Improving hole transfer of boron nitride quantum dots modified PDI for efficient photodegradation
Shiqing Ma, Chundong Peng, Zeyu Jia, Yanmei Feng, Kai Chen, Hao Ding, Daimei Chen, Zhong-Yong Yuan
Improving hole transfer of boron nitride quantum dots modified PDI for efficient photodegradation
In recent years, organic photocatalyst under visible-light absorption has shown significant potential for solving environmental problems. However, it is still a great challenge for constructing a highly active organic photocatalyst due to the low separation efficiency of photogenerated carriers. Herein, an effective and robust photocatalyst perylene-3,4,9,10-tetracarboxylic diamide/boron nitride quantum dots (PDI/BNQDs), consisting of self-assemble PDI with π–π stacking structure and BNQDs, has been constructed and researched under visible light irradiation. The PDI/BNQDs composite gradually increases organic pollutant photodegradation with the loading amount of BNQDs. With 10 mL of BNQDs solution added (PDI/BNQDs-10), the organic pollutant photodegradation performance reaches a maximum, about 6.16 times higher with methylene blue and 1.68 times higher with ciprofloxacin than that of pure PDI supramolecular. The enhancement is attributed to improved separation of photogenerated carriers from self-assembled PDI by BNQDs due to their preeminent ability to extract holes. This work is significant for the supplement of PDI supramolecular composite materials. We believe that this photocatalytic design is capable of expanding organic semiconductors’ potential for their applications in photocatalysis.
PDI / boron nitride / quantum dots / photocatalysis / hole transfer
[1] |
Wang L, Zhang X, Yu X, Gao E, Shen Z, Zhang X, Ge S, Liu J, Gu Z J, Chen C. An all-organic semiconductor C3N4/PDINH heterostructure with advanced antibacterial photocatalytic therapy activity. Advanced Materials, 2019, 31(33): 190265
CrossRef
Google scholar
|
[2] |
Chen J, Li Y, Li J, Han J, Zhu G, Ren L. Crystal design of bismuth oxyiodide with highly exposed (110) facets on curved carbon nitride for the photocatalytic degradation of pollutants in wastewater. Frontiers of Chemical Science and Engineering, 2022, 16(7): 1125–1138
CrossRef
Google scholar
|
[3] |
Peng C, Jia Z, Zhong Y, Ao W, Chen D, Wang R, Ding H, Wu X, Wang J, Du G. Preparation of Bi3.64Mo0.36O6.55 by reflux method and its application in photodegradation of organic pollution. Journal of Materials Science Materials in Electronics, 2021, 32(13): 17890–17900
CrossRef
Google scholar
|
[4] |
Zhong Y, He Z, Chen D, Hao D, Hao W. Enhancement of photocatalytic activity of Bi2MoO6 by fluorine substitution. Applied Surface Science, 2019, 467: 740–748
CrossRef
Google scholar
|
[5] |
Takeda H, Kamiyama H, Okamoto K, Irimajiri M, Mizutani T, Koike K, Sekine A, Ishitani O. Highly efficient and robust photocatalytic systems for CO2 reduction consisting of a Cu(I) photosensitizer and Mn(I) catalysts. Journal of the American Chemical Society, 2018, 140(49): 17241–17254
CrossRef
Google scholar
|
[6] |
Miao H, Yang J, Wei Y, Li W, Zhu Y. Visible-light photocatalysis of PDI nanowires enhanced by plasmonic effect of the gold nanoparticles. Applied Catalysis B: Environmental, 2018, 239: 61–67
CrossRef
Google scholar
|
[7] |
Hu D, Fu J, Chen S, Li J, Yang Q, Gao J, Tang H, Kan Z, Duan T, Lu S, Sun K, Xiao Z. Block copolymers as efficients cathode interlayer materials for organic solar cells. Frontiers of Chemical Science and Engineering, 2021, 15(3): 571–578
CrossRef
Google scholar
|
[8] |
Fang X, Shang Q, Wang Y, Jiao L, Yao T, Li Y, Zhang Q, Luo Y, Jiang H L. Single Pt atoms confined into a metal-organic framework for efficient photocatalysis. Advanced Materials, 2018, 30(7): 1705112
CrossRef
Google scholar
|
[9] |
Wang G, He C T, Huang R, Mao J, Wang D, Li Y. Photoinduction of Cu single atoms decorated on UiO-66-NH2 for enhanced photocatalytic reduction of CO2 to liquid fuels. Journal of the American Chemical Society, 2020, 142(45): 19339–19345
CrossRef
Google scholar
|
[10] |
