Engineering the electronic and geometric structure of VO_x/BN@TiO₂ heterostructure for efficient aerobic oxidative desulfurization

Abstract

Particle size governs the electronic and geometric structure of metal nanoparticles (NPs), shaping their catalytic performances in heterogeneous catalysis. However, precisely controlling the size of active metal NPs and thereafter their catalytic activities remain an affordable challenge in ultra-deep oxidative desulfurization (ODS) field. Herein, a series of highly-efficient VO_x/boron nitride nanosheets (BNNS)@TiO₂ heterostructures, therein, cetyltrimethylammonium bromide cationic surfactants serving as intercalation agent, BNNS and MXene as precursors, with various VO_x NP sizes were designed and controllably constructed by a facile intercalation confinement strategy. The properties and structures of the prepared catalysts were systematically characterized by different technical methods, and their catalytic activities were investigated for aerobic ODS of dibenzothiophene (DBT). The results show that the size of VO_x NPs and V⁵⁺/V⁴⁺ play decisive roles in the catalytic aerobic ODS of VO_x/BNNS@TiO₂ catalysts and that VO_x/BNNS@TiO₂-2 exhibits the highest ODS activity with 93.7% DBT conversion within 60 min under the reaction temperature of 130 °C and oxygen flow rate of 200 mL·min^–1, which is due to its optimal VO_x dispersion, excellent reducibility and abundant active species. Therefore, the finding here may contribute to the fundamental understanding of structure-activity in ultra-deep ODS and inspire the advancement of highly-efficient catalyst.

Graphical abstract

Keywords

oxidative desulfurization / boron nitride / vanadium / MXene / intercalation confinement

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (Grant Nos. 22178154 and 22002050), the Postdoctoral Science Foundation of China (Grant Nos. 2022T150765 and 2020M683154), Project of Jiangsu University Senior Talents Foundation (Grant No. 20JDG35) and National Engineering Laboratory for Mobile Source Emission Control Technology (Grant No. NELMS2020B01).

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-022-2242-3 and is accessible for authorized users.

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