Enhanced C3H6/C3H8 separation performance in polysulfone membrane blended with rigid ZIF-8 crystals
Jiayu Luo, Luxi Lyu, Zongjie Yin, Yanying Wei
Enhanced C3H6/C3H8 separation performance in polysulfone membrane blended with rigid ZIF-8 crystals
Metal-organic frameworks have a wide range of applications in the field of membrane separation, but the inherent flexible structure and the difficulty for scale-up hinder their further applications. Herein, the relatively rigid zeolitic imidazolate framework-8 particles prepared under an electric field (E-ZIF-8) were used as the fillers in polysulfone (PSF) to form series of mixed matrix membranes. It was found that the introduction of E-ZIF-8 improves both the C3H6 permeability and C3H6/C3H8 selectivity of the membranes. Compared with the bare PSF membrane, the C3H6/C3H8 selectivity of the 30 wt % E-ZIF-8@PSF membrane increased by ~230%, while the C3H6 permeability was enhanced by ~830%. In addition, time and pressure dependence analysis demonstrated that such E-ZIF-8@PSF membranes also exhibited good long-term stability and pressure resistance, offering significant industrialization advantages.
gas separation / metal-organic frameworks / mixed matrix membranes
[1] |
Azhin M , Kaghazchi T , Rahmani M . A review on olefin/paraffin separation using reversible chemical complexation technology. Journal of Industrial and Engineering Chemistry, 2008, 14(5): 622–638
CrossRef
Google scholar
|
[2] |
Bryan P F . Removal of propylene from fuel-grade propane. Separation and Purification Reviews, 2004, 33(2): 157–182
CrossRef
Google scholar
|
[3] |
Fallanza M , Ortiz A , Gorri D , Ortiz I . Experimental study of the separation of propane/propylene mixtures by supported ionic liquid membranes containing Ag+-rtils as carrier. Separation and Purification Technology, 2012, 97: 83–89
CrossRef
Google scholar
|
[4] |
PanYLiTLestariGLaiZ. Effective separation of propylene/propane binary mixtures by ZIF-8 membranes. Journal of Membrane Science, 2012, 390–391: 93–98
|
[5] |
Deng J , Lu Z , Ding L , Li Z K , Wei Y , Caro J , Wang H . Fast electrophoretic preparation of large-area two-dimensional titanium carbide membranes for ion sieving. Chemical Engineering Journal, 2021, 408: 127806
CrossRef
Google scholar
|
[6] |
Liu H , Chen Y , Wei Y , Wang H . CO2-tolerant U-shaped hollow fiber membranes for hydrogen separation. International Journal of Hydrogen Energy, 2017, 42(7): 4208–4215
CrossRef
Google scholar
|
[7] |
Li L , Duan Y , Liao S , Ke Q , Qiao Z , Wei Y . Adsorption and separation of propane/propylene on various ZIF-8 polymorphs: insights from GCMC simulations and the ideal adsorbed solution theory (IAST). Chemical Engineering Journal, 2020, 386: 123945
CrossRef
Google scholar
|
[8] |
Zhou Y , Zhang Y , Xue J , Wang R , Yin Z , Ding L , Wang H . Graphene oxide-modified g-C3N4 nanosheet membranes for efficient hydrogen purification. Chemical Engineering Journal, 2021, 420(1): 129574
CrossRef
Google scholar
|
[9] |
Burns R L , Koros W J . Defining the challenges for C3H6/C3H8 separation using polymeric membranes. Journal of Membrane Science, 2003, 211(2): 299–309
CrossRef
Google scholar
|
[10] |
Steel K M , Koros W J . An investigation of the effects of pyrolysis parameters on gas separation properties of carbon materials. Carbon, 2005, 43(9): 1843–1856
CrossRef
Google scholar
|
[11] |
Xu L , Rungta M , Koros W J . Matrimid derived carbon molecular sieve hollow fiber membranes for ethylene/ethane separation. Journal of Membrane Science, 2011, 380(1–2): 138–147
CrossRef
Google scholar
|
[12] |
Ma X , Lin Y S , Wei X , Kniep J . Ultrathin carbon molecular sieve membrane for propylene/propane separation. AIChE Journal. American Institute of Chemical Engineers, 2016, 62(2): 491–499
CrossRef
Google scholar
|
[13] |
Kosinov N , Gascon J , Kapteijn F , Hensen E J . Recent developments in zeolite membranes for gas separation. Journal of Membrane Science, 2016, 499: 65–79
CrossRef
Google scholar
|
[14] |