Zhao Y, Liu H, Wu C, Zhang Z, Pan Q, Hu F, Wang R, Li P, Huang X, Li Z. Fully sp2-carbon conjugated two-dimensional covalent organic frameworks as artificial photosystem I with unprecedented efficiency. Angewandte Chemie International Edition, 2019, 58(16): 5376–5381
CrossRef
Google scholar
|
[11] |
Wang S, Li D, Sun C, Yang S, Guan Y, He H. Synthesis and characterization of g-C3N4/Ag3VO4 composites with significantly enhanced visible-light photocatalytic activity for triphenylmethane dye degradation. Applied Catalysis B: Environmental, 2014, 144: 885–892
CrossRef
Google scholar
|
[12] |
Liao G, Gong Y, Zhang L, Gao H, Yang G J, Fang B. Semiconductor polymeric graphitic carbon nitride photocatalysts: the “holy grail” for the photocatalytic hydrogen evolution reaction under visible light. Energy & Environmental Science, 2019, 12(7): 2080–2147
CrossRef
Google scholar
|
[13] |
Li X B, Liu J Y, Huang J T, He C Z, Feng Z J, Chen Z, Wan L F, Deng F. All organic S-scheme heterojunction PDI-Ala/S-C3N4 photocatalyst with enhanced photocatalytic performance. Acta Physico Chimica Sinica, 2021, 37(6): 2010030
|
[14] |
Yang J, Miao H, Jing J, Zhu Y, Choi W. Photocatalytic activity enhancement of PDI supermolecular via π–π action and energy level adjusting with graphene quantum dots. Applied Catalysis B: Environmental, 2021, 281: 119547
CrossRef
Google scholar
|
[15] |
Fateeva A, Chater P A, Ireland C P, Tahir A A, Khimyak Y Z, Wiper P V, Darwent J R, Rosseinsky M J. A water-stable porphyrin-based metal–organic framework active for visible-light photocatalysis. Angewandte Chemie International Edition, 2021, 51(30): 7440–7444
CrossRef
Google scholar
|
[16] |
Rafiq M, Chen Z, Tang H, Hu Z, Zhang X, Xing Y, Li Y, Huang F. Water-alcohol-soluble hyperbranched polyelectrolytes and their application in polymer solar cells and photocatalysis. ACS Applied Polymer Materials, 2020, 2(1): 12–18
CrossRef
Google scholar
|
[17] |
Zhang Z, Zhu Y, Chen X, Zhang H, Wang J. A full-spectrum metal-free porphyrin supramolecular photocatalyst for dual functions of highly efficient hydrogen and oxygen evolution. Advanced Materials, 2019, 31(7): 1806626
CrossRef
Google scholar
|
[18] |
Weingarten A S, Kazantsev R V, Palmer L C, McClendon M, Koltonow A R, Samuel A P S, Kiebala D J, Wasielewski M R, Stupp S I. Self-assembling hydrogel scaffolds for photocatalytic hydrogen production. Nature Chemistry, 2014, 6(11): 964–970
CrossRef
Google scholar
|
[19] |
Chen P, Blaney L, Cagnetta G, Huang J, Wang B, Wang Y, Deng S, Yu G. Degradation of ofloxacin by perylene diimide supramolecular nanofiber sunlight-driven photocatalysis. Environmental Science & Technology, 2019, 53(3): 1564–1575
CrossRef
Google scholar
|
[20] |
Gao Q, Xu J, Wang Z, Zhu Y. Enhanced visible photocatalytic oxidation activity of perylene diimide/g-C3N4 n–n heterojunction via π–π interaction and interfacial charge separation. Applied Catalysis B: Environmental, 2020, 271: 118933
CrossRef
Google scholar
|
[21] |
Cheng W, Chen H, Ji C, Yang R, Yin M. A perylenediimide-based nanocarrier monitors curcumin release with an “off–on” fluorescence switch. Polymer Chemistry, 2019, 10(20): 2551–2558
CrossRef
Google scholar
|
[22] |
Zhang Z, Zhang L, Zhou L, Lei Y, Zhang Y, Huang C. Redox signaling and unfolded protein response coordinate cell fate decisions under ER stress. Redox Biology, 2019, 25: 101047
CrossRef
Google scholar
|
[23] |
Jung T H, Yoo B, Wang L, Dodabalapur A, Jones B A, Facchetti A, Wasielewski M R, Marks T J. Nanoscale n-channel and ambipolar organic field-effect transistors. Applied Physics Letters, 2006, 88(18): 183102
CrossRef
Google scholar
|
[24] |
Cheng H, Huai J, Gao L, Li Z. Novel self-assembled phosphonic acids monolayers applied in N-channel perylene diimide (PDI) organic field effect transistors. Applied Surface Science, 2016, 378: 545–551
CrossRef
Google scholar
|
[25] |
Macedo A G, Christopholi L P, Gavim A E X, de Deus J F, Teridi M A M, Yusoff A B, da Silva W J. Perylene derivatives for solar cells and energy harvesting: a review of materials, challenges and advances. Journal of Materials Science Materials in Electronics, 2019, 30(17): 15803–15824
CrossRef
Google scholar
|
