NiFeRuOx nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawater splitting

Yu Liu , Lin Chen , Yong Wang , Yuan Dong , Liang Zhou , Susana I. Córdoba de Torresi , Kenneth I. Ozoemena , Xiao-Yu Yang

Front. Chem. Sci. Eng. ›› 2023, Vol. 17 ›› Issue (11) : 1698 -1706.

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Front. Chem. Sci. Eng. ›› 2023, Vol. 17 ›› Issue (11) : 1698 -1706. DOI: 10.1007/s11705-023-2334-8
RESEARCH ARTICLE
RESEARCH ARTICLE

NiFeRuOx nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawater splitting

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Abstract

The electrocatalyst NiFeRuOx/NF, comprised of NiFeRuOx nanosheets grown on Ni foam, was synthesized using a hydrothermal process followed by thermal annealing. NiFeRuOx/NF displays high electrocatalytic activity and stability for overall alkaline seawater splitting: 98 mV@ 10 mA∙cm−2 in hydrogen evolution reaction, 318 mV@ 50 mA∙cm−2 in oxygen evolution reaction, and a cell voltage of 1.53 V@ 10 mA∙cm−2, as well as 20 h of durability. A solar-driven system containing such a bifunctional NiFeRuOx/NF has an almost 100% Faradaic efficiency. The NiFeRuOx coating around Ni foam is an anti-corrosion layer and also a critical factor for enhancement of bifunctional performances.

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NiFeRuOx nanosheets / Ni foam / electrocatalysis / overall seawater splitting / solar-driven system

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Yu Liu,Lin Chen,Yong Wang,Yuan Dong,Liang Zhou,Susana I. Córdoba de Torresi,Kenneth I. Ozoemena,Xiao-Yu Yang. NiFeRuOx nanosheets on Ni foam as an electrocatalyst for efficient overall alkaline seawater splitting. Front. Chem. Sci. Eng., 2023, 17(11): 1698-1706 DOI:10.1007/s11705-023-2334-8

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