RESEARCH ARTICLE

Diversity-oriented synthesis of blue emissive nitrogen heterocycles and their conjugation with carbon nano-onions

  • Viviana Maffeis 1 ,
  • Lisa Moni 2 ,
  • Daniele Di Stefano 2 ,
  • Silvia Giordani , 1,3 ,
  • Renata Riva , 4
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  • 1. Nano Carbon Materials, Istituto Italiano di Tecnologia (IIT), 10144 Torino, Italy
  • 2. Department of Chemistry and Industrial Chemistry, University of Genova, 16146 Genova, Italy
  • 3. School of Chemical Sciences, Dublin City University, Dublin 9, Ireland
  • 4. Department of Pharmacy, University of Genova, 16147 Genova, Italy

Received date: 30 Nov 2018

Accepted date: 08 Feb 2019

Published date: 15 Feb 2020

Copyright

2019 Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature

Abstract

The search for new fluorescent molecules for possible applications as functional p-electron systems and their conjugation with different nanomaterials is nowadays of paramount importance to broaden the availability of materials with different properties. Herein we present a diversity-oriented approach to heterocyclic luminophores based on a multicomponent Ugi reaction followed by a Pd-mediated cascade sequence. The new molecules are coupled to carbon nano-onions, and hybrid systems represent the first example of blue emitters conjugated with these carbon nanoparticles.

Cite this article

Viviana Maffeis , Lisa Moni , Daniele Di Stefano , Silvia Giordani , Renata Riva . Diversity-oriented synthesis of blue emissive nitrogen heterocycles and their conjugation with carbon nano-onions[J]. Frontiers of Chemical Science and Engineering, 2020 , 14(1) : 76 -89 . DOI: 10.1007/s11705-019-1833-0

Acknowledgements

Istituto Italiano di Tecnologia and the University of Genova are gratefully acknowledged for financial support. S.G. acknowledges the COST Action CA 15107 “Multi-Functional Nano-Carbon Composite Materials Network (MultiComp)”. The authors wish to thank Prof. Luis Echegoyen (UTEP) for supervising V.M. in the synthesis of pristine CNOs.
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