[26] |
Dayneko S V, Cieplechowicz E, Bhojgude S S, Van Humbeck J F, Pahlevani M, Welch G C. Improved performance of solution processed OLEDs using N-annulated perylene diimide emitters with bulky side-chains. Materials Advances, 2021, 2(3): 933–936
CrossRef
Google scholar
|
[27] |
Ma L, Qin D, Liu Y, Zhan X. n-Type organic light-emitting transistors with high mobility and improved air stability. Journal of Materials Chemistry C, 2018, 6(3): 535–540
CrossRef
Google scholar
|
[28] |
Yang J, Liu C, Cai C, Hu X, Huang Z, Duan X, Meng X, Yuan Z, Tan L, Chen Y. High-performance perovskite solar cells with excellent humidity and thermo-stability via fluorinated perylene diimide. Advanced Energy Materials, 2019, 9(18): 1900198
CrossRef
Google scholar
|
[29] |
Kim Y O, Moon B J, Lee A, Kim J I, Lee S K, Lee Y S, Bae S, Hong B H, Jung Y C. A multifunctional tyrosine-immobilized PAH molecule as a universal cathode interlayer enables high-efficiency inverted polymer solar cells. Advanced Optical Materials, 2021, 9(21): 2101006
CrossRef
Google scholar
|
[30] |
Wang W, Li X, Deng F, Liu J, Gao X, Huang J, Xu J, Feng Z, Chen Z, Han L. Novel organic/inorganic PDI-urea/BiOBr S-scheme heterojunction for improved photocatalytic antibiotic degradation and H2O2 production. Chinese Chemical Letters, 2022, 33(12): 5200–5207
CrossRef
Google scholar
|
[31] |
Li X, Kang B, Dong F, Deng F, Han L, Gao X, Xu J, Hou X, Feng Z, Chen Z, Liu L, Huang J. BiOBr with oxygen vacancies capture 0D black phosphorus quantum dots for high efficient photocatalytic ofloxacin degradation. Applied Surface Science, 2022, 539: 153422
CrossRef
Google scholar
|
[32] |
Wei W, Wei Z, Liu D, Zhu Y. Enhanced visible-light photocatalysis via back-electron transfer from palladium quantum dots to perylene diimide. Applied Catalysis B: Environmental, 2018, 230: 49–57
CrossRef
Google scholar
|
[33] |
Han R, Liu F, Wang X, Huang M, Li W, Yamauchi Y, Sun X, Huang Z. Functionalised hexagonal boron nitride for energy conversion and storage. Journal of Materials Chemistry A, 2020, 8(29): 14384–14399
CrossRef
Google scholar
|
[34] |
Li H, Tay R Y, Tsang S H, Zhen X, Teo E H T. Controllable synthesis of highly luminescent boron nitride quantum dots. Small, 2015, 11(48): 6491–6499
CrossRef
Google scholar
|
[35] |
Yang Y, Zhang C, Huang D, Zeng G, Huang J, Lai C, Zhou C, Wang W, Guo H, Xue W, Deng R, Cheng M, Xiong W. Boron nitride quantum dots decorated ultrathin porous g-C3N4: intensified exciton dissociation and charge transfer for promoting visible-light-driven molecular oxygen activation. Applied Catalysis B: Environmental, 2019, 245: 87–99
CrossRef
Google scholar
|
[36] |
Guo Y, Nie Y, Liang Z, Peilin W, Ma Q. Ag3PO4 NP@MoS2 nanosheet enhanced F, S-doped BN quantum dot electrochemiluminescence biosensor for K-ras tumor gene detection. Talanta, 2021, 228: 122221
CrossRef
Google scholar
|
[37] |
Huo B, Liu B, Chen T, Cui L, Xu G, Liu M, Liu J. One-step synthesis of fluorescent boron nitride quantum dots via a hydrothermal strategy using melamine as nitrogen source for the detection of ferric ions. Langmuir, 2017, 33(40): 10673–10678
CrossRef
Google scholar
|
[38] |
Wei Z, Liu M, Zhang Z, Yao W, Tan H, Zhu Y. Efficient visible-light-driven selective oxygen reduction to hydrogen peroxide by oxygen-enriched graphitic carbon nitride polymers. Energy & Environmental Science, 2018, 11(9): 2581–2589
CrossRef
Google scholar
|
[39] |
Li C, Che H, Liu C, Che G, Charpentier P A, Xu W, Wang X, Liu L. Facile fabrication of g-C3N4 QDs/BiVO4 Z-scheme heterojunctiontowards enhancing photodegradation activity under visible light. Journal of the Taiwan Institute of Chemical Engineers, 2019, 95: 669–681
CrossRef
Google scholar
|
[40] |
Cassabois G, Valvin P, Gil B. Hexagonal boron nitride is an indirect bandgap semiconductor. Nature Photonics, 2016, 10(4): 262–266
CrossRef
Google scholar
|
[41] |
Ding Y, He P, Li S, Chang B, Zhang S, Wang Z, Chen J, Yu J, Wu S, Zeng H, Tao L. Efficient full-color boron nitride quantum dots for thermostable flexible displays. ACS Nano, 2021, 15(9): 14610–14617
CrossRef
Google scholar
|
/
〈 | 〉 |