Gascon J , Kapteijn F , Zornoza B , Sebastian V , Casado C , Coronas J . Practical approach to zeolitic membranes and coatings: state of the art, opportunities, barriers, and future perspectives. Chemistry of Materials, 2012, 24(15): 2829–2844
CrossRef
Google scholar
|
[15] |
Zhou X , Miao G , Xu G , Luo J , Yang C , Xiao J . Mixed (Ag+, Ca2+)-LTA zeolite with suitable pore feature for effective separation of C3H6/C3H8. Chemical Engineering Journal, 2022, 450(1): 137913
CrossRef
Google scholar
|
[16] |
An H , Cho K , Back S , Do X , Jeon J D , Lee H , Baek K Y , Lee J . The significance of the interfacial interaction in mixed matrix membranes for enhanced propylene/propane separation performance and plasticization resistance. Separation and Purification Technology, 2021, 261: 118279
CrossRef
Google scholar
|
[17] |
Chen Y , Qiao Z , Lv D , Duan C , Sun X , Wu H , Shi R , Xia Q , Li Z . Efficient adsorptive separation of C3H6 over C3H8 on flexible and thermoresponsive CPL-1. Chemical Engineering Journal, 2017, 328: 360–367
CrossRef
Google scholar
|
[18] |
Yuan Y , Wu H , Xu Y , Lv D , Tu S , Wu Y , Li Z , Xia Q . Selective extraction of methane from C1/C2/C3 on moisture-resistant MIL-142A with interpenetrated networks. Chemical Engineering Journal, 2020, 395: 125057
CrossRef
Google scholar
|
[19] |
Chen Y , Wu H , Yu L , Tu S , Wu Y , Li Z , Xia Q . Separation of propylene and propane with pillar-layer metal-organic frameworks by exploiting thermodynamic-kinetic synergetic effect. Chemical Engineering Journal, 2022, 431(4): 133284
CrossRef
Google scholar
|
[20] |
Li K , Olson D H , Seidel J , Emge T J , Gong H , Zeng H , Li J . Zeolitic imidazolate frameworks for kinetic separation of propane and propene. Journal of the American Chemical Society, 2009, 131(30): 10368–10369
CrossRef
Google scholar
|
[21] |
Zhang C , Lively R P , Zhang K , Johnson J R , Karvan O , Koros W J . Unexpected molecular sieving properties of zeolitic imidazolate framework-8. Journal of Physical Chemistry Letters, 2012, 3(16): 2130–2134
CrossRef
Google scholar
|
[22] |
Kwon H T , Jeong H K , Lee A S , An H S , Lee J S . Heteroepitaxially grown zeolitic imidazolate framework membranes with unprecedented propylene/propane separation performances. Journal of the American Chemical Society, 2015, 137(38): 12304–12311
CrossRef
Google scholar
|
[23] |
Knebel A , Geppert B , Volgmann K , Kolokolov D I , Stepanov A G , Twiefel J , Heitjans P , Volkmer D , Caro J . Defibrillation of soft porous metal-organic frameworks with electric fields. Science, 2017, 358(6361): 347–351
CrossRef
Google scholar
|
[24] |
Zhou S , Wei Y , Li L , Duan Y , Hou Q , Zhang L , Ding L X , Xue J , Wang H , Caro J . Paralyzed membrane: current-driven synthesis of a metal-organic framework with sharpened propene/propane separation. Science Advances, 2018, 4(10): eaau1393
CrossRef
Google scholar
|
[25] |
Hillman F , Zimmerman J M , Paek S M , Hamid M R A , Lim W T , Jeong H K . Rapid microwave-assisted synthesis of hybrid zeolitic–imidazolate frameworks with mixed metals and mixed linkers. Journal of Materials Chemistry. A, Materials for Energy and Sustainability, 2017, 5(13): 6090–6099
CrossRef
Google scholar
|
[26] |
Fan W , Ying Y , Peh S B , Yuan H , Yang Z , Yuan Y D , Shi D , Yu X , Kang C , Zhao D . Multivariate polycrystalline metal-organic framework membranes for CO2/CH4 separation. Journal of the American Chemical Society, 2021, 143(42): 17716–17723
CrossRef
Google scholar
|
[27] |
Lee M J , Kwon H T , Jeong H K . High-flux zeolitic imidazolate framework membranes for propylene/propane separation by postsynthetic linker exchange. Angewandte Chemie International Edition, 2018, 57(1): 156–161
CrossRef
Google scholar
|
[28] |
Hou Q , Zhou S , Wei Y , Caro J , Wang H . Balancing the grain boundary structure and the framework flexibility through bimetallic MOF membranes for gas separation. Journal of the American Chemical Society, 2020, 142(21): 9582–9586
CrossRef
Google scholar
|
[29] |
Choi E , Choi J I , Kim Y J , Kim Y J , Eum K , Choi Y , Kwon O , Kim M , Choi W , Ji H .
