Frontiers of Chemical Science and Engineering >
Synthesis of aluminum nanoparticles as additive to enhance ignition and combustion of high energy density fuels
Received date: 07 Aug 2017
Accepted date: 31 Oct 2017
Published date: 18 Sep 2018
Copyright
High energy density fuels are critical for hypersonic aerospace propulsion but suffer from difficulties of ignition delay and incomplete combustion. This research reports aluminum nanoparticles (Al NPs) assisted ignition and combustion of high energy density JP-10 fuel. Al NPs with a size of 16 nm were fabricated through a mild and simple method by decomposing AlH3·Et2O with the addition of a surfactant ligand. The uniform size distribution, nanoscaled size and surface ligand make Al NPs stably suspend in JP-10, with 80% NPs being dispersed in the liquid fuel after six months. A shock tube test shows that the presence of 1 wt-% Al NPs can significantly shorten ignition delay time at temperature of 1500 to 1750 K, promote the combustion, and enhance energy release of JP-10. This work demonstrates the potential of Al NPs as ignition and combustion additive for high energy density fuel in hypersonic applications.
Xiu-Tian-Feng E , Lei Zhang , Fang Wang , Xiangwen Zhang , Ji-Jun Zou . Synthesis of aluminum nanoparticles as additive to enhance ignition and combustion of high energy density fuels[J]. Frontiers of Chemical Science and Engineering, 2018 , 12(3) : 358 -366 . DOI: 10.1007/s11705-018-1702-2
1 |
Chung H S, Chen C S H, Kremer R A, Boulton J R, Burdette G W. Recent developments in high-energy density liquid hydrocarbon fuels. Energy & Fuels, 1999, 13(3): 641–649
|
2 |
Keshavarz M H, Monjezi K H, Esmailpour K, Zamani M. Performance assessment of some isomers of saturated polycyclic hydrocarbons for use as jet fuel. Propellants, Explosives, Pyrotechnics, 2015, 40(2): 309–314
|
3 |
Sibi M G, Singh B, Kumar R, Pendem C, Sinha A K. Single-step catalytic liquid-phase hydroconversion of DCPD into high energy density fuel exo-THDCPD. Green Chemistry, 2012, 14(4): 976–983
|
4 |
Wang L, Zou J-J, Zhang X, Wang L. Isomerization of tetrahydrodicyclopentadiene using ionic liquid: Green alternative for jet propellant-10 and adamantine. Fuel, 2012, 91(1): 164–169
|
5 |
Huang M Y, Wu J C, Shieu F S, Lin J J. Isomerization of endotetrahydrodicyclopentadiene over clay-supported chloroaluminate ionic liquid catalysts. Journal of Molecular Catalysis A Chemical, 2010, 315(1): 69–75
|
6 |
Zou J-J, Xiong Z, Zhang X, Liu G, Wang L, Mi Z. Kinetics of tricyclopentadiene hydrogenation over Pd-B/γ-Al2O3 amorphous catalyst. Industrial & Engineering Chemistry Research, 2007, 46(13): 4415–4420
|
7 |
Wang L, Zou J-J, Zhang X, Wang L. Rearrangement of tetrahydrotricyclopentadiene using acidic ionic liquid: Synthesis of diamondoid fuel. Energy & Fuels, 2011, 25(4): 1342–1347
|
8 |
Zou J-J, Zhang X, Kong J, Wang L. Hydrogenation of dicyclopentadiene over amorphous nickel alloy catalyst SRNA-4. Fuel, 2008, 87(17): 3655–3659
|
9 |
Zou J-J, Xiong Z, Wang L, Zhang X, Mi Z. Preparation of Pd-B/γ-Al2O3 amorphous catalyst for the hydrogenation of tricyclopentadiene. Journal of Molecular Catalysis A Chemical, 2007, 271(1-2): 209–215
|
10 |
E X-T-F, Zhang Y, Zou J-J, Wang L, Zhang X. Oleylamine-protected metal (Pt, Pd) nanoparticles for pseudohomogeneous catalytic cracking of JP-10 jet fuel. Industrial & Engineering Chemistry Research, 2014, 53(31): 12312–12318
|
11 |
E X-T-F, Zhang Y, Zou J-J, Zhang X, Wang L. Shape evolution in Brust-Schiffrin synthesis of Au nanoparticles. Materials Letters, 2014, 118(3): 196–199
|
12 |
Van Devener B, Anderson S L. Breakdown and combustion of JP-10 fuel catalyzed by nanoparticulate CeO2 and Fe2O3. Energy & Fuels, 2006, 20(5): 1886–1894
|
13 |
Shimizu T, Abid A D, Poskrebyshev G, Wang H, Nabity J, Engel J, Yu J, Wickham D, Van Devener B, Anderson S L, Williams S. Methane ignition catalyzed by in situ generated palladium nanoparticles. Combustion and Flame, 2010, 157(3): 421–435
|
14 |
Van Devener B, Anderson S L, Shimizu T, Wang H, Nabity J, Engel J, Yu J, Wickham D, Williams S. In situ generation of Pd/PdO nanoparticle methane combustion catalyst: Correlation of particle surface chemistry with ignition. Journal of Physical Chemistry C, 2015, 80033(80138): 20632–20639
|
15 |
Guo Y, Yang Y, Fang W, Hu S. Resorcinarene-encapsulated Ni-B nano-amorphous alloys for quasi-homogeneous catalytic cracking of JP-10. Applied Catalysis A, General, 2014, 469(3): 213–220
