Enhanced charge extraction for all-inorganic perovskite solar cells by graphene oxide quantum dots modified TiO₂ layer

Abstract

All-inorganic cesium lead bromide (CsPbBr₃) perovskite solar cells have been attracting growing interest due to superior performance stability and low cost. However, low light absorbance and large charge recombination at TiO₂/CsPbBr₃ interface or within CsPbBr₃ film still prevent further performance improvement. Herein, we report devices with high power conversion efficiency (9.16%) by introducing graphene oxide quantum dots (GOQDs) between TiO₂ and perovskite layers. The recombination of interfacial radiation can be effectively restrained due to enhanced charge transfer capability. GOQDs with C-rich active sites can involve in crystallization and fill within the CsPbBr₃ perovskite film as functional semiconductor additives. This work provides a promising strategy to optimize the crystallization process and boost charge extraction at the surface/interface optoelectronic properties of perovskites for high efficient and low-cost solar cells.

Graphical abstract

Keywords

all inorganic / perovskite solar cells / graphene oxide quantum dots / high performance / stability

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