Design and synthesis of ZnCo2O4/CdS for substantially improved photocatalytic hydrogen production

Xiaohong Li, Youji Li, Xin Guo, Zhiliang Jin

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PDF(5689 KB)
Front. Chem. Sci. Eng. ›› 2023, Vol. 17 ›› Issue (5) : 606-616. DOI: 10.1007/s11705-022-2233-4
RESEARCH ARTICLE

Design and synthesis of ZnCo2O4/CdS for substantially improved photocatalytic hydrogen production

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Abstract

In this study, the hydrogen evolution performance of CdS nanorods is improved using ZnCo2O4. ZnCo2O4 nanospheres are synthesized using the hydrothermal and calcination methods, and CdS nanorods are synthesized using the solvothermal method. From the perspective of morphology, numerous CdS nanorods are anchored on the ZnCo2O4 microspheres. According to the experimental results of photocatalytic hydrogen evolution, the final hydrogen evolution capacity of 7417.5 μmol∙g–1∙h–1 is slightly more than two times that of the single CdS, which proves the feasibility of our study. Through various characterization methods, it is proved that the composite sample has suitable optoelectronic properties. In addition, ZnCo2O4 itself exhibits good conductivity and low impedance, which shortens the charge-transfer path. Overall, the introduction of ZnCo2O4 expands the adsorption range of light and improves the performance of photocatalytic hydrogen evolution. This design can provide reference for developing high-efficiency photocatalysts.

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Keywords

ZnCo2O4 nanosphere / CdS nanorods / photocatalytic hydrogen evolution

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Xiaohong Li, Youji Li, Xin Guo, Zhiliang Jin. Design and synthesis of ZnCo2O4/CdS for substantially improved photocatalytic hydrogen production. Front. Chem. Sci. Eng., 2023, 17(5): 606‒616 https://doi.org/10.1007/s11705-022-2233-4

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Acknowledgement

This work was financially supported by the National Natural Science Foundation of China (Grant No. 22062001) and the graduate innovation project of North Minzu University (Grant No. YCX22166).

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