CrossRef
Google scholar
|
[30] |
Babu D J , He G , Hao J , Vahdat M T , Schouwink P A , Mensi M , Agrawal K V . Restricting lattice flexibility in polycrystalline metal-organic framework membranes for carbon capture. Advanced Materials, 2019, 31(28): 1900855
CrossRef
Google scholar
|
[31] |
Zhou S , Shekhah O , Ramírez A , Lyu P , Abou-Hamad E , Jia J , Li J , Bhatt P M , Huang Z , Jiang H .
CrossRef
Google scholar
|
[32] |
Zhao Y , Yang X , Luo J , Wei Y , Wang H . Fast-current-driven synthesis of ultrathin ZIF-8 membrane on ceramic tube for propene/propane separation. AIChE Journal. American Institute of Chemical Engineers, 2023, 69(4): e17934
CrossRef
Google scholar
|
[33] |
Zhao Y , Yang X , Luo J , Wei Y , Wang H . Porous stainless steel hollow fiber-supported ZIF-8 membranes via FCDS for hydrogen/carbon dioxide separation. Separation and Purification Technology, 2022, 295: 121365
CrossRef
Google scholar
|
[34] |
Zhao Y , Wei Y , Lyu L , Hou Q , Caro J , Wang H . Flexible polypropylene-supported ZIF-8 membranes for highly efficient propene/propane separation. Journal of the American Chemical Society, 2020, 142(50): 20915–20919
CrossRef
Google scholar
|
[35] |
FlanigenE MBroachR WWilsonS T. Zeolites in Industrial Separation and Catalysis. 1st ed. Berlin: Wiley-VCH Verlag GmbH & Co. KGaA, 2010, 329–353
|
[36] |
Zhang C , Zhang K , Xu L , LaBreche Y , Kraftschik B , Koros W J . Highly scalable ZIF-based mixed-matrix hollow fiber membranes for advanced hydrocarbon separations. AIChE Journal. American Institute of Chemical Engineers, 2014, 60(7): 2625–2635
CrossRef
Google scholar
|
[37] |
Ma X , Swaidan R J , Wang Y , Hsiung C E , Han Y , Pinnau I . Highly compatible hydroxyl-functionalized microporous polyimide-ZIF-8 mixed matrix membranes for energy efficient propylene/propane separation. ACS Applied Nano Materials, 2018, 1(7): 3541–3547
CrossRef
Google scholar
|
[38] |
Park S , Abdul Hamid M R , Jeong H K . Highly propylene-selective mixed-matrix membranes by in situ metal-organic framework formation using a polymer-modification strategy. ACS Applied Materials & Interfaces, 2019, 11(29): 25949–25957
CrossRef
Google scholar
|
[39] |
Lyu L , Wu H , Li L , Wei Y , Wang H C . 3H6/C3H8 adsorption behavior study of stiffened ZIF-8 prepared under an electric field. Chemieingenieurtechnik, 2022, 94(1–2): 119–127
CrossRef
Google scholar
|
[40] |
Zhang Y , Jia Y , Li M , Hou L . Influence of the 2-methylimidazole/zinc nitrate hexahydrate molar ratio on the synthesis of zeolitic imidazolate framework-8 crystals at room temperature. Scientific Reports, 2018, 8(1): 9597
CrossRef
Google scholar
|
[41] |
Saliba D , Ammar M , Rammal M , Al-Ghoul M , Hmadeh M . Crystal growth of ZIF-8, ZIF-67, and their mixed-metal derivatives. Journal of the American Chemical Society, 2018, 140(5): 1812–1823
CrossRef
Google scholar
|
[42] |
Su N C , Sun D T , Beavers C M , Britt D K , Queen W L , Urban J J . Enhanced permeation arising from dual transport pathways in hybrid polymer-MOF membranes. Energy & Environmental Science, 2016, 9(3): 922–931
CrossRef
Google scholar
|
[43] |
Rupiasih N N , Suyanto H , Sumadiyasa M , Wendri N . Study of effects of low doses UV radiation on microporous polysulfone membranes in sterilization process. Open Journal of Organic Polymer Materials, 2013, 3(1): 12–18
CrossRef
Google scholar
|
[44] |
