Newly-modeled graphene-based ternary nanocomposite for the magnetophotocatalytic reduction of CO₂ with electrochemical performance

Abstract

The development of CO₂ into hydrocarbon fuels has emerged as a green method that could help mitigate global warning. The novel structured photocatalyst is a promising material for use in a photocatalytic and magneto-electrochemical method that fosters the reduction of CO₂ by suppressing the recombination of electron−hole pairs and effectively transferring the electrons to the surface for the chemical reaction of CO₂ reduction. In our study, we have developed a novel-structured AgCuZnS₂–graphene–TiO₂ to analyze its catalytic activity toward the selective evolution of CO₂. The selectivity of each nanocomposite substantially enhanced the activity of the AgCuZnS₂–graphene–TiO₂ ternary nanocomposite due to the successful interaction, and the selectivity of the final product was improved to a value 3 times higher than that of the pure AgCuZnS₂ and 2 times higher than those of AgCuZnS₂–graphene and AgCuZnS₂–TiO₂ under ultra-violet (UV)-light (λ = 254 nm) irradiation in the photocatalytic process. The electrochemical CO₂ reduction test was also conducted to analyze the efficacy of the AgCuZnS₂–graphene–TiO₂ when used as a working electrode in laboratory electrochemical cells. The electrochemical process was conducted under different experimental conditions, such as various scan rates (mV·s^–1), under UV-light and with a 0.07 T magnetic-core. The evolution of CO₂ substantially improved under UV-light (λ = 254 nm) and with 0.07 T magnetic-core treatment; these improvements were attributed to the facts that the UV-light activated the electron-transfer pathway and the magnetic core controlled the pathway of electron-transmission/prevention to protect it from chaotic electron movement. Among all tested nanocomposites, AgCuZnS₂–graphene–TiO₂ absorbed the CO₂ most strongly and showed the best ability to transfer the electron to reduce the CO₂ to methanol. We believe that our newly-modeled ternary nanocomposite opens up new opportunities for the evolution of CO₂ to methanol through an electrochemical and photocatalytic process.

Graphical abstract

Keywords

ternary nanocomposite / photocatalytic / electrochemical CO₂ reduction / UV-light / magnetic core

References

[1] Jae H L, Sung I K, Sun M P, Misook K. A p-n heterojunction NiS-sensitized TiO₂ photocatalytic system for efficient photoreduction of carbon dioxide to methane. Ceramics International, 2017, 43 : 1768– 1774

[2] Zhang W, Xu R. Surface engineered active photocatalysts without noble metals: CuS–Zn_xCd_1−xS nanospheres by one-step synthesis. International Journal of Hydrogen Energy, 2009, 34 : 8495– 8503

[3] Shen Q, Chen Z, Huang X, Liu M, Zhao G. High-yield and selective photoelectrocatalytic reduction of CO₂ to formate by metallic copper decorated Co₃O₄ nanotube arrays. Environmental Science & Technology, 2015, 49 : 5828– 5835

[4] Li X, Wen J, Low J, Fang Y, Yu J. Design and fabrication of semiconductor photocatalyst for photocatalytic reduction of CO₂ to solar fuel. Science China Materials, 2014, 57 : 70– 100

[5] Peng H, Mo Z, Liao S, Liang H, Yang L, Luo F, Song H, Zhong Y, Zhang B. High performance Fe- and N-doped carbon catalyst with graphene structure for oxygen reduction. Scientific Reports, 2013, 3( 1): 1765

[6] Diptiman D, Estak M A, Sumit M, Biswajit M, Shyamal K S. Amorphous molybdenum sulfide quantum dots: an efficient hydrogen evolution electrocatalyst in neutral medium. Journal of Materials Chemistry A, 2016, 40 : 15486– 15493

[7] Li X, Yu J, Jaroniec M, Chen X. Cocatalysts for selective photoreduction of CO₂ into solar fuels. Chemical Reviews, 2019, 119( 6): 3962– 4179

[8] Xu F, Zhang J, Zhu B, Yu J, Xu J. CuInS₂ sensitized TiO₂ hybrid nanofibers for improved photocatalytic CO₂ reduction. Applied Catalysis B: Environmental, 2018, 230( 15): 194– 202

[9] Liang Z, Shen R, Hau Ng Y, Zhang P, Xiang Q, Li X. A review on 2D MoS₂ cocatalysts in photocatalytic H₂ production. Journal of Materials Science and Technology, 2020, 56 : 89– 121

[10] Shen R C, Ren D D, Ding Y N, Guan Y T, Ng Y H, Zhang P, Li X. Nanostructured CdS for efficient photocatalytic H₂ evolution: a review. Science China Materials, 2020, 63 : 2153– 2188

