanocrystals for high-performance lithium-sulfur batteries. ACS Nano, 2013, 7(6): 5367–5375

54 Yuan S, Guo Z, Wang L, Hu S, Wang Y, Xia Y. Leaf-like graphene-oxide-wrapped sulfur for high-performance lithium-sulfur battery. Advancement of Science, 2015, 2(8): 1500071

55 Tang Q, Jiang L, Liu J, Wang S, Sun G. Effect of surface manganese valence of manganese oxides on the activity of the oxygen reduction reaction in alkaline media. ACS Catalysis, 2014, 4(2): 457–463

56 Chulliyote R, Hareendrakrishnakumar H, Raja M, Gladis J M, Stephan A M. Sulfur-immobilized nitrogen and oxygen co-doped hierarchically porous biomass carbon for lithium-sulfur batteries: Influence of sulfur content and distribution on its performance. ChemistrySelect, 2017, 2(32): 10484–10495

57 Liu Y, Zhao X, Chauhan G S, Ahn J H. Nanostructured nitrogen-doped mesoporous carbon derived from polyacrylonitrile for advanced lithium sulfur batteries. Applied Surface Science, 2016, 380: 151–158

58 Wu H, Mou J, Zhou L, Zheng Q, Jiang N, Lin D. Cloud cap-like, hierarchically porous carbon derived from mushroom as an excellent host cathode for high performance lithium-sulfur batteries. Electrochimica Acta, 2016, 212: 1021–1030

59 Wu Y, Xu C, Guo J, Su Q, Du G, Zhang J. Enhanced electrochemical performance by wrapping graphene on carbon nanotube/sulfur composites for rechargeable lithium-sulfur batteries. Materials Letters, 2014, 137: 277–280

60 Guo J, Zhang J, Jiang F, Zhao S, Su Q, Du G. Microporous carbon nanosheets derived from corncobs for lithium-sulfur batteries. Electrochimica Acta, 2015, 176: 853–860

61 Zhang J, Xiang J, Dong Z, Liu Y, Wu Y, Xu C, Du G. Biomass derived activated carbon with 3D connected architecture for rechargeable lithium-sulfur batteries. Electrochimica Acta, 2014, 116: 146–151

62 Wei S, Zhang H, Huang Y, Wang W, Xia Y, Yu Z. Pig bone derived hierarchical porous carbon and its enhanced cycling performance of lithium-sulfur batteries. Energy & Environmental Science, 2011, 4(3): 736–740

63 Qin F, Zhang K, Fang J, Lai Y, Li Q, Zhang Z, Li J. High performance lithium sulfur batteries with a cassava-derived carbon sheet as a polysulfides inhibitor. New Journal of Chemistry, 2014, 38(9): 4549–4554

64 You X L, Liu L J, Zhang M Y, Walle M D, Li Y, Liu Y N. Novel biomass derived hierarchical porous carbon for lithium sulfur batteries. Materials Letters, 2018, 217: 167–170

65 Zhao X, Kim M, Liu Y, Ahn H J, Kim K W, Cho K K, Ahn J H. Root-like porous carbon nanofibers with high sulfur loading enabling superior areal capacity of lithium sulfur batteries. Carbon, 2018, 128: 138–146

66 Zhao Y, Ren J, Tan T, Babaa M R, Bakenov Z, Liu N, Zhang Y. Biomass waste inspired highly porous carbon for high performance lithium/sulfur batteries. Nanomaterials (Basel, Switzerland), 2017, 7(9): 260

67 Feng J, Qin X, Ma Z, Yang J, Yang W, Shao G. A novel acetylene black/sulfur@ graphene composite cathode with unique three-dimensional sandwich structure for lithium-sulfur batteries. Electrochimica Acta, 2016, 190: 426–433

68 Zhang J, Dong Z, Wang X, Zhao X, Tu J, Su Q, Du G. Sulfur nanocrystals anchored graphene composite with highly improved electrochemical performance for lithium-sulfur batteries. Journal of Power Sources, 2014, 270: 1–8

69 Chen F, Yang J, Bai T, Long B, Zhou X. Biomass waste-derived honeycomb-like nitrogen and oxygen dual-doped porous carbon for high performance lithium-sulfur batteries. Electrochimica Acta, 2016, 192: 99–109

70 Stankovich S, Dikin D A, Piner R D, Kohlhaas K A, Kleinhammes A, Jia Y, Wu Y, Nguyen S T, Ruoff R S. Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon, 2007, 45(7): 1558–1565