Bai S , Sridhar S , Khan A A . Metal-ion mediated separation of propylene from propane using PPO membranes. Journal of Membrane Science, 1998, 147(1): 131–139
CrossRef
Google scholar
|
[45] |
Sridhar S , Khan A A . Simulation studies for the separation of propylene and propane byepthylcellulose membrane. Journal of Membrane Science, 1999, 159(1–2): 209–219
CrossRef
Google scholar
|
[46] |
Staudt-Bickel C , Koros W J . Olefin/paraffin gas separations with 6FDA-based polyimide membranes. Journal of Membrane Science, 2000, 170(2): 205–214
CrossRef
Google scholar
|
[47] |
AskariMXiaoYLiPChungT S. Natural gas purification and olefin/paraffin separation using cross-linkable 6FDA-Durene/DABA co-polyimides grafted with α, β, and γ-cyclodextrin. Journal of Membrane Science, 2012, 390–391: 141–151
|
[48] |
Tanaka K , Taguchi A , Hao J Q , Kita H , Okamoto K . Permeation and separation properties of polyimide membranes to olefins and paraffins. Journal of Membrane Science, 1996, 121(2): 197–207
CrossRef
Google scholar
|
[49] |
Zhang C , Dai Y , Johnson J R , Karvan O , Koros W J . High performance ZIF-8/6FDA-DAM mixed matrix membrane for propylene/propane separations. Journal of Membrane Science, 2012, 389: 34–42
CrossRef
Google scholar
|
[50] |
Park S , Jeong H K . Cross-linked polyimide/ZIF-8 mixed-matrix membranes by in situ formation of ZIF-8: effect of cross-linking on their propylene/propane separation. Membranes, 2022, 12(10): 964
CrossRef
Google scholar
|
[51] |
Peng D , Feng X , Yang G , Niu X , Liu Z , Zhang Y . In-situ growth of silver complex on ZIF-8 towards mixed matrix membranes for propylene/propane separation. Journal of Membrane Science, 2023, 668: 121267
CrossRef
Google scholar
|
[52] |
Cheng Z , Zhang P , Wang Z , Jiang H , Wang W , Liu D , Wang L , Zhu G , Zou X . A bipyridyl covalent organic framework with coordinated Cu(I) for membrane C3H6/C3H8 separation. Small, 2023, 19(30): 2300438
CrossRef
Google scholar
|
[53] |
Su Y , Li D , Shan M , Feng X , Gascon J , Wang Y , Zhang Y . Uniformly distributed mixed matrix membranes via a solution processable strategy for propylene/propane separation. Angewandte Chemie International Edition, 2024, 63(7): e202316093
CrossRef
Google scholar
|
[54] |
Jung J P , Kim M J , Bae Y S , Kim J H . Facile preparation of Cu(I) impregnated MIL-101(Cr) and its use in a mixed matrix membrane for olefin/paraffin separation. Journal of Applied Polymer Science, 2018, 135(31): 46545
CrossRef
Google scholar
|
[55] |
Sun H , Ma C , Wang T , Xu Y , Yuan B , Li P , Kong Y . Preparation and characterization of C60-filled ethyl cellulose mixed-matrix membranes for gas separation of propylene/propane. Chemical Engineering & Technology, 2014, 37(4): 611–619
CrossRef
Google scholar
|
[56] |
Gholamipour N , Sadeghi M , Shafiei M . Effect of silica nanoparticles on the performance of polysulfone membranes for olefin-paraffin separation. Chemical Engineering & Technology, 2019, 42(11): 2292–2301
CrossRef
Google scholar
|
[57] |
Zhang Q , Li H , Chen S , Duan J , Jin W . Mixed-matrix membranes with soluble porous organic molecular cage for highly efficient C3H6/C3H8 separation. Journal of Membrane Science, 2020, 611: 118288
CrossRef
Google scholar
|
[58] |
Jiang H , Guo Z , Wang H , Liu X , Ren Y , Huang T , Xue J , Wu H , Zhang J , Yin Y .
CrossRef
Google scholar
|
/
〈 | 〉 |