|
16 |
E X-T-F, Pan L, Wang F, Wang L, Zhang X, Zou J-J. Al-nanoparticle-containing nanofluid fuel: Synthesis, stability, properties, and propulsion performance. Industrial & Engineering Chemistry Research, 2016, 55(10): 2738–2745
|
17 |
Allen C, Mittal G, Sung C J, Toulson E, Lee T. An aerosol rapid compression machine for studying energetic-nanoparticle-enhanced combustion of liquid fuels. Proceedings of the Combustion Institute, 2011, 33(2): 3367–3374
|
18 |
Starik A M, Kuleshov P S, Sharipov A S, Titova N S. Kinetics of ignition and combustion in the Al-CH4-O2 System. Energy & Fuels, 2014, 28(10): 6579–6588
|
19 |
Smirnov V V, Kostritsa S A, Kobtsev V D, Titova N S, Starik A M. Experimental study of combustion of composite fuel comprising n-decane and aluminum nanoparticles. Combustion and Flame, 2015, 162(10): 3554–3561
|
20 |
Haber J A, Buhro W E. Kinetic instability of nanocrystalline aluminum prepared by chemical synthesis; facile room-temperature grain growth. Journal of the American Chemical Society, 1998, 120(42): 10847–10855
|
21 |
Jouet R J, Warren A D, Rosenberg D M, Bellitto V J, Park K, Zachariah M R. Surface passivation of bare aluminum nanoparticles using perfluoroalkyl carboxylic acids. Chemistry of Materials, 2005, 800(17): 2987–2996
|
22 |
Jouet R J, Carney J R, Granholm R H, Sandusky H W, Warren A D. Preparation and reactivity analysis of novel perfluoroalkyl coated aluminium nanocomposites. Materials Science and Technology, 2006, 22(4): 422–429
|
23 |
Foley T J, Johnson C E, Higa K T. Inhibition of oxide formation on aluminum nanoparticles by transition metal coating. Chemistry of Materials, 2005, 17(16): 4086–4091
|
24 |
Fernando K A S, Smith M J, Harruff B A, Lewis W K, Guliants E A, Bunker C E. Sonochemically assisted thermal decomposition of alane N,N-dimethylethylamine with titanium (IV) isopropoxide in the presence of oleic acid to yield air-stable and size-selective aluminum core-shell nanoparticles. Journal of Physical Chemistry C, 2009, 113(2): 500–503
|
25 |
Xu S, Liao Q. Shock tube study on auto-ignition delay of kerosene aerosol and its cracked mixture. Procedia Engineering, 2015, 99(1): 338–343
|
26 |
Goulet P J G, Lennox R B. New insights into Brust-Schiffrin metal nanoparticle synthesis. Journal of the American Chemical Society, 2010, 132(28): 9582–9584
|
27 |
Xia Y, Xiong Y, Lim B, Skrabalak S E. Shape-controlled synthesis of metal nanocrystals: Simple chemistry meets complex physics? Angewandte Chemie International Edition, 2009, 48(1): 60–103
|
28 |
Lewis W K, Rosenberger A T, Gord J R, Crouse C A, Harruff B A, Shiral Fernando K A, Smith M J, Phelps D K, Spowart J E, Guliants E A,
|
29 |
Bournel F, Laffon C, Parent P, Tourillon G. Adsorption of acrylic acid on aluminium at 300 K: A multi-spectroscopic study. Surface Science, 1996, 352-354(95): 228–231
|
30 |
Lee H M, Kim Y J. Preparation of size-controlled fine Al particles for application to rear electrode of Si solar cells. Solar Energy Materials and Solar Cells, 2011, 95(12): 3352–3358
|
31 |
Hammerstroem D W, Burgers M A, Chung S W, Guliants E A, Bunker C E, Wentz K M, Hayes S E, Buckner S W, Jelliss P A. Aluminum nanoparticles capped by polymerization of alkyl-substituted epoxides: Ratio-dependent stability and particle size. Inorganic Chemistry, 2011, 50(11): 5054–5059
|
32 |
Gan Y, Qiao L. Combustion characteristics of fuel droplets with addition of nano and micron-sized aluminum particles. Combustion and Flame, 2011, 158(2): 354–368
|
33 |
Zhao Y, Yi H, Jia F, Li H, Peng C, Song S. A novel method for determining the thickness of hydration shells on nanosheets: A case of montmorillonite in water. Powder Technology, 2017, 306(7): 74–79
|
34 |
Davidson D F, Horning D C, Herbon J T, Hanson R K. Shock tube measurements of JP-10 ignition. Proceedings of the Combustion Institute, 2000, 28(2): 1687–1692
|
35 |
Li Y, Kalia R K, Nakano A, Vashishta P. Size effect on the oxidation of aluminum nanoparticle: Multimillion-atom reactive molecular dynamics simulations. Journal of Applied Physics, 2013, 114(13): 134312–134322
|
36 |
Levitas V I. Burn time of aluminum nanoparticles: Strong effect of the heating rate and melt-dispersion mechanism. Combustion and Flame, 2009, 156(2): 543–546
|
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