[11] Yang Y, Que W, Zhang X, Yin X, Xing Y, Que M, Zhao H, Du Y. High-quality Cu₂ZnSnS₄ and Cu₂ZnSnSe₄ nanocrystals hybrid with ZnO and NaYF₄: Yb, Tm as efficient photocatalytic sensitizers. Applied Catalysis B: Environmental, 2017, 200 : 402– 411

[12] Xue W, Chang W, Hu X, Fan J, Liu E. 2D mesoporous ultrathin Cd_0.5Zn_0.5S nanosheet: fabrication mechanism and application potential for photocatalytic H₂ evolution. Chinese Journal of Catalysis, 2021, 42 : 152– 163

[13] Li K, Zhang S, Li Y, Fan J, Lv K. MXenes as noble-metal-alternative co-catalysts in photocatalysis. Chinese Journal of Catalysis, 2021, 42 : 3– 14

[14] Inoue T, Fujishima A, Konishi S, Honda K. Photoelectrocatalytic reduction of carbon dioxide in aqueous suspensions of semiconductor powders. Nature, 1979, 277 : 637– 638

[15] Roy N Hirano Y Sudhagar P Suzuki N Katsumata K Nakata K Kondo T Yuasa M Serzawa I Takayama T. Boron-doped diamond semiconductor electrodes: efficient photoelectrochemical CO₂ reduction through surface modification . Scientific Reports, 2016

[16] Liu Y, Chen S, Quan X, Yu H. Efficient electrochemical reduction of carbon dioxide to acetate on nitrogen-doped nano diamond. Journal of the American Chemical Society, 2015, 137 : 11631– 11636

[17] Cheng L, Zhang D, Liao Y, Fan J, Xiang Q. Structural engineering of 3D hierarchical Cd_0.8Zn_0.2S for selective photocatalytic CO₂ reduction. Chinese Journal of Catalysis, 2021, 42 : 131– 140

[18] Xiong H, Xie X, Wang M, Hou Y, Hou X. CVD grown carbon nanotubes on reticulated skeleton for brine desalination. Acta Physico-Chimica Sinica, 2020, 36( 9): 1912008 (in Chinese)

[19] Eda G, Fanchini G, Chhowalla M. Large-area ultrathin films of reduced graphene oxide as a transparent and flexible electronic material. Nature Nanotechnology, 2008, 3 : 270– 274

[20] Tian H, Wan C, Xue X, Hu X, Wang X. Effective electron transfer pathway of the ternary TiO₂/RGO/Ag nanocomposite with enhanced photocatalytic activity under visible light. Catalysts, 2017, 7 : 156

[21] Xie Q, He W, Liu S, Li C, Zhang J, Wong P K. Bifunctional S-scheme g-C₃N₄/Bi/BiVO₄ hybrid photocatalysts toward artificial carbon cycling. Chinese Journal of Catalysis, 2020, 42 : 140– 153

[22] Duan S, Wu S, Wang L, She H, Huang J, Wang Q. Rod-shaped metal organic framework structured PCN-222(Cu)/TiO₂ composites for efficient photocatalytic CO₂ reduction. Acta Physico-Chimica Sinica, 2020, 36 : 1905086 (in Chinese)

[23] Zeng B, Zeng W. Synthesis of reduced graphene oxide loaded ZnS/Ag₂S quantum dot heterostructures via ion-exchange for high-efficiency photocatalytic hydrogen production. Digest Journal of Nanomaterials and Biostructures, 2017, 12( 1): 215– 222

[24] Surekha G, Krishnaia K V, Ravi N, Suvarna R P. FTIR, Raman and XRD analysis of graphene oxide films prepared by modified Hummers method. Journal of Physics: Conference Series, 2020, 1495 : 012012

[25] Yu S, Wang X, Zhang R, Yang T, Ai Y, Wen T, Huang W, Hayat T, Alsaedi A, Wang X. Complex roles of solution chemistry on graphene oxide coagulation onto titanium dioxide: batch experiments, spectroscopy analysis and theoretical calculation. Scientific Reports, 2017, 7 : 39625

[26] Coronado J M Fresno F Hernández-Alonso M D Portela R Suárez S García R S de la Peña O’Shea V A. Design of advanced photocatalytic materials for energy and environmental applications. In: Green Energy and Technology. Heidenberg: Springer, 2013

[27] Reyes-Coronado D, Rodríguez-Gattorno G, Espinaso-Pesqueira M E, Cab C, de Coss R, Oskam G. Phase-pure TiO₂ nanoparticles: anatase, brookite and rutile. Nanotechnology, 2008, 19 : 145605

[28] Ferrari A, Basko D. Raman spectroscopy as a versatile tool for studying the properties of graphene. Nature Nanotechnology, 2013, 8 : 235– 246

[29] Pitna L B, Kavan L, Zukalova M, Mocek K, Frank O. In situ Raman spectroelectrochemistry as a useful tool for detection of TiO₂ (anatase) impurities in TiO₂(B) and TiO₂(rutile). Monatshefte für Chemie, 2016, 147 : 951– 959

[30] Watanabe F, Nima Z, Honda T, Mitsuhara M, Nishida M, Biris A S. X-ray photoelectron spectroscopy and transmission electron microscopy analysis of silver-coated gold nanorods designed for bio nanotechnology applications. Nanotechnology, 2017, 28 : 025704

[31] Ghodselahi T, Vesaghi M A, Shafiekhani A, Baghizadeh A, Lameii M. XPS study of the Cu@Cu₂O core-shell nanoparticles. Applied Surface Science, 2008, 255( 5): 2730– 2734

[32] Sun X F, Wang S G, Zhang X M, Chen J P, Li X M, Gao B Y, Ma Y. Spectroscopic study of Zn²⁺ and Co²⁺ binding to extracellular polymeric substances (EPS) from aerobic granules. Journal of Colloid and Interface Science, 2009, 335( 1): 11– 17

[33] Kim S, Britcher L, Kumar S, Griesser H J. XPS study of sulfur and phosphorus compounds with different oxidation states. Sains Malaysiana, 2018, 47( 8): 1913– 1922

[34] Al-Gaashani R, Najjar A, Zakaria Y, Mansour S, Atieh M A. XPS and structural studies of high quality graphene oxide and reduced graphene oxide prepared by different chemical oxidation methods. Ceramics International, 2019, 45( 11): 14439– 14448

[35] Mai W, Wen F, Xie D, Leng Y, Mu Z. Structure and composition study of carbon-doped titanium oxide film combined with first principles. Journal of Advanced Ceramics, 2014, 3( 1): 49– 55

[36] Kovtun A, Jones D, Dell’Elce S, Treossi E, Liscio A, Palermo V. Accurate chemical analysis of graphene-based materials using X-ray photoelectron spectroscopy. Carbon, 2019, 143 : 268– 275

[37] Zambaga O, Jung C H, Oh W C. New modeling of AgFeNi₂S₄−graphene−TiO₂ ternary nanocomposite with chelate compounds and its photocatalytic reduction of CO₂. Journal of Materials Science Materials in Electronics, 2021, 32 : 9804– 9821

[38] Wang X, Jiang Z, Chen H, Wang K, Wang X. Photocatalytic CO₂ reduction with water vapor to CO and CH₄ in a recirculation reactor by Ag-Cu₂O/TiO₂ Z-scheme heterostructures. Journal of Alloys and Compounds, 2021, 896 : 163030

[39] Tahir M, Tahir B. Constructing S-scheme 2D/0D g-C₃N₄/TiO₂ NPs/MPs heterojunction with 2D-Ti₃AlC₂ MAX cocatalyst for photocatalytic CO₂ reduction to CO/CH₄ in fixed-bed and monolith photoreactors. Journal of Materials Science and Technology, 2022, 103 : 195– 210

[40] Raza A, Shen H, Haidry A A, Sun L, Liu R, Cui S. Studies of Z-scheme WO₃-TiO₂/Cu₂ZnSnS₄ ternary nanocomposite with enhanced CO₂ photoreduction under visible light irradiation. Journal of CO₂ Utilization , 2020, 37 : 260– 271

[41] Park A R, Nam M G, Kim A Y, Kim K S, Lee J Y, Kim W J, Yoo P J. Si/Co-CoSi₂/reduced graphene oxide ternary nanocomposite anodes for Li-ion batteries with enhanced capacity and cycling stability. Journal of Alloys and Compounds, 2017, 724 : 1134– 1142

[42] Fei X Tan H Cheng B Zhu B Zhang L. 2D/2D black phosphorus/ g-C₃N₄ S-scheme heterojunction photocatalysts for CO₂ reduction investigated using DFT calculations . Acta Physico-Chimica Sinica, 2021, 37(6): 2010027 (in Chinese)

[43] Quan H, Qian K, Xuan Y, Lou L L, Yu K, Liu S. Superior performance in visible-light-driven hydrogen evolution reaction of three-dimensionally ordered macroporous SrTiO₃ decorated with Zn_xCd_1−xS. Frontiers of Chemical Science and Engineering, 2021, 15 : 1561– 1571

[44] Yang Y, Zhang D, Xiang Q. Plasma-modified Ti₃C₂T_x/CdS hybrids with oxygen-containing groups for high-efficiency photocatalytic hydrogen production. Nanoscale, 2019, 11 : 18797– 18805

Electronic Supplementary Material

Supplementary material is available in the online version of this article at https://dx.doi.org/10.1007/s11705-022-2166-y and is accessible for authorized users.

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