RESEARCH ARTICLE

Oil bleed from elastomeric thermal silicone conductive pads

  • Yuqi Chen 1 ,
  • Yakai Feng , 1,2 ,
  • Jingqi Zhao 3 ,
  • Jingbo Shen 3 ,
  • Menghuang Feng 3
Expand
  • 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
  • 2. Collaborative Innovation Center of Chemical Science and Chemical Engineering (Tianjin), Tianjin 300072, China
  • 3. Tianjin Laird Electronic Material Co., Ltd. Tianjin 300457, China

Received date: 18 Mar 2016

Accepted date: 26 May 2016

Published date: 29 Nov 2016

Copyright

2016 Higher Education Press and Springer-Verlag Berlin Heidelberg

Abstract

Oil bleed is a serious problem in elastomeric thermal silicone conductive pads. The components of the oil bleed and the effect of the silicone chemical parameters on the amount of oil bleed have been determined. The main components of oil bleeds are the uncrosslinked silicones in the cured resins, which include the unreacted silicone materials and the macromolecular substances produced by the hydrosilylation reaction. Cured resins with a high crosslinking density and a high molecular weight of vinyl silicone residues had a lower amount of oil bleed. In addition, a low Si-H content also reduced the amount of oil bleed.

Cite this article

Yuqi Chen , Yakai Feng , Jingqi Zhao , Jingbo Shen , Menghuang Feng . Oil bleed from elastomeric thermal silicone conductive pads[J]. Frontiers of Chemical Science and Engineering, 2016 , 10(4) : 509 -516 . DOI: 10.1007/s11705-016-1586-y

1
Sim L C, Ramanan S R, Ismail H, Seetharamu K N, Goh T J. Thermal characterization of Al2O3 and ZnO reinforced silicone rubber as thermal pads for heat dissipation purposes. Thermochimica Acta, 2005, 430(1-2): 155–165

DOI

2
Rachel G. Thermal interface materials: Opportunities and challenges for developers. Translational Materials Research, 2015, 2(2): 020301

DOI

3
Kim E S, Kim E J, Shim J H, Yoon J S. Thermal stability and ablation properties of silicone rubber composites. Journal of Applied Polymer Science, 2008, 110(2): 1263–1270

DOI

4
Jiang Q, Wang X, Zhu Y T, Hui D, Qiu Y P. Mechanical, electrical and thermal properties of aligned carbon nanotube/polyimide composites. Composites. Part B, Engineering, 2014, 56: 408–412

DOI

5
Crawford B, Doherty A P, Spedding P L, Herron W, Proctor M. Viscosity of siloxane gum and silicone rubbers. Asia-Pacific Journal of Chemical Engineering, 2010, 5(6): 882–894

DOI

6
Salam M H, El-Gamal S, El-Maqsoud D M, Abd Mohsen M. Correlation of electrical and swelling properties with nano free-volume structure of conductive silicone rubber composites. Polymer Composites, 2013, 34(12): 2105–2115

DOI

7
Zha J W, Zhu Y H, Li W K, Bai J B, Dang Z M. Low dielectric permittivity and high thermal conductivity silicone rubber composites with micro-nano-sized particles. Applied Physics Letters, 2012, 101(6): 062905

DOI

8
Zhou W Y, Wang C F, An Q L, Ou H Y. Thermal properties of heat conductive silicone rubber filled with hybrid fillers. Journal of Composite Materials, 2008, 42(2): 173–187

DOI

9
Chen L F, Xie H Q. Silicon oil based multiwalled carbon nanotubes nanofluid with optimized thermal conductivity enhancement. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 2009, 352(1-3): 136–140

DOI

10
Kemaloglu S, Ozkoc G, Aytac A. Properties of thermally conductive micro and nano size boron nitride reinforced silicon rubber composites. Thermochimica Acta, 2010, 499(1-2): 40–47

DOI

11
Cheng J P, Liu T, Zhang J, Wang B B, Ying J, Liu F, Zhang X B. Influence of phase and morphology on thermal conductivity of alumina particle/silicone rubber composites. Applied Physics. A, Materials Science & Processing, 2014, 117(4): 1985–1992

DOI

12
Mi Y N, Liang G Z, Gu A J, Zhao F P, Yuan L. Thermally conductive aluminum nitride-multiwalled carbon nanotube/cyanate ester composites with high flame retardancy and low dielectric loss. Industrial & Engineering Chemistry Research, 2013, 52(9): 3342–3353

DOI

13
Li T, Chen J, Dai H Y, Liu D W, Xiang H W, Chen Z P. Dielectric properties of CaCu3Ti4O12-silicone rubber composites. Journal of Materials Science Materials in Electronics, 2015, 26(1): 312–316

DOI

14
Paul D R, Mark J E. Fillers for polysiloxane (“silicone”) elastomers. Progress in Polymer Science, 2010, 35(7): 893–901

DOI

15
Mu Q H, Feng S G, Diao G Z. Thermal conductivity of silicone rubber filled with ZnO. Polymer Composites, 2007, 28(2): 125–130

DOI

16
Ventura I A, Rahaman A, Lubineau G. The thermal properties of a carbon nanotube-enriched epoxy: Thermal conductivity, curing, and degradation kinetics. Journal of Applied Polymer Science, 2013, 130(4): 2722–2733

DOI

17
Wang X J, Zhang L Z, Pei L X. Thermal conductivity augmentation of composite polymer materials with artificially controlled filler shapes. Journal of Applied Polymer Science, 2014, 131(8): 39550

DOI

18
Gan L, Shang S M, Yuen M C W, Jiang S X, Luo N M. Facile preparation of graphene nanoribbon filled silicone rubber nanocomposite with improved thermal and mechanical properties. Composites. Part B, Engineering, 2015, 69: 237–242

DOI

19
Ionita M, Pandele A M, Crica L, Pilan L. Improving the thermal and mechanical properties of polysulfone by incorporation of graphene oxide. Composites. Part B, Engineering, 2014, 59: 133–139

DOI

20
Ji T, Zhang L Q, Wang W C, Liu Y, Zhang X F, Lu Y L. Cold plasma modification of boron nitride fillers and its effect on the thermal conductivity of silicone rubber/boron nitride composites. Polymer Composites, 2012, 33(9): 1473–1481

DOI

21
Wu L K, Ying J, Chen L T. Improvement of thermal conductivity of silicone by carbon nanotube array (CNTA). Advanced Materials Research, 2014, 1061-1062: 96–99

DOI

22
Zhou W Y, Qi S H, Tu C C, Zhao H Z, Wang C F, Kou J L. Effect of the particle size of Al2O3 on the properties of filled heat-conductive silicone rubber. Journal of Applied Polymer Science, 2007, 104(2): 1312–1318

DOI

23
Zhou W Y, Yu D M, Wang C F, An Q L, Qi S H. Effect of filler size distribution on the mechanical and physical properties of alumina-filled silicone rubber. Polymer Engineering and Science, 2008, 48(7): 1381–1388

DOI

24
Zhou W Y, Qi S H, Zhao H Z, Liu N L. Thermally conductive silicone rubber reinforced with boron nitride particle. Polymer Composites, 2007, 28(1): 23–28

DOI

25
Zou H, Zhang L Q, Tian M, Wu S Z, Zhao S H. Study on the structure and properties of conductive silicone rubber filled with nickel-coated graphite. Journal of Applied Polymer Science, 2010, 115(5): 2710–2717

DOI

26
René S, Stefan R L, Katrin A, Martina B, André B, Thomas G. Transparent silicone calcium fluoride nanocomposite with improved thermal conductivity. Macromolecular Materials and Engineering, 2015, 300(1): 80–85

DOI

27
Shang S M, Gan L, Yuen M C W, Jiang S X, Luo M N. Carbon nanotubes based high temperature vulcanized silicone rubber nanocomposite with excellent elasticity and electrical properties. Composites. Part A, Applied Science and Manufacturing, 2014, 66: 135–141

DOI

28
Das A, Kasaliwal G R, Jurk R, Boldt R, Fischer D, Stöckelhuber K W, Heinrich G. Rubber composites based on graphene nanoplatelets, expanded graphite, carbon nanotubes and their combination: A comparative study. Composites Science and Technology, 2012, 72(16): 1961–1967

DOI

29
Wang Q, Gao W, Xie Z M. Highly thermally conductive room-temperature-vulcanized silicone rubber and silicone grease. Journal of Applied Polymer Science, 2003, 89(9): 2397–2399

DOI

30
Stein J, Lewis L N, Gao Y, Scott R A. In situ determination of the active catalyst in hydrosilylation reactions using highly reactive Pt(0) catalyst precursors. Journal of the American Chemical Society, 1999, 121(15): 3693–3703

DOI

31
Lweis L N, Colborn R E, Grade H, Bryant G L Jr, Sumpter C A, Scott R A. Mechanism of formation of platinum(0) complexes containing silicon-vinyl ligands. Organometallics, 1995, 14(5): 2202–2213

DOI

32
Zhao M, Feng Y K, Li G, Li Y, Wang Y L, Han Y, Sun X J, Tan X H. Synthesis of an adhesion-enhancing polysiloxane containing epoxy groups for addition-cure silicone light emitting diodes encapsulant. Polymers for Advanced Technologies, 2014, 25(9): 927–933

DOI

33
Zhao M, Feng Y K, Li G, Li Y, Wang Y L, Han Y, Sun X J, Tan X H. Preparation and performance of phenyl-vinyl-POSS/addition-type curable silicone rubber hybrid material. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 2014, 51(8): 639–645

DOI

34
Zhao M, Feng Y K, Li G, Li Y, Wang Y L, Han Y, Sun X J, Tan X H. Fabrication of siloxane hybrid material with high adhesion and high refractive index for light emitting diodes (LEDs) encapsulation. Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 2014, 51(8): 653–658

DOI

35
Gan L, Shang S M, Jiang S X. Impact of vinyl concentration of a silicone rubber on the properties of the graphene oxide filled silicone rubber composites. Composites. Part B, Engineering, 2016, 84: 294–300

DOI

